DOI: 10.1002/smll.200500496. In Situ Raman Study on Single‐ and Double‐Walled Carbon Nanotubes as a Function of Lithium Insertion

In Situ Raman Study on Single‐ and Double‐Walled Carbon Nanotubes as a Function of Lithium Insertion

10.1002/smll.200500496

Crossref journal-article

Wiley

Small (311)

Abstract

AbstractWe investigated the electrochemical lithium ion (Li+) insertion/desertion behavior on highly pure and bundled single‐ and double‐walled carbon nanotubes (SWNTs and DWNTs) using an in situ Raman technique. In general, two storage sites could host Li+ in SWNT and DWNT bundles when varying an external potential: a) the outer surface sites, and b) the interstitial spaces within the bundles. The most sensitive changes in the tangential mode (TM) of the Raman spectra upon doping with Li+ can be divided into two regions. The first region was found from 2.8 to 1.0 V (the coverage of Li+ on the outer surface of a bundled nanotube) and was characterized by the loss of resonant conditions via partial charge transfer, where the G+ line of the SWNT and the TM of the outer tube of DWNTs experienced a highly depressed intensity, but remained almost constant in frequency. The appearance of a Breit–Wigner–Fano (BWF) profile provided strong evidence of metallic inner tubes within DWNTs. The second region was observed when the applied potentials ranged from 0.9 to 0 V and was characterized by Li+ diffusion into the interstitial sites of the bundled nanotube material. This phenomenon invoked a large downshift of the G− band in SWNTs, and a small downshift of the TM of the inner tube of DWNTs caused by expansion of the CC bonds due to the charge transferred to the nanotubes, and the disappearance of the BWF profile through the screening effect of the interstitial Li+ layers.

Bibliography

Kim, Y. A., Kojima, M., Muramatsu, H., Umemoto, S., Watanabe, T., Yoshida, K., Sato, K., Ikeda, T., Hayashi, T., Endo, M., Terrones, M., & Dresselhaus, M. S. (2006). In Situ Raman Study on Singleâ and DoubleâWalled Carbon Nanotubes as a Function of Lithium Insertion. Small, 2(5), 667â676. Portico.

Authors 12

Yoong Ahm Kim (first)
Masahito Kojima (additional)
Hiroyuki Muramatsu (additional)
Souichiro Umemoto (additional)
Takaaki Watanabe (additional)
Kazuto Yoshida (additional)
Keigo Sato (additional)
Takuya Ikeda (additional)
Takuya Hayashi (additional)
Morinobu Endo (additional)
Mauricio Terrones (additional)
Mildred S. Dresselhaus (additional)

References 37 Referenced 75

10.1016/B978-008042683-9/50013-3
10.1016/S0008-6223(99)00141-4
10.1016/S0008-6223(00)00157-3
10.1016/j.carbon.2003.09.021
10.1038/30694
10.1016/S0009-2614(99)00486-8
10.1149/1.1393615
10.1103/PhysRevLett.88.015502
10.1016/S0378-7753(99)00130-5
10.1038/433476a
10.1016/0022-0248(76)90115-9
{'key': 'e_1_2_6_12_2', 'first-page': '568', 'volume': '18', 'author': 'Endo M.', 'year': '1988', 'journal-title': 'Chem. Tech.'} / Chem. Tech. by Endo M. (1988)
10.1149/1.1837049
10.1016/S0008-6223(98)80036-5
10.1038/40827
10.1021/jp984362t
10.1016/S0009-2614(00)01335-X
10.1016/S0009-2614(03)00157-X
10.1103/PhysRevLett.90.257403
10.1016/S0009-2614(00)00940-4
10.1002/cphc.200300916
10.1002/adfm.200400048
10.1149/1.2086855
10.1038/362520a0
10.1016/j.carbon.2005.03.041
10.1016/S0008-6223(00)00137-8
10.1016/0008-6223(88)90078-4
10.1103/PhysRevLett.86.1118
10.1016/S0009-2614(99)00399-1
10.1080/000187300413184
10.1103/PhysRevB.65.155412
10.1016/0378-7753(94)02073-C
10.1103/PhysRevB.71.045408
10.1103/PhysRevB.66.195406
10.1103/PhysRevB.66.161404
10.1016/j.carbon.2004.06.041
10.1002/adma.200304942

Dates

Type	When
Created	19 years, 5 months ago (March 15, 2006, 3:47 a.m.)
Deposited	1 year, 10 months ago (Oct. 8, 2023, 4:45 a.m.)
Indexed	3 weeks, 1 day ago (July 30, 2025, 10:06 a.m.)
Issued	19 years, 4 months ago (March 27, 2006)
Published	19 years, 4 months ago (March 27, 2006)
Published Online	19 years, 4 months ago (March 27, 2006)
Published Print	19 years, 3 months ago (May 1, 2006)

Funders 0

None

BibTeX

@article{Kim_2006, title={In Situ Raman Study on Single‐ and Double‐Walled Carbon Nanotubes as a Function of Lithium Insertion}, volume={2}, ISSN={1613-6829}, url={http://dx.doi.org/10.1002/smll.200500496}, DOI={10.1002/smll.200500496}, number={5}, journal={Small}, publisher={Wiley}, author={Kim, Yoong Ahm and Kojima, Masahito and Muramatsu, Hiroyuki and Umemoto, Souichiro and Watanabe, Takaaki and Yoshida, Kazuto and Sato, Keigo and Ikeda, Takuya and Hayashi, Takuya and Endo, Morinobu and Terrones, Mauricio and Dresselhaus, Mildred S.}, year={2006}, month=mar, pages={667–676} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        30
      ]
    ],
    "date-time": "2025-07-30T14:06:27Z",
    "timestamp": 1753884387558
  },
  "reference-count": 37,
  "publisher": "Wiley",
  "issue": "5",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2006,
            3,
            15
          ]
        ],
        "date-time": "2006-03-15T00:00:00Z",
        "timestamp": 1142380800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2006,
        5
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>We investigated the electrochemical lithium ion (Li<jats:sup>+</jats:sup>) insertion/desertion behavior on highly pure and bundled single\u2010 and double\u2010walled carbon nanotubes (SWNTs and DWNTs) using an in\u2005situ Raman technique. In general, two storage sites could host Li<jats:sup>+</jats:sup> in SWNT and DWNT bundles when varying an external potential: a)\u2005the outer surface sites, and b)\u2005the interstitial spaces within the bundles. The most sensitive changes in the tangential mode (TM) of the Raman spectra upon doping with Li<jats:sup>+</jats:sup> can be divided into two regions. The first region was found from 2.8 to 1.0\u2005V (the coverage of Li<jats:sup>+</jats:sup> on the outer surface of a bundled nanotube) and was characterized by the loss of resonant conditions via partial charge transfer, where the G<jats:sup>+</jats:sup> line of the SWNT and the TM of the outer tube of DWNTs experienced a highly depressed intensity, but remained almost constant in frequency. The appearance of a Breit\u2013Wigner\u2013Fano (BWF) profile provided strong evidence of metallic inner tubes within DWNTs. The second region was observed when the applied potentials ranged from 0.9 to 0\u2005V and was characterized by Li<jats:sup>+</jats:sup> diffusion into the interstitial sites of the bundled nanotube material. This phenomenon invoked a large downshift of the G<jats:sup>\u2212</jats:sup> band in SWNTs, and a small downshift of the TM of the inner tube of DWNTs caused by expansion of the C\uf8ffC bonds due to the charge transferred to the nanotubes, and the disappearance of the BWF profile through the screening effect of the interstitial Li<jats:sup>+</jats:sup> layers.</jats:p>",
  "DOI": "10.1002/smll.200500496",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        3,
        15
      ]
    ],
    "date-time": "2006-03-15T08:47:23Z",
    "timestamp": 1142412443000
  },
  "page": "667-676",
  "source": "Crossref",
  "is-referenced-by-count": 75,
  "title": "In Situ Raman Study on Single\u2010 and Double\u2010Walled Carbon Nanotubes as a Function of Lithium Insertion",
  "prefix": "10.1002",
  "volume": "2",
  "author": [
    {
      "given": "Yoong\u2005Ahm",
      "family": "Kim",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Masahito",
      "family": "Kojima",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Hiroyuki",
      "family": "Muramatsu",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Souichiro",
      "family": "Umemoto",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Takaaki",
      "family": "Watanabe",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Kazuto",
      "family": "Yoshida",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Keigo",
      "family": "Sato",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Takuya",
      "family": "Ikeda",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Takuya",
      "family": "Hayashi",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Morinobu",
      "family": "Endo",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Mauricio",
      "family": "Terrones",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Mildred\u2005S.",
      "family": "Dresselhaus",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_6_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/B978-008042683-9/50013-3"
    },
    {
      "key": "e_1_2_6_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(99)00141-4"
    },
    {
      "key": "e_1_2_6_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(00)00157-3"
    },
    {
      "key": "e_1_2_6_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.carbon.2003.09.021"
    },
    {
      "key": "e_1_2_6_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/30694"
    },
    {
      "key": "e_1_2_6_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(99)00486-8"
    },
    {
      "key": "e_1_2_6_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1393615"
    },
    {
      "key": "e_1_2_6_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.88.015502"
    },
    {
      "key": "e_1_2_6_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0378-7753(99)00130-5"
    },
    {
      "key": "e_1_2_6_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/433476a"
    },
    {
      "key": "e_1_2_6_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-0248(76)90115-9"
    },
    {
      "key": "e_1_2_6_12_2",
      "first-page": "568",
      "volume": "18",
      "author": "Endo M.",
      "year": "1988",
      "journal-title": "Chem. Tech."
    },
    {
      "key": "e_1_2_6_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1837049"
    },
    {
      "key": "e_1_2_6_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(98)80036-5"
    },
    {
      "key": "e_1_2_6_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/40827"
    },
    {
      "key": "e_1_2_6_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp984362t"
    },
    {
      "key": "e_1_2_6_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(00)01335-X"
    },
    {
      "key": "e_1_2_6_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(03)00157-X"
    },
    {
      "key": "e_1_2_6_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.90.257403"
    },
    {
      "key": "e_1_2_6_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(00)00940-4"
    },
    {
      "key": "e_1_2_6_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/cphc.200300916"
    },
    {
      "key": "e_1_2_6_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.200400048"
    },
    {
      "key": "e_1_2_6_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.2086855"
    },
    {
      "key": "e_1_2_6_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/362520a0"
    },
    {
      "key": "e_1_2_6_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.carbon.2005.03.041"
    },
    {
      "key": "e_1_2_6_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(00)00137-8"
    },
    {
      "key": "e_1_2_6_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0008-6223(88)90078-4"
    },
    {
      "key": "e_1_2_6_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.86.1118"
    },
    {
      "key": "e_1_2_6_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(99)00399-1"
    },
    {
      "key": "e_1_2_6_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/000187300413184"
    },
    {
      "key": "e_1_2_6_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.65.155412"
    },
    {
      "key": "e_1_2_6_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0378-7753(94)02073-C"
    },
    {
      "key": "e_1_2_6_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.71.045408"
    },
    {
      "key": "e_1_2_6_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.66.195406"
    },
    {
      "key": "e_1_2_6_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.66.161404"
    },
    {
      "key": "e_1_2_6_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.carbon.2004.06.041"
    },
    {
      "key": "e_1_2_6_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200304942"
    }
  ],
  "container-title": "Small",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fsmll.200500496",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/smll.200500496",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        8
      ]
    ],
    "date-time": "2023-10-08T08:45:11Z",
    "timestamp": 1696754711000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/smll.200500496"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "references-count": 37,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          2006,
          5
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/smll.200500496"
  ],
  "URL": "http://dx.doi.org/10.1002/smll.200500496",
  "relation": {},
  "ISSN": [
    "1613-6810",
    "1613-6829"
  ],
  "subject": [],
  "container-title-short": "Small",
  "published": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  }
}