DOI: 10.1002/sia.740220161. High‐resolution electron‐energy‐loss spectroscopy of hydroxyl groups at the surface of bulk insulating oxides

High‐resolution electron‐energy‐loss spectroscopy of hydroxyl groups at the surface of bulk insulating oxides

10.1002/sia.740220161

Crossref journal-article

Wiley

Surface and Interface Analysis (311)

Abstract

AbstractThe capability of high‐resolution electron‐energy‐loss spectroscopy to study adsorbates at the surface of bulk insulating oxides has been applied to the cases of OH/MgO(100) and OH/α‐Al2O3(0001). On MgO(100), two types of OH have been identified, either bonded to surface Mg ions (A type) or due to proton adsorption on surface oxygen ions (B type). Dense OH adlayers on MgO(100) (5‐coordinate Mg) have been seen to correspond to νOH(A) = 3690 cm−1 (νOH > 3700 cm−1 being suggested to be related to defects and/or low coverages). On α‐Al2O3(0001), a sharp stretching band νOH has been recorded at 3720 cm−1 and assigned to OH bonded (or bridge‐bonded) to Al in octahedral position.

Bibliography

Coustet, V., & Jupille, J. (1994). Highâresolution electronâenergyâloss spectroscopy of hydroxyl groups at the surface of bulk insulating oxides. Surface and Interface Analysis, 22(1â12), 280â283. Portico.

Authors 2

Valérie Coustet (first)
Jacques Jupille (additional)

References 22 Referenced 38

10.1016/S0167-2991(08)63996-8
10.1080/03602457808080878
10.1039/tf9656102754
10.1039/f19898500441
10.1016/0039-6028(92)90475-L
10.1016/0254-0584(88)90016-8
10.1080/05704928508060432
10.1103/PhysRevB.33.5682
{'key': 'e_1_2_1_10_2', 'author': 'Coustet V.', 'journal-title': 'Surf. Sci.'} / Surf. Sci. by Coustet V.
10.1021/ac50059a017
10.1002/sia.740010103
10.1002/sia.740171305
10.1016/0368-2048(76)80015-1
10.1103/PhysRev.140.A2076
{'key': 'e_1_2_1_16_2', 'author': 'Didier F.', 'journal-title': 'Surf. Sci.'} / Surf. Sci. by Didier F.
10.1016/S0039-6028(87)81192-5
10.1007/BF00770893
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10.1063/1.449902
10.1016/0039-6028(91)90170-W

Dates

Type	When
Created	20 years, 3 months ago (May 28, 2005, 8 a.m.)
Deposited	1 year, 11 months ago (Aug. 31, 2023, 12:45 a.m.)
Indexed	2 months ago (June 27, 2025, 3:45 p.m.)
Issued	31 years, 1 month ago (July 1, 1994)
Published	31 years, 1 month ago (July 1, 1994)
Published Online	20 years, 11 months ago (Sept. 15, 2004)
Published Print	31 years, 1 month ago (July 1, 1994)

Funders 0

None

BibTeX

@article{Coustet_1994, title={High‐resolution electron‐energy‐loss spectroscopy of hydroxyl groups at the surface of bulk insulating oxides}, volume={22}, ISSN={1096-9918}, url={http://dx.doi.org/10.1002/sia.740220161}, DOI={10.1002/sia.740220161}, number={1–12}, journal={Surface and Interface Analysis}, publisher={Wiley}, author={Coustet, Valérie and Jupille, Jacques}, year={1994}, month=jul, pages={280–283} }

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