DOI: 10.1002/sia.740040508. X‐ray photoelectron spectroscopic studies of carbon fibre surfaces. III—Industrially treated fibres and the effect of heat and exposure to oxygen

X‐ray photoelectron spectroscopic studies of carbon fibre surfaces. III—Industrially treated fibres and the effect of heat and exposure to oxygen

10.1002/sia.740040508

Crossref journal-article

Wiley

Surface and Interface Analysis (311)

Abstract

AbstractCarbon fibres, surface treated by an industrial process, were analysed by x‐ray photoelectron spectroscopy (XPS). The results allow the surface chemistry to be compared with that achieved by controlled laboratory methods. It is found that industrial treatment has less control over individual fibre surface treatment than in the laboratory treated fibres, and that the reproducibity of treatment varies with the treatment method. As the level of treatment is increased the spectra show an increase in the C/O and C/N surface functional groups. In contrast to the laboratory treated fibres there is no identifiable difference in the types or proportions of C/O groups with the amount of surface treatment, and the overall changes in the spectra are much less. The type and proportion of surface groups between treated and untreated fibres are different. C=O type groups appear to dominate in the treated fibre samples over O—O— type groups. Mass spectroscopic analysis associated with heat treatment can be very usefully combined with XPS analysis in the same apparatus as an aid to the understanding of complex industrially treated samples. Thus the effect of surface treatment can be effectively reversed by heat treatment to very high temperatures, with the regeneration of a fibre surface which resembles that of the untreated fibre surface. Exposure of the heated fibre after cooling to gaseous oxygen causes little change in the surface chemistry.

Bibliography

Proctor, A., & Sherwood, P. M. A. (1982). Xâray photoelectron spectroscopic studies of carbon fibre surfaces. IIIâIndustrially treated fibres and the effect of heat and exposure to oxygen. Surface and Interface Analysis, 4(5), 212â219. Portico.

Authors 2

Andrew Proctor (first)
Peter M. A. Sherwood (additional)

References 13 Referenced 69

{'key': 'e_1_2_1_2_2', 'first-page': '151', 'volume-title': 'Chemistry and Physics of Carbon', 'author': 'McKee D. W.', 'year': '1973'} / Chemistry and Physics of Carbon by McKee D. W. (1973)
A.ProctorandP. M. A.Sherwood J. Electron Spectrosc. Relat. Phenom.in press.
A.ProctorandP. M. A.Sherwood Carbonin press.
{'key': 'e_1_2_1_5_2', 'first-page': '495', 'volume': '5', 'author': 'Sherwood P. M. A.', 'year': '1980', 'journal-title': 'J. Microsc. Spectrosc. Electron.'} / J. Microsc. Spectrosc. Electron. by Sherwood P. M. A. (1980)
10.1021/ac00238a008
10.1021/ac50064a018
10.1016/S0022-0728(79)80286-7
10.1021/ac60214a047
10.1016/0015-0568(79)90011-3
10.1002/pol.1979.170170404
W.Watt private communication.
F.Jones private communication.
J.Harvey private communication.

Dates

Type	When
Created	20 years, 8 months ago (Dec. 30, 2004, 4:40 p.m.)
Deposited	1 year, 9 months ago (Nov. 12, 2023, 2:52 a.m.)
Indexed	1 week, 2 days ago (Aug. 27, 2025, 12:25 p.m.)
Issued	42 years, 11 months ago (Oct. 1, 1982)
Published	42 years, 11 months ago (Oct. 1, 1982)
Published Online	20 years, 11 months ago (Sept. 15, 2004)
Published Print	42 years, 11 months ago (Oct. 1, 1982)

Funders 0

None

BibTeX

@article{Proctor_1982, title={X‐ray photoelectron spectroscopic studies of carbon fibre surfaces. III—Industrially treated fibres and the effect of heat and exposure to oxygen}, volume={4}, ISSN={1096-9918}, url={http://dx.doi.org/10.1002/sia.740040508}, DOI={10.1002/sia.740040508}, number={5}, journal={Surface and Interface Analysis}, publisher={Wiley}, author={Proctor, Andrew and Sherwood, Peter M. A.}, year={1982}, month=oct, pages={212–219} }

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