DOI: 10.1002/sia.2072. Surface film formation on a graphite electrode in Li‐ion batteries: AFM and XPS study

Surface film formation on a graphite electrode in Li‐ion batteries: AFM and XPS study

10.1002/sia.2072

Crossref journal-article

Wiley

Surface and Interface Analysis (311)

Abstract

AbstractThe formation of a passivation film (solid electrolyte interphase, SEI) at the surface of the negative electrode of full LiCoO2/graphite lithium‐ion cells using LiPF6 (1M) in carbonate solvents as electrolyte was investigated by means of x‐ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). The analyses were carried out at different potentials of the first and the fifth cycles, showing the potential‐dependent character of the surface‐film species formation. These species were mainly identified as Li2CO3 up to 3.8 V and LiF up to 4.2 V. This study shows the formation of the SEI during charging and its partial dissolution during discharge. Copyright © 2005 John Wiley & Sons, Ltd.

Bibliography

Leroy, S., Blanchard, F., DedryvÃ¨re, R., Martinez, H., CarrÃ©, B., Lemordant, D., & Gonbeau, D. (2005). Surface film formation on a graphite electrode in Liâion batteries: AFM and XPS study. Surface and Interface Analysis, 37(10), 773â781. Portico.

Authors 7

S. Leroy (first)
F. Blanchard (additional)
R. Dedryvère (additional)
H. Martinez (additional)
B. Carré (additional)
D. Lemordant (additional)
D. Gonbeau (additional)

References 23 Referenced 236

{'key': 'e_1_2_1_2_2', 'first-page': '383', 'volume-title': 'Handbook of Battery Materials', 'author': 'Winter M', 'year': '1999'} / Handbook of Battery Materials by Winter M (1999)
10.1149/1.2128859
10.1149/1.1837858
10.1149/1.1392585
10.1149/1.2114288
10.1149/1.2100722
10.1149/1.2048659
10.1021/jp962815t
10.1016/S0013-4686(99)00194-2
10.1016/S0379-6779(97)04101-5
10.1016/S0378-7753(03)00277-5
10.1016/S0013-4686(02)00044-0
10.1103/PhysRevB.5.4709
10.1016/0368-2048(76)80015-1
10.1016/S0378-7753(01)00505-5
{'key': 'e_1_2_1_17_2', 'first-page': '631', 'volume-title': 'Interfacial Electrochemistry', 'author': 'McCreery RL', 'year': '1999'} / Interfacial Electrochemistry by McCreery RL (1999)
10.1149/1.1597882
10.1016/S0378-7753(01)00529-8
10.1149/1.1760992
10.1149/1.1861994
10.1149/1.2086855
10.1016/S0022-1139(98)00161-4
BlanchardF.Study of gas generation in lithium‐ion batteries during charge or floating conditions PhD Dissertation University of Tours France 2004.

Dates

Type	When
Created	20 years ago (July 28, 2005, 11:48 a.m.)
Deposited	1 year, 9 months ago (Nov. 16, 2023, 4:36 p.m.)
Indexed	19 hours, 55 minutes ago (Aug. 20, 2025, 8:59 a.m.)
Issued	20 years ago (July 28, 2005)
Published	20 years ago (July 28, 2005)
Published Online	20 years ago (July 28, 2005)
Published Print	19 years, 10 months ago (Oct. 1, 2005)

Funders 0

None

BibTeX

@article{Leroy_2005, title={Surface film formation on a graphite electrode in Li‐ion batteries: AFM and XPS study}, volume={37}, ISSN={1096-9918}, url={http://dx.doi.org/10.1002/sia.2072}, DOI={10.1002/sia.2072}, number={10}, journal={Surface and Interface Analysis}, publisher={Wiley}, author={Leroy, S. and Blanchard, F. and Dedryvère, R. and Martinez, H. and Carré, B. and Lemordant, D. and Gonbeau, D.}, year={2005}, month=jul, pages={773–781} }

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