Sonochemistry: Theory and applications
10.1002/recl.19941131202
Crossref journal-article
Wiley
Recueil des Travaux Chimiques des Pays-Bas (311)
Abstract

AbstractUltrasound can be used in chemistry to increase both reaction rates and yields of products. Most effects of ultrasound on chemical reactions are due to cavitation: the formation and collapse of small bubbles in the solvent. In this review, we first outline the physical background of cavitation, and discuss its dependence on factors such as sound intensity and frequency, solvent and temperature. The impact of ultrasound on chemical reactions is considered for homogeneous reactions and for heterogeneous liquid‐solid systems. The first area is mainly illustrated by a discussion of the effect of ultrasound on polymerization and depolymerization reactions, the second by selected examples in organic synthesis. The tendency of ultrasound to change reaction mechanisms in favour of homolytic (instead of heterolytic) pathways, is also briefly discussed. The specific preference for a particular pathway under sonochemical conditions, different from that under mechanical stirring has been termed “sonochemical switching”. Ultrasonic equipment for lab‐scale experiments are compared, and some practical “tricks and traps” are given.

Bibliography

Pestman, J. M., Engberts, J. B. F. N., & de Jong, F. (1994). Sonochemistry: Theory and applications. Recueil Des Travaux Chimiques Des Pays-Bas, 113(12), 533–542. Portico.

Authors 3
  1. Jolanda M. Pestman (first)
  2. Jan B. F. N. Engberts (additional)
  3. Feike de Jong (additional)
References 104 Referenced 72
  1. {'key': 'e_1_2_1_2_2', 'first-page': '1', 'volume-title': 'Sonochemistry: The Uses of Ultrasound in Chemistry', 'author': 'Mason T.J.', 'year': '1990'} / Sonochemistry: The Uses of Ultrasound in Chemistry by Mason T.J. (1990)
  2. 10.1016/0160-9327(89)90086-0
  3. 10.1039/cs9871600239
  4. {'key': 'e_1_2_1_5_2', 'first-page': '1', 'volume': '1', 'author': 'Bremner D.', 'year': '1990', 'journal-title': 'Adv. Sonochem.'} / Adv. Sonochem. by Bremner D. (1990)
  5. T.J.Mason Chem. Ind.47(1993).
  6. 10.1016/0041-624X(90)90033-K
  7. C.Einhorn J.EinhornandJ.L.Luche Synthesis787(1989). (10.1055/s-1989-27398)
  8. 10.1016/S0065-3055(08)60573-0
  9. {'key': 'e_1_2_1_10_2', 'first-page': '198', 'volume': '1', 'author': 'Suslick K.S.', 'year': '1990', 'journal-title': 'Adv. Sonochemistry'} / Adv. Sonochemistry by Suslick K.S. (1990)
  10. 10.1088/0370-1301/63/9/305
  11. 10.1088/0370-1301/64/12/302
  12. 10.1016/0041-624X(85)90024-1
  13. {'key': 'e_1_2_1_14_2', 'first-page': '39', 'volume': '1', 'author': 'Margulis M.A.', 'year': '1990', 'journal-title': 'Adv. Sonochem.'} / Adv. Sonochem. by Margulis M.A. (1990)
  14. 10.1016/0041-624X(92)90065-T
  15. 10.1016/S0040-4039(00)97559-2
  16. 10.1016/S0040-4039(00)97560-9
  17. 10.1016/S0040-4039(00)92288-3
  18. 10.1016/0041-624X(92)90066-U
  19. 10.1016/0041-624X(90)90038-P
  20. 10.1038/scientificamerican0289-80
  21. {'key': 'e_1_2_1_22_2', 'first-page': '9', 'volume-title': 'Sonochemistry: the Uses of Ultrasound in Chemistry', 'author': 'Lorimer J.P.', 'year': '1990'} / Sonochemistry: the Uses of Ultrasound in Chemistry by Lorimer J.P. (1990)
  22. 10.1016/0041-624X(87)90003-5
  23. 10.1126/science.253.5026.1397
  24. 10.1063/1.1743145
  25. {'key': 'e_1_2_1_26_2', 'first-page': '1', 'volume': '2', 'author': 'Kruus P.', 'year': '1991', 'journal-title': 'Adv. Sonochem.'} / Adv. Sonochem. by Kruus P. (1991)
  26. 10.1021/jo00241a017
  27. 10.1021/j100182a020
  28. 10.1016/0041-624X(92)90030-P
  29. {'key': 'e_1_2_1_30_2', 'first-page': '31', 'volume': '21', 'author': 'Abdulla R.F.', 'year': '1988', 'journal-title': 'Aldrichimica Acta'} / Aldrichimica Acta by Abdulla R.F. (1988)
  30. 10.1021/j100103a027
  31. 10.1126/science.247.4949.1439
  32. 10.1039/cs9871600275
  33. 10.1021/ja00188a081
  34. 10.1016/0040-4039(91)80174-5
  35. T.Ando S.Sumi T.Kawate J.IchiharaandT.Hanafusa J. Chem. Soc. Chem. Commun.439(1984). (10.1039/C39840000439)
  36. 10.1016/0041-624X(90)90040-U
  37. 10.1135/cccc19821334
  38. G.Price Chem. Ind.75(1993).
  39. {'key': 'e_1_2_1_40_2', 'first-page': '87', 'volume-title': 'Current Trends in Sonochemistry', 'author': 'Price G.', 'year': '1992'} / Current Trends in Sonochemistry by Price G. (1992)
  40. {'key': 'e_1_2_1_41_2', 'first-page': '115', 'volume-title': 'Chemistry with Ultrasound', 'author': 'Lorimer J.P.', 'year': '1990'} / Chemistry with Ultrasound by Lorimer J.P. (1990)
  41. 10.1016/0041-624X(83)90041-0
  42. 10.1016/0041-624X(87)90005-9
  43. 10.1021/j100261a044
  44. J.P.Lorimer T.J.MasonandD.Kershaw J. Chem. Soc. Chem. Commun.1217(1991). (10.1039/c39910001217)
  45. 10.1002/marc.1988.030090106
  46. 10.1016/0041-624X(90)90036-N
  47. 10.1016/0041-624X(88)90035-2
  48. 10.1016/0032-3861(93)90793-A
  49. 10.1021/ma00050a010
  50. 10.1016/0041-624X(91)90047-C
  51. 10.1007/3-540-07942-4_6
  52. 10.1021/j100375a073
  53. 10.1021/j100321a052
  54. 10.1021/j100324a005
  55. {'key': 'e_1_2_1_56_2', 'first-page': '231', 'volume': '1', 'author': 'Price G.J.', 'year': '1990', 'journal-title': 'Adv. Sonochem.'} / Adv. Sonochem. by Price G.J. (1990)
  56. 10.1080/00222338708076937
  57. 10.1016/0014-3057(93)90114-U
  58. 10.1002/pi.4990240306
  59. 10.1295/polymj.13.927
  60. 10.1080/10101329208054107
  61. 10.1080/00222338208066479
  62. 10.1080/00222338208074435
  63. {'key': 'e_1_2_1_64_2', 'first-page': '455', 'volume': '22', 'author': 'Chen K.', 'year': '1985', 'journal-title': 'J. Macromol. Sci. Chem.'} / J. Macromol. Sci. Chem. by Chen K. (1985)
  64. 10.1111/j.2042-7158.1988.tb07001.x
  65. 10.1002/masy.19880190122
  66. {'key': 'e_1_2_1_67_2', 'first-page': '69', 'volume-title': 'Sonochemistry: the Uses of Ultrasound in Chemistry', 'author': 'Davidson R.S.', 'year': '1990'} / Sonochemistry: the Uses of Ultrasound in Chemistry by Davidson R.S. (1990)
  67. 10.3987/REV-89-398
  68. {'key': 'e_1_2_1_69_2', 'volume-title': 'Ultrasound: Its Chemical, Physical, and Biological Effects', 'author': 'Suslick K.S.', 'year': '1988'} / Ultrasound: Its Chemical, Physical, and Biological Effects by Suslick K.S. (1988)
  69. {'key': 'e_1_2_1_70_2', 'volume-title': 'Chemistry with Ultrasound', 'author': 'Mason T.J.', 'year': '1990'} / Chemistry with Ultrasound by Mason T.J. (1990)
  70. 10.1016/0041-624X(92)90069-X
  71. 10.1021/ja00186a070
  72. 10.1021/jo00304a008
  73. 10.1021/jo00304a009
  74. 10.1021/jo00304a010
  75. 10.1021/ja00356a014
  76. 10.1021/ja00414a054
  77. 10.1016/0041-624X(92)90068-W
  78. 10.1016/S0040-4039(00)74352-8
  79. L.A.Sarandeses A.MouriñoandJ.L.Luche J. Chem. Soc. Chem. Commun.798(1992). (10.1039/C39920000798)
  80. 10.1080/00397919108020831
  81. L.A.Sarandeses A.MouriñoandJ.L.Luche J. Chem. Soc. Chem. Commun.818(1991). (10.1039/C39910000818)
  82. 10.1016/0040-4039(91)85094-L
  83. 10.1021/jo00053a023
  84. 10.1016/0041-624X(87)90011-4
  85. 10.1039/p19920000407
  86. 10.1080/00397919108020824
  87. 10.1021/jo00133a053
  88. 10.1016/0040-4039(93)88006-5
  89. 10.1016/S0040-4039(00)60588-9
  90. 10.1021/ja00017a049
  91. {'key': 'e_1_2_1_92_2', 'volume-title': "Practical Sonochemistry. User's Guide to Applications in Chemistry and Chemical Engineering", 'author': 'Mason T.J.', 'year': '1991'} / Practical Sonochemistry. User's Guide to Applications in Chemistry and Chemical Engineering by Mason T.J. (1991)
  92. {'key': 'e_1_2_1_93_2', 'first-page': '60', 'volume-title': 'Sonochemistry: the Uses of Ultrasound in Chemistry', 'author': 'Mason T.J.', 'year': '1990'} / Sonochemistry: the Uses of Ultrasound in Chemistry by Mason T.J. (1990)
  93. 10.1016/0041-624X(90)90034-L
  94. 10.1016/0300-9467(92)80003-S
  95. 10.1121/1.1909000
  96. 10.1121/1.1907987
  97. {'key': 'e_1_2_1_98_2', 'first-page': '363', 'volume': '15', 'author': 'Boucher R.M.G.', 'year': '1970', 'journal-title': 'Brit. Chem. Eng.'} / Brit. Chem. Eng. by Boucher R.M.G. (1970)
  98. 10.1016/0041-624X(87)90012-6
  99. P.D.Martin Chem. Ind.233 (1993). (10.1016/S0074-7696(08)60770-6)
  100. 10.1016/0041-624X(92)90078-Z
  101. {'key': 'e_1_2_1_102_2', 'first-page': '296', 'volume': '70', 'author': 'Martin P.D.', 'year': '1992', 'journal-title': 'Trans. I. Chem. E.'} / Trans. I. Chem. E. by Martin P.D. (1992)
  102. {'key': 'e_1_2_1_103_2', 'first-page': '189', 'volume-title': 'Chemistry with Ultrasound', 'author': 'Goodwin T.J.', 'year': '1990'} / Chemistry with Ultrasound by Goodwin T.J. (1990)
  103. 10.1016/0041-624X(92)90072-T
  104. {'key': 'e_1_2_1_105_2', 'first-page': '187', 'volume': '2', 'author': 'Senapati N.', 'year': '1991', 'journal-title': 'Adv. Sonochem.'} / Adv. Sonochem. by Senapati N. (1991)
Dates
Type When
Created 14 years, 11 months ago (Sept. 13, 2010, 8:31 p.m.)
Deposited 1 year, 10 months ago (Oct. 24, 2023, 3:14 a.m.)
Indexed 28 minutes ago (Sept. 2, 2025, 6:22 p.m.)
Issued 31 years, 8 months ago (Jan. 1, 1994)
Published 31 years, 8 months ago (Jan. 1, 1994)
Published Online 15 years ago (Sept. 2, 2010)
Published Print 31 years, 8 months ago (Jan. 1, 1994)
Funders 0

None

@article{Pestman_1994, title={Sonochemistry: Theory and applications}, volume={113}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19941131202}, DOI={10.1002/recl.19941131202}, number={12}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Pestman, Jolanda M. and Engberts, Jan B. F. N. and de Jong, Feike}, year={1994}, month=jan, pages={533–542} }