DOI: 10.1002/recl.19841031002. Behaviour of poly(pyrrole) and poly(<i>N</i>‐methylpyrrole) electrodes in acetonitrile

Behaviour of poly(pyrrole) and poly(N‐methylpyrrole) electrodes in acetonitrile

10.1002/recl.19841031002

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractThe impedance of poly(pyrrole) (PP) and poly(N‐methylpyrrole) (PMP) films on platinum in an acetonitrile, LiClO4 solution has been measured. At potentials more positive than a characteristic value, the electrodes exhibit porous behaviour and the impedance is determined by the double‐layer capacitance and the solution resistance inside the pores. At more negative potentials, the PP and PMP electrodes behave like flat‐plate electrodes and two impedance contributions can be distinguished, i.e. a material contribution (material resistance and material capacitance) and a contribution from the interphase polymer‐electrolyte (faradaic resistance and double‐layer capacitance).

Bibliography

Jakobs, R. C. M., Janssen, L. J. J., & Barendrecht, E. (1984). Behaviour of poly(pyrrole) and poly(Nâmethylpyrrole) electrodes in acetonitrile. Recueil Des Travaux Chimiques Des Pays-Bas, 103(10), 275â281. Portico.

Authors 3

R. C. M. Jakobs (first)
L. J. J. Janssen (additional)
E. Barendrecht (additional)

References 17 Referenced 36

A. F.Diaz K. K.KanazawaandG. P.Gardini J. Chem. Soc. Chem. Commun.635(1979). (10.1039/c39790000635)
10.1016/S0022-0728(83)80561-0
10.1149/1.2124250
{'key': 'e_1_2_1_4_2', 'first-page': '24', 'volume-title': 'Electrochemical Methods', 'author': 'Bard A. J.', 'year': '1980'} / Electrochemical Methods by Bard A. J. (1980)
{'key': 'e_1_2_1_5_2', 'first-page': '329', 'volume-title': 'Advances in Electrochemistry and Electrochemical Engineering', 'author': 'de Levie R.', 'year': '1967'} / Advances in Electrochemistry and Electrochemical Engineering by de Levie R. (1967)
10.1016/0013-4686(72)87016-6
A. G. C.Kobussen Thesis Utrecht University 1981 pp.41–46.
10.1016/S0022-0728(76)80332-4
10.1002/recl.19600791013
R.de Levie Thesis Amsterdam University 1963 p.33.
{'key': 'e_1_2_1_11_2', 'first-page': '754', 'volume-title': 'Modern Electrochemistry', 'author': "Bockris J. O'M.", 'year': '1970'} / Modern Electrochemistry by Bockris J. O'M. (1970)
A. F.DiazandJ. I.Castillo J. Chem. Soc. Chem. Commun.397(1980). (10.1039/c39800000397)
10.1016/S0022-0728(81)80008-3
{'key': 'e_1_2_1_14_2', 'first-page': '145', 'volume': '17', 'author': 'Diaz A.', 'year': '1981', 'journal-title': 'Chem. Scr.'} / Chem. Scr. by Diaz A. (1981)
10.1149/1.2124000
10.1016/S0022-0728(79)80057-1
10.1016/0368-1874(82)85140-X

Dates

Type	When
Created	14 years, 11 months ago (Sept. 13, 2010, 10:50 p.m.)
Deposited	1 year, 10 months ago (Oct. 20, 2023, 12:16 p.m.)
Indexed	1 year, 4 months ago (April 11, 2024, 9:08 p.m.)
Issued	41 years, 7 months ago (Jan. 1, 1984)
Published	41 years, 7 months ago (Jan. 1, 1984)
Published Online	14 years, 11 months ago (Sept. 2, 2010)
Published Print	41 years, 7 months ago (Jan. 1, 1984)

Funders 0

None

BibTeX

@article{Jakobs_1984, title={Behaviour of poly(pyrrole) and poly(N‐methylpyrrole) electrodes in acetonitrile}, volume={103}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19841031002}, DOI={10.1002/recl.19841031002}, number={10}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Jakobs, R. C. M. and Janssen, L. J. J. and Barendrecht, E.}, year={1984}, month=jan, pages={275–281} }

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