Abstract
AbstractPotentiometric titration data of poly(ethylenimine) (PEI) and poly(vinylamine) (PVA) are presented. They are described in a phenomenological way by the procedures of Henderson‐Hasselbalch and Mandel, respectively and the conforming parameters are calculated. The values of the parameters are compared for the two polymers mutually and with literature data for other weak polyelectrolytes. Marked specific differences are indicated. These are explained in a qualitative way from the nature of the ionizable group and structure of the polymers. A more quantitative explanation will be attempted in a following paper.
References
24
Referenced
69
10.1039/jr9560002448
- R.Bastian Thesis Polytechnic Institute of Brooklyn 1956.
- J.Robins Thesis Polytechnic Institute of Brooklyn 1959.
10.1021/ja01468a011
10.1002/macp.1963.020590117
10.1016/S0022-0728(69)80132-4
10.1002/pol.1957.1202310401
{'key': 'e_1_2_1_8_2', 'first-page': '62', 'volume': '58', 'author': 'Marcus R. A.', 'year': '1954', 'journal-title': 'J. Phys. Chem.'}
/ J. Phys. Chem. by Marcus R. A. (1954)10.1063/1.1743393
10.1063/1.1744468
10.1080/00222337008081731
10.1016/0014-3057(70)90005-4
10.1002/recl.19730920102
- C. J. Bloysvan TreslongandC. F. H.Morra To be published.
- J. Th. G.Overbeek Colloid Science 1 Amsterdam1952.
- J. C.Leyte Thesis Leiden1961.
10.1021/j150523a011
10.1002/pol.1957.1202310438
10.1524/zpch.1958.15.1-6.093
{'issue': '8', 'key': 'e_1_2_1_19_2', 'first-page': '1841', 'volume': '2', 'author': 'Mandel M.', 'year': '1970', 'journal-title': 'J. Pol. Sci.'}
/ J. Pol. Sci. by Mandel M. (1970){'key': 'e_1_2_1_20_2', 'volume-title': 'Dissociation constants of organic bases in aqueous solution', 'author': 'Perrin D. D.', 'year': '1965'}
/ Dissociation constants of organic bases in aqueous solution by Perrin D. D. (1965)10.1021/ed049p682
- J. W. A.van den Berg Thesis Leiden1971.
- A.Polderman Thesis Leiden1973.
Dates
Type | When |
---|---|
Created | 14 years, 11 months ago (Sept. 13, 2010, 11:55 p.m.) |
Deposited | 1 year, 9 months ago (Nov. 13, 2023, 4:28 p.m.) |
Indexed | 1 month, 2 weeks ago (July 20, 2025, 12:28 a.m.) |
Issued | 51 years, 8 months ago (Jan. 1, 1974) |
Published | 51 years, 8 months ago (Jan. 1, 1974) |
Published Online | 15 years ago (Sept. 2, 2010) |
Published Print | 51 years, 8 months ago (Jan. 1, 1974) |
@article{van_Treslong_1974, title={Poly(ethylenimine) II. Potentiometric titration behaviour in comparison with other weak polyelectrolytes}, volume={93}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19740930612}, DOI={10.1002/recl.19740930612}, number={6}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={van Treslong, C. J. Bloys and Staverman, A. J.}, year={1974}, month=jan, pages={171–178} }