DOI: 10.1002/recl.19730920903. Pyrazoles and imidazoles as ligands. Part xviii: Neutral and anionic pyrazole coordinated to Cu(I) and Ag(I)

Pyrazoles and imidazoles as ligands. Part xviii: Neutral and anionic pyrazole coordinated to Cu(I) and Ag(I)

10.1002/recl.19730920903

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractA few compounds having the general formula M(L)+2 X− are reported, in which M(I) = Cu or Ag, X− = BF−4, NO−3, Cl−, Br−, and L stands for pyrazole, 3(5)‐methylpyrazole and 4‐nitropyrazole. The compounds are formed by reaction of MX and L in acidic medium. Infrared spectra of the compounds are consistent with linear cations ML+2 and uncoordinated anions.Apart from the above compounds, a different class of compounds is formed in less protic media. These compounds are salt like and have the formula M+L−, with M+ = Cu+ and Ag+ and L = pyrazole, 4‐iodopyrazole, 4‐bromopyrazole, 4‐ethylpyrazole, 4‐nitropyrazole and 3(5)‐methylpyrazole.Infrared spectra, mass spectra, X‐ray powder diagrams and solubility studies indicate that these compounds are at least trimeric and possibly polymeric with bridging pyrazolate anions between the metal ions.

Bibliography

Okkersen, H., Groeneveld, W. L., & Reedijk, J. (1973). Pyrazoles and imidazoles as ligands. Part xviii: Neutral and anionic pyrazole coordinated to Cu(I) and Ag(I). Recueil Des Travaux Chimiques Des Pays-Bas, 92(9), 945â953. Portico.

Authors 3

H. Okkersen (first)
W. L. Groeneveld (additional)
J. Reedijk (additional)

References 17 Referenced 36

10.1002/recl.19690881210
10.1002/recl.19700890607
10.1002/recl.19700890917
10.1002/recl.19710900202
10.1002/recl.19710900302
10.1107/S0365110X67002245
10.1107/S0567740869002627
10.1021/ic50105a045
{'key': 'e_1_2_1_9_2', 'first-page': '521', 'author': 'Reimann C. W.', 'year': '1971', 'journal-title': 'Acta Cryst.'} / Acta Cryst. by Reimann C. W. (1971)
10.1002/cber.188902201183
10.1021/cr60279a003
10.1002/recl.19660851203
{'key': 'e_1_2_1_13_2', 'first-page': '170', 'volume': '31', 'author': 'Klinko V. T.', 'year': '1961', 'journal-title': 'J. Chem. USSR'} / J. Chem. USSR by Klinko V. T. (1961)
{'key': 'e_1_2_1_14_2', 'first-page': '256', 'volume': '273', 'author': 'Buchner E.', 'year': '1893', 'journal-title': 'Ann.'} / Ann. by Buchner E. (1893)
{'key': 'e_1_2_1_15_2', 'first-page': '186', 'volume': '598', 'author': 'Hüttel R.', 'year': '1956', 'journal-title': 'Ann.'} / Ann. by Hüttel R. (1956)
10.1002/cber.18930260156
{'key': 'e_1_2_1_17_2', 'volume-title': 'Progress in Inorganic Chemistry', 'author': 'Spiro T. G.', 'year': '1970'} / Progress in Inorganic Chemistry by Spiro T. G. (1970)

Dates

Type	When
Created	14 years, 11 months ago (Sept. 13, 2010, 11:58 p.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 2:19 p.m.)
Indexed	1 year, 1 month ago (July 8, 2024, 3:49 a.m.)
Issued	52 years, 8 months ago (Jan. 1, 1973)
Published	52 years, 8 months ago (Jan. 1, 1973)
Published Online	15 years ago (Sept. 2, 2010)
Published Print	52 years, 8 months ago (Jan. 1, 1973)

Funders 0

None

BibTeX

@article{Okkersen_1973, title={Pyrazoles and imidazoles as ligands. Part xviii: Neutral and anionic pyrazole coordinated to Cu(I) and Ag(I)}, volume={92}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19730920903}, DOI={10.1002/recl.19730920903}, number={9}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Okkersen, H. and Groeneveld, W. L. and Reedijk, J.}, year={1973}, month=jan, pages={945–953} }

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