DOI: 10.1002/recl.19690880912. A semi‐empirical energy‐level diagram for octahedral cobalt(II) complexes

A semi‐empirical energy‐level diagram for octahedral cobalt(II) complexes

10.1002/recl.19690880912

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractMethods of calculation for the parameters Dq and B from the ligand‐field spectra of octahedral cobalt(II) compounds are discussed. A method of calculation is introduced, which considers the lowering of the 4T1g (F) state by spin‐orbit splitting. This calculation is applied to the spectra of 43 octahedrally coordinated cobalt(II) compounds.With the aid of the spectral data an energy‐level diagram is constructed, into which the absorption bands are fitted.Comparison of calculated Dq and B values with corresponding values for isomorphous nickel(II) compounds shows that ‐ in general ‐ the crystalfield parameter Dq is highest for cobalt, although the differences with nickel are less than 4 % in most cases. The calculated B values corresponds with those of Ni, with differences less than 1 % for many ligands.

Bibliography

Reedijk, J., Driessen, W. L., & Groeneveld, W. L. (1969). A semiâempirical energyâlevel diagram for octahedral cobalt(II) complexes. Recueil Des Travaux Chimiques Des Pays-Bas, 88(9), 1095â1109. Portico.

Authors 3

J. Reedijk (first)
W. L. Driessen (additional)
W. L. Groeneveld (additional)

References 43 Referenced 156

{'key': 'e_1_2_1_1_2', 'volume-title': 'Absorption Spectra and Chemical Bonding in Complexes', 'author': 'Jørgensen C. K.', 'year': '1962'} / Absorption Spectra and Chemical Bonding in Complexes by Jørgensen C. K. (1962)
10.1021/j100800a038
{'key': 'e_1_2_1_3_2', 'volume-title': 'Introduction to Ligand Field Theory', 'author': 'Ballhausen C. J.', 'year': '1962'} / Introduction to Ligand Field Theory by Ballhausen C. J. (1962)
10.1143/JPSJ.9.753
{'key': 'e_1_2_1_5_2', 'volume-title': 'Modern Coordination Chemistry', 'author': 'Dunn T. M.', 'year': '1964'} / Modern Coordination Chemistry by Dunn T. M. (1964)
{'key': 'e_1_2_1_6_2', 'first-page': '8', 'volume-title': 'Structure and Bonding', 'author': 'Jørgensen C. K.', 'year': '1966'} / Structure and Bonding by Jørgensen C. K. (1966)
10.1002/recl.19680870203
10.1021/ed045p711
10.1016/0022-1902(66)80394-9
10.1002/hlca.19630460603
10.1021/ic50002a017
10.1016/S0020-1693(00)93150-5
10.1021/ic50061a021
10.1002/zaac.19683590513
10.1021/ic50058a030
10.1016/0022-1902(68)80447-6
10.1021/ic50067a027
10.1098/rspa.1951.0063
{'key': 'e_1_2_1_19_2', 'volume-title': 'Introduction to Ligand Fields', 'author': 'Figgis B. N.', 'year': '1966'} / Introduction to Ligand Fields by Figgis B. N. (1966)
{'key': 'e_1_2_1_19_3', 'first-page': '2086', 'author': 'Figgis B. N.', 'journal-title': 'J. Chem. Soc.'} / J. Chem. Soc. by Figgis B. N.
{'key': 'e_1_2_1_20_2', 'first-page': '318', 'volume-title': 'Inorganic Electronic Spectroscopy', 'author': 'Lever A. B. P.', 'year': '1968'} / Inorganic Electronic Spectroscopy by Lever A. B. P. (1968)
P. W. N. M.van Leeuwen Thesis Leiden 1967.
10.1063/1.1734387
10.1103/PhysRev.109.256
{'key': 'e_1_2_1_24_2', 'first-page': '1247', 'volume': '86', 'author': 'van Leeuwen P. W. N. M.', 'year': '1967', 'journal-title': 'Rec. Trav. Chim.'} / Rec. Trav. Chim. by van Leeuwen P. W. N. M. (1967)
10.1002/recl.19670861107
10.1002/recl.19680870114
10.1002/recl.19680870706
10.1002/recl.19690880414
D.KnetschandW. L.Groeneveld to be published.
10.1021/ja01497a003
{'key': 'e_1_2_1_31_2', 'first-page': '950', 'author': 'Nicholls D.', 'journal-title': 'J. Chem. Soc.'} / J. Chem. Soc. by Nicholls D.
10.1016/S0020-1693(00)92493-9
10.1002/recl.19690880415
A. G.HinzeandW. L.Groeneveld Rec. Trav. Chim. in the press.
10.1002/recl.19690880604
M. W. G.de BolsterandW. L.Groeneveld to be published.
10.1002/recl.19690880914
10.1002/recl.19690880811
H.NieuwenhuyseandJ.Reedijk to be published.
A. P.ZuurandJ.Reedijk to be published.
C. A. A.van DrielandW. L.Groeneveld to be published.
10.1021/ic50039a034

Dates

Type	When
Created	14 years, 11 months ago (Sept. 14, 2010, 12:16 a.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 3:12 p.m.)
Indexed	1 year, 2 months ago (June 6, 2024, 6 p.m.)
Issued	56 years, 7 months ago (Jan. 1, 1969)
Published	56 years, 7 months ago (Jan. 1, 1969)
Published Online	14 years, 11 months ago (Sept. 2, 2010)
Published Print	56 years, 7 months ago (Jan. 1, 1969)

Funders 0

None

BibTeX

@article{Reedijk_1969, title={A semi‐empirical energy‐level diagram for octahedral cobalt(II) complexes}, volume={88}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19690880912}, DOI={10.1002/recl.19690880912}, number={9}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Reedijk, J. and Driessen, W. L. and Groeneveld, W. L.}, year={1969}, month=jan, pages={1095–1109} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        6,
        6
      ]
    ],
    "date-time": "2024-06-06T22:00:34Z",
    "timestamp": 1717711234596
  },
  "reference-count": 43,
  "publisher": "Wiley",
  "issue": "9",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2010,
            9,
            2
          ]
        ],
        "date-time": "2010-09-02T00:00:00Z",
        "timestamp": 1283385600000
      },
      "content-version": "vor",
      "delay-in-days": 15219,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1969,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Methods of calculation for the parameters Dq and B from the ligand\u2010field spectra of octahedral cobalt(II) compounds are discussed. A method of calculation is introduced, which considers the lowering of the <jats:sup>4</jats:sup><jats:italic>T</jats:italic><jats:sub>1<jats:italic>g</jats:italic></jats:sub> (<jats:italic>F</jats:italic>) state by spin\u2010orbit splitting. This calculation is applied to the spectra of 43 octahedrally coordinated cobalt(II) compounds.</jats:p><jats:p>With the aid of the spectral data an energy\u2010level diagram is constructed, into which the absorption bands are fitted.</jats:p><jats:p>Comparison of calculated Dq and B values with corresponding values for isomorphous nickel(II) compounds shows that \u2010 in general \u2010 the crystalfield parameter Dq is highest for cobalt, although the differences with nickel are less than 4 % in most cases. The calculated B values corresponds with those of Ni, with differences less than 1 % for many ligands.</jats:p>",
  "DOI": "10.1002/recl.19690880912",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2010,
        9,
        14
      ]
    ],
    "date-time": "2010-09-14T04:16:12Z",
    "timestamp": 1284437772000
  },
  "page": "1095-1109",
  "source": "Crossref",
  "is-referenced-by-count": 156,
  "title": "A semi\u2010empirical energy\u2010level diagram for octahedral cobalt(II) complexes",
  "prefix": "10.1002",
  "volume": "88",
  "author": [
    {
      "given": "J.",
      "family": "Reedijk",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "W. L.",
      "family": "Driessen",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "W. L.",
      "family": "Groeneveld",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2010,
        9,
        2
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_1_2",
      "volume-title": "Absorption Spectra and Chemical Bonding in Complexes",
      "author": "J\u00f8rgensen C. K.",
      "year": "1962"
    },
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100800a038"
    },
    {
      "key": "e_1_2_1_3_2",
      "volume-title": "Introduction to Ligand Field Theory",
      "author": "Ballhausen C. J.",
      "year": "1962"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1143/JPSJ.9.753"
    },
    {
      "key": "e_1_2_1_5_2",
      "volume-title": "Modern Coordination Chemistry",
      "author": "Dunn T. M.",
      "year": "1964"
    },
    {
      "key": "e_1_2_1_6_2",
      "first-page": "8",
      "volume-title": "Structure and Bonding",
      "author": "J\u00f8rgensen C. K.",
      "year": "1966"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19680870203"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ed045p711"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-1902(66)80394-9"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/hlca.19630460603"
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50002a017"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)93150-5"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50061a021"
    },
    {
      "key": "e_1_2_1_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/zaac.19683590513"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50058a030"
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-1902(68)80447-6"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50067a027"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1098/rspa.1951.0063"
    },
    {
      "key": "e_1_2_1_19_2",
      "volume-title": "Introduction to Ligand Fields",
      "author": "Figgis B. N.",
      "year": "1966"
    },
    {
      "key": "e_1_2_1_19_3",
      "first-page": "2086",
      "author": "Figgis B. N.",
      "journal-title": "J. Chem. Soc."
    },
    {
      "key": "e_1_2_1_20_2",
      "first-page": "318",
      "volume-title": "Inorganic Electronic Spectroscopy",
      "author": "Lever A. B. P.",
      "year": "1968"
    },
    {
      "key": "e_1_2_1_21_2",
      "unstructured": "P. W. N. M.van Leeuwen Thesis Leiden 1967."
    },
    {
      "key": "e_1_2_1_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1734387"
    },
    {
      "key": "e_1_2_1_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRev.109.256"
    },
    {
      "key": "e_1_2_1_24_2",
      "first-page": "1247",
      "volume": "86",
      "author": "van Leeuwen P. W. N. M.",
      "year": "1967",
      "journal-title": "Rec. Trav. Chim."
    },
    {
      "key": "e_1_2_1_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19670861107"
    },
    {
      "key": "e_1_2_1_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19680870114"
    },
    {
      "key": "e_1_2_1_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19680870706"
    },
    {
      "key": "e_1_2_1_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19690880414"
    },
    {
      "key": "e_1_2_1_29_2",
      "unstructured": "D.KnetschandW. L.Groeneveld to be published."
    },
    {
      "key": "e_1_2_1_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01497a003"
    },
    {
      "key": "e_1_2_1_31_2",
      "first-page": "950",
      "author": "Nicholls D.",
      "journal-title": "J. Chem. Soc."
    },
    {
      "key": "e_1_2_1_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)92493-9"
    },
    {
      "key": "e_1_2_1_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19690880415"
    },
    {
      "key": "e_1_2_1_34_2",
      "unstructured": "A. G.HinzeandW. L.Groeneveld Rec. Trav. Chim. in the press."
    },
    {
      "key": "e_1_2_1_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19690880604"
    },
    {
      "key": "e_1_2_1_36_2",
      "unstructured": "M. W. G.de BolsterandW. L.Groeneveld to be published."
    },
    {
      "key": "e_1_2_1_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19690880914"
    },
    {
      "key": "e_1_2_1_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/recl.19690880811"
    },
    {
      "key": "e_1_2_1_39_2",
      "unstructured": "H.NieuwenhuyseandJ.Reedijk to be published."
    },
    {
      "key": "e_1_2_1_40_2",
      "unstructured": "A. P.ZuurandJ.Reedijk to be published."
    },
    {
      "key": "e_1_2_1_41_2",
      "unstructured": "C. A. A.van DrielandW. L.Groeneveld to be published."
    },
    {
      "key": "e_1_2_1_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50039a034"
    }
  ],
  "container-title": "Recueil des Travaux Chimiques des Pays-Bas",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frecl.19690880912",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/recl.19690880912",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        11,
        13
      ]
    ],
    "date-time": "2023-11-13T20:12:05Z",
    "timestamp": 1699906325000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/recl.19690880912"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1969,
        1
      ]
    ]
  },
  "references-count": 43,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          1969,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/recl.19690880912"
  ],
  "URL": "http://dx.doi.org/10.1002/recl.19690880912",
  "relation": {},
  "ISSN": [
    "0165-0513",
    "0165-0513"
  ],
  "subject": [],
  "container-title-short": "Recl. Trav. Chim. Pays\u2010Bas",
  "published": {
    "date-parts": [
      [
        1969,
        1
      ]
    ]
  }
}