DOI: 10.1002/recl.19690880611. Chemistry and spectroscopy in strongly acidic solutions. Part XXIII: Reversible reaction between carbonium ions and hydrogen

Chemistry and spectroscopy in strongly acidic solutions. Part XXIII: Reversible reaction between carbonium ions and hydrogen

10.1002/recl.19690880611

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractThe reduction of aliphatic carbonium ions to alkanes with molecular hydrogen is reported. A kinetic study of this reaction has been made in the two‐phase solvent system HFFreon 113. The following parameters were investigated: temperature, hydrogen pressure, deuterium isotope effect and structure of the carbonium ion.The kinetics of the reverse reaction ‐ formation of carbonium ions from alkanes and protons in the system HF‐SbF5 ‐ were studied for the case of trimethylcarbonium ion. From the equilibrium constant an upper limit for the basicity of isobutene has been calculated.

Bibliography

Hogeveen, H., Gaasbeek, C. J., & Bickel, A. F. (1969). Chemistry and spectroscopy in strongly acidic solutions. Part XXIII: Reversible reaction between carbonium ions and hydrogen. Recueil Des Travaux Chimiques Des Pays-Bas, 88(6), 703â718. Portico.

Authors 3

H. Hogeveen (first)
C.J. Gaasbeek (additional)
A.F. Bickel (additional)

References 20 Referenced 49

A.F.Bickel C.J.Gaasbeek H.Hogeveen J.M.OelderikandJ.C.Platteeuw Chem. Commun.1967 634. (10.1039/c19670000634)
The reduction of pentamethylbenzyl cation with molecular hydrogen has been reported some years ago byH.M.Buck Mrs.M.J.v. d. Sluys H.P.J.M.Dekkers H.H.BrongersmaandL.J.Oosterhoff Tetrahedron Letters1964 2987.
10.1002/recl.19670861206
10.1021/ja00985a039
10.1021/ja01006a600
10.1021/ja01012a066
H.HogeveenandA.F.Bickel Chem. Commun.1967 635. (10.1039/c19670000635)
10.1002/recl.19680870311
Dr.J.M.Oelderik unpublished results.
10.1002/recl.19680870614
10.1002/recl.19680870212
10.1021/ja01205a519
10.1021/ja01149a098
C.D.Nenitzescu M.M.AvramandE.SliamBull. Soc. Chim. France1955 1266.
10.1039/tf9585400186
aC.MacleanandE.L.Mackor Proceedings of the XIth Colloque Ampère Eindhoven 1962 p.571.
10.1021/ja01601a014
10.1002/recl.19680870213
10.1002/9780470171813.ch3
10.1021/ja01530a059

Dates

Type	When
Created	14 years, 11 months ago (Sept. 14, 2010, 12:17 a.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 2:33 p.m.)
Indexed	1 year, 9 months ago (Nov. 24, 2023, 9:36 a.m.)
Issued	56 years, 8 months ago (Jan. 1, 1969)
Published	56 years, 8 months ago (Jan. 1, 1969)
Published Online	15 years ago (Sept. 2, 2010)
Published Print	56 years, 8 months ago (Jan. 1, 1969)

Funders 0

None

BibTeX

@article{Hogeveen_1969, title={Chemistry and spectroscopy in strongly acidic solutions. Part XXIII: Reversible reaction between carbonium ions and hydrogen}, volume={88}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19690880611}, DOI={10.1002/recl.19690880611}, number={6}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Hogeveen, H. and Gaasbeek, C.J. and Bickel, A.F.}, year={1969}, month=jan, pages={703–718} }

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