Abstract
AbstractSo far no members of the group of coordination compounds in which PCl3 acts as a donor molecule have been investigated crystallographically, although many such compounds are known to exist. We have studied the structure of a relatively simple representative of this group, AuCl·PCl3. Univalent gold is always found to have a linear coordination, even when the analogous copper and silver complexes show a tetrahedral coordination of the metal atom. AuCl·PCl3 is no exception and also shows a linear configuration at the gold atom.
References
4
Referenced
22
- See for exampleH.LipsonandW.Cochran “The Determination of Crystal Structures” 1953 pages175and221.
10.1107/S0365110X55002508
{'key': 'e_1_2_1_3_2', 'volume-title': 'Tables of Interatomic Distances', 'year': '1958'}
/ Tables of Interatomic Distances (1958){'key': 'e_1_2_1_4_2', 'volume': '17', 'author': 'Lindqvist I.', 'year': '1960', 'journal-title': 'Nova Acta Regiae Soc. Sci. Upsaliensis (4)'}
/ Nova Acta Regiae Soc. Sci. Upsaliensis (4) by Lindqvist I. (1960)
Dates
Type | When |
---|---|
Created | 14 years, 11 months ago (Sept. 14, 2010, 12:59 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 7, 2023, 2:11 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 21, 2024, 8:43 a.m.) |
Issued | 63 years, 8 months ago (Jan. 1, 1962) |
Published | 63 years, 8 months ago (Jan. 1, 1962) |
Published Online | 15 years ago (Sept. 2, 2010) |
Published Print | 63 years, 8 months ago (Jan. 1, 1962) |
@article{Arai_1962, title={The structure of AuCl.PCl3}, volume={81}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19620810408}, DOI={10.1002/recl.19620810408}, number={4}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Arai, Gerda J.}, year={1962}, month=jan, pages={307–312} }