DOI: 10.1002/recl.19560751107. The energetics of highly charged spherical micelles as applied to sodium lauryl sulphate

The energetics of highly charged spherical micelles as applied to sodium lauryl sulphate

10.1002/recl.19560751107

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractThe electrical free energy of micelle formation is treated for spherical micelles with a Gouy type double layer, allowing for high surface charge. Use is made of double layer computations carried out by Hoskin for spherical particles with high surface potential. A procedure is developed for interpolating between Hoskin's results. A correction is applied for the difference between the smeared out surface charge as in the model calculations and the actual assembly of discrete charges.From the equilibrium equation for micellization in which this electrical free energy occurs together with terms depending on the concentrations of free ions and of micelles the non‐electrical part of the standard free energy of micelle formation (W‐TΔSo) can be calculated.The method is applied to micelles of sodium lauryl sulphate in aqueous sodium chloride solutions. In this system W‐TΔSo is found to be nearly independent of micelle size and slightly above 1 kT per carbon atom in the chain. Comparison with other data on the free energy change in the transfer of aliphatic chains from water to non‐polar surroundings shows excellent agreement.

Bibliography

Overbeek, J. Th. G., & Stigter, D. (1956). The energetics of highly charged spherical micelles as applied to sodium lauryl sulphate. Recueil Des Travaux Chimiques Des Pays-Bas, 75(11), 1263â1284. Portico.

Authors 2

J. Th. G. Overbeek (first)
D. Stigter (additional)

References 21 Referenced 31

10.1002/recl.19540730713
10.1111/j.1749-6632.1949.tb27293.x
10.1021/j150488a006
10.1246/bcsj.27.73
W.Prins Studies on some long‐chain sodium alkyl‐1 sulfates Thesis Leyden 1955.
{'key': 'e_1_2_1_6_2', 'first-page': '38', 'volume-title': 'The Physical Chemistry of Electrolytic Solutions', 'author': 'Harned H. S.', 'year': '1950'} / The Physical Chemistry of Electrolytic Solutions by Harned H. S. (1950)
{'key': 'e_1_2_1_7_2', 'first-page': '78', 'volume-title': 'Theory of the Stability of Lyophobic Colloids', 'author': 'Verwey E. J. W.', 'year': '1948'} / Theory of the Stability of Lyophobic Colloids by Verwey E. J. W. (1948)
10.1039/tf9534901471
10.1021/j150523a014
10.1063/1.1750534
10.1039/TF9555100728
10.1021/j150526a012
10.1021/j150526a013
{'key': 'e_1_2_1_14_2', 'first-page': '360', 'volume-title': 'The Psysical Chemistry of Electrolytic Solutions', 'author': 'Harned H. S.', 'year': '1950'} / The Psysical Chemistry of Electrolytic Solutions by Harned H. S. (1950)
10.1002/recl.19540730802
{'issue': '9', 'key': 'e_1_2_1_16_2', 'author': 'Lamm O.', 'year': '1944', 'journal-title': 'Arkiv Kemi Mineral Geol.'} / Arkiv Kemi Mineral Geol. by Lamm O. (1944)
10.1016/0095-8522(54)90067-7
10.1246/bcsj.26.101
H.Reerink Private communication.
10.1039/tf9555100561
10.1007/978-3-642-52803-3

Dates

Type	When
Created	14 years, 11 months ago (Sept. 14, 2010, 1:27 a.m.)
Deposited	1 year, 10 months ago (Oct. 7, 2023, 1:23 p.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 12:37 p.m.)
Issued	69 years, 7 months ago (Jan. 1, 1956)
Published	69 years, 7 months ago (Jan. 1, 1956)
Published Online	14 years, 11 months ago (Sept. 2, 2010)
Published Print	69 years, 7 months ago (Jan. 1, 1956)

Funders 0

None

BibTeX

@article{Overbeek_1956, title={The energetics of highly charged spherical micelles as applied to sodium lauryl sulphate}, volume={75}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19560751107}, DOI={10.1002/recl.19560751107}, number={11}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Overbeek, J. Th. G. and Stigter, D.}, year={1956}, month=jan, pages={1263–1284} }

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