Abstract
AbstractIt is already well known that in a number of cases polyvalent chlorides and oxychlorides are able to form quite stable complexes. It was, however, not clear what influences determine the formation of these complexes, and we therefore made a number of investigations for the purpose of getting some insight into the properties of these chlorides and the reaction mechanism of complex formation. It is thought that polyvalent chlorides and oxychlorides behave in fundamentally different ways, the former forming complexes by a Cl− ion donor mechanism, the latter predominantly by dipole interaction.
References
15
Referenced
19
- W. L.Groeneveld On Chloro‐… onium Compounds. Proceedings of the Symposium on Co‐ordination Chemistry (Copenhagen1954)140.
10.1002/recl.19520711114
10.1002/recl.19530720711
- W. L.Groeneveld thesis Leyden1953.
10.1021/ja01143a542
10.1002/recl.19540730907
- H.Houtgraaf thesis Amsterdam1954.
- Sidgwick Chemical Elements and Their Compounds.Gmelin Handbuch der Anorg. Chem.
- W. L.Groeneveld not yet published.
- Only PCl4+. VCl5−.
10.1002/zaac.19512660608
- In fact an incomplete double decomposition takes place: formation of POCl3instead of P2O5.
10.1002/zaac.19522700115
10.1007/BF00900447
- W. L.Groeneveld: to be published.
Dates
Type | When |
---|---|
Created | 14 years, 11 months ago (Sept. 14, 2010, 1:31 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 19, 2023, 12:14 p.m.) |
Indexed | 1 year, 9 months ago (Nov. 24, 2023, 12:20 a.m.) |
Issued | 69 years, 8 months ago (Jan. 1, 1956) |
Published | 69 years, 8 months ago (Jan. 1, 1956) |
Published Online | 15 years ago (Sept. 2, 2010) |
Published Print | 69 years, 8 months ago (Jan. 1, 1956) |
@article{Groeneveld_1956, title={Contribution to complex formation with polyvalent chlorides and oxychlorides}, volume={75}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19560750516}, DOI={10.1002/recl.19560750516}, number={5}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Groeneveld, W. L.}, year={1956}, month=jan, pages={594–602} }