DOI: 10.1002/recl.19490681204. Visible light and x‐ray scattering by concentrated solutions of macromolecules

Visible light and x‐ray scattering by concentrated solutions of macromolecules

10.1002/recl.19490681204

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractThe problem of X‐ray scattering by macromolecules in solution is identical with that for visible light if the relative visible index of refraction of the particles is near unity. The theory of the angular distribution and decrease of transmission due to scattering by independent particles of various shapes and sizes is outlined. For a system of non‐independent particles, the interparticle interferences of the scattered wavelets must also be considered. The Zernike and Prins expression for spherically symmetric distributions is applied to a dilute system of hard spheres and to the Kirkwood idealized liquid of hard spheres. The role of repulsive forces is considered and the correlation between the angular distribution of scattering and the osmotic pressure of the system is indicated. An extension of the theory to non‐spherically symmetric systems such as concentrated solutions of elongated particles is suggested. Applications are made to solutions of the rod‐shaped tobacco mosaic virus. A theory of the two‐phase formation of solutions of the virus is presented and evidence of the existence of three‐dimensional virus crystals in a 2.5% solution of tobacco mosaic virus is given.

Bibliography

Oster, G. (1949). Visible light and xâray scattering by concentrated solutions of macromolecules. Recueil Des Travaux Chimiques Des Pays-Bas, 68(12), 1123â1136. Portico.

Authors 1

Gerald Oster (first)

References 39 Referenced 24

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Dates

Type	When
Created	14 years, 11 months ago (Sept. 14, 2010, 2:10 a.m.)
Deposited	1 year, 10 months ago (Oct. 6, 2023, 10:39 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 9:57 a.m.)
Issued	76 years, 8 months ago (Jan. 1, 1949)
Published	76 years, 8 months ago (Jan. 1, 1949)
Published Online	15 years ago (Sept. 2, 2010)
Published Print	76 years, 8 months ago (Jan. 1, 1949)

Funders 0

None

BibTeX

@article{Oster_1949, title={Visible light and x‐ray scattering by concentrated solutions of macromolecules}, volume={68}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19490681204}, DOI={10.1002/recl.19490681204}, number={12}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Oster, Gerald}, year={1949}, month=jan, pages={1123–1136} }

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