DOI: 10.1002/recl.19410600202. The entropy of liquid mixtures: I. The theory of Raoult's Law

The entropy of liquid mixtures: I. The theory of Raoult's Law

10.1002/recl.19410600202

Crossref journal-article

Wiley

Recueil des Travaux Chimiques des Pays-Bas (311)

Abstract

AbstractRaoult's law for dilute solutions is derived theoretically from a model of the liquid state by the use of statistical mechanics. This method seems to be better adapted to the problem than Planck's method. It is shown that the decrease of the molecular potential of the solvent is caused by the fact that the number of configurations of the mixture contains factors originating from the solute molecules and proportional to the number of solvent molecules. When every solute molecule contributes one such factor, the mixture obeys Raoult's law in great dilution.

Bibliography

Staverman, A. J., & van Santen, J. H. (1941). The entropy of liquid mixtures: I. The theory of Raoultâs Law. Recueil Des Travaux Chimiques Des Pays-Bas, 60(2), 76â84. Portico.

Authors 2

A. J. Staverman (first)
J. H. van Santen (additional)

References 21 Referenced 84

10.1515/zpch-1938-4004 / Z. physik. Chem. B. by Fredenhagen K. (1938)
{'key': 'e_1_2_1_1_3', 'first-page': '313', 'volume': '46', 'year': '1940', 'journal-title': 'Z. physik. Chem. B.'} / Z. physik. Chem. B. (1940)
{'key': 'e_1_2_1_1_4', 'first-page': '291', 'volume': '47', 'year': '1940', 'journal-title': 'Z. physik. Chem. B.'} / Z. physik. Chem. B. (1940)
10.1515/zpch-1939-18435 / Z. physik. Chem. A. by Frahm H. (1939)
{'key': 'e_1_2_1_3_2', 'first-page': '566', 'volume': '36', 'author': 'Wohl K.', 'year': '1935', 'journal-title': 'Physik. Z.'} / Physik. Z. by Wohl K. (1935)
M.Planck Vorlesungen über Thermodynamik(1930). (10.1515/9783112337325)
{'key': 'e_1_2_1_5_2', 'first-page': '194', 'volume': '36', 'author': 'Fredenhagen K.', 'year': '1935', 'journal-title': 'Physik. Z.'} / Physik. Z. by Fredenhagen K. (1935)
{'key': 'e_1_2_1_5_3', 'first-page': '317', 'volume': '39', 'year': '1938', 'journal-title': 'Physik. Z.'} / Physik. Z. (1938)
10.1098/rspa.1932.0027
10.1098/rspa.1935.0020
{'key': 'e_1_2_1_7_3', 'volume-title': 'Statistical Mechanics', 'author': 'Fowler R. H.', 'year': '1936'} / Statistical Mechanics by Fowler R. H. (1936)
10.1021/cr60064a007
{'key': 'e_1_2_1_9_2', 'first-page': '3', 'author': 'Prins J. A.', 'year': '1936', 'journal-title': 'Physica'} / Physica by Prins J. A. (1936)
R. H.FowlerandG. S.Rushbrooke Trans. Faraday Soc.1937.1272. (10.1039/tf9373301272)
10.1002/hlca.19350180139
10.1002/recl.19380570912
{'key': 'e_1_2_1_13_2', 'volume-title': 'Solubility', 'author': 'Hildebrand J. H.', 'year': '1936'} / Solubility by Hildebrand J. H. (1936)
{'key': 'e_1_2_1_14_2', 'first-page': '317', 'volume': '39', 'author': 'Fredenhagen K.', 'year': '1938', 'journal-title': 'Physik. Z.'} / Physik. Z. by Fredenhagen K. (1938)
10.1007/BF01428306
10.1515/zpch-1939-4429 / Z. physik. Chem. by Meyer K. H. (1939)
10.1002/bbpc.19360421010

Dates

Type	When
Created	14 years, 11 months ago (Sept. 14, 2010, 2:43 a.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 5:58 p.m.)
Indexed	2 months, 3 weeks ago (June 3, 2025, 12:45 p.m.)
Issued	84 years, 7 months ago (Jan. 1, 1941)
Published	84 years, 7 months ago (Jan. 1, 1941)
Published Online	14 years, 11 months ago (Sept. 3, 2010)
Published Print	84 years, 7 months ago (Jan. 1, 1941)

Funders 0

None

BibTeX

@article{Staverman_1941, title={The entropy of liquid mixtures: I. The theory of Raoult’s Law}, volume={60}, ISSN={0165-0513}, url={http://dx.doi.org/10.1002/recl.19410600202}, DOI={10.1002/recl.19410600202}, number={2}, journal={Recueil des Travaux Chimiques des Pays-Bas}, publisher={Wiley}, author={Staverman, A. J. and van Santen, J. H.}, year={1941}, month=jan, pages={76–84} }

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