Abstract
AbstractComplexes of the type [crown+M]+ were observed following laser desorption ionization of 18‐crown‐6 molecules ‘doped’ with K+, Cs+, and Ba+. Laser desorption ionization of 15‐crown‐5 and 12‐crown‐4 ‘doped’ with the same metals gave [(crown)]2+[M]+ type sandwich complexes. Binding energies of crown ethers with different metal ions in all such complexes have been estimated from appearance energies obtained in the collisionally‐activated dissociation of the corresponding laster desorbed complexes.
Bibliography
Katritzky, A. R., Malhotra, N., Ramanathan, R., Kemerait, R. C., Zimmerman, J. A., & Eyler, J. R. (1992). Measurement of gasâphase binding energies of crown ethers with metal ions by Fourierâtransform ion cyclotron resonance mass spectrometry. Rapid Communications in Mass Spectrometry, 6(1), 25â27. Portico.
References
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Dates
Type | When |
---|---|
Created | 20 years, 3 months ago (May 29, 2005, 5:34 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 23, 2023, 5:33 p.m.) |
Indexed | 1 year, 7 months ago (Feb. 7, 2024, 9:03 a.m.) |
Issued | 33 years, 8 months ago (Jan. 1, 1992) |
Published | 33 years, 8 months ago (Jan. 1, 1992) |
Published Online | 20 years, 4 months ago (April 8, 2005) |
Published Print | 33 years, 8 months ago (Jan. 1, 1992) |
@article{Katritzky_1992, title={Measurement of gas‐phase binding energies of crown ethers with metal ions by Fourier‐transform ion cyclotron resonance mass spectrometry}, volume={6}, ISSN={1097-0231}, url={http://dx.doi.org/10.1002/rcm.1290060106}, DOI={10.1002/rcm.1290060106}, number={1}, journal={Rapid Communications in Mass Spectrometry}, publisher={Wiley}, author={Katritzky, Alan R. and Malhotra, N. and Ramanathan, R. and Kemerait, R. C. and Zimmerman, Jaffrey A. and Eyler, John R.}, year={1992}, month=jan, pages={25–27} }