DOI: 10.1002/pssb.19690350108. Rotational Structure of Vibronic Absorption and Luminescence Spectra of NO Impurity Molecules in Potassium Halide Crystals

Rotational Structure of Vibronic Absorption and Luminescence Spectra of NO Impurity Molecules in Potassium Halide Crystals

10.1002/pssb.19690350108

Crossref journal-article

Wiley

physica status solidi (b) (311)

Abstract

AbstractThe rotational structure of the pure‐electronic (near 4000 Å) and other zero‐phonon lines associated with v1 and v2 modes is observed in the vibronic spectra of NO ions in KCl and KBr crystals at liquid helium temperature. Three components in the (0, 0) group of the absorption spectrum of KCl‐NO have the intervals 7 and 10 cm−1, the resonant (0, 0) group in emission consists of two components. In the KBr host some components show additional splitting. The rotation of NO in KCl about the top axis a is found to be somewhat hindered in the ground state and nearly free in the excited electronic state. Some emission occurs from thermal nonequilibrium rotational states which gives evidence for rather slow rotation‐phonon relaxation. Several groups of the absorption spectra exhibit rotational perturbations which are suggested to be caused by Coriolis interaction between the vibrations v′1(A1) and v′3(B1).

Bibliography

Avarmaa, R., & Rebane, L. (1969). Rotational Structure of Vibronic Absorption and Luminescence Spectra of NO Impurity Molecules in Potassium Halide Crystals. Physica Status Solidi (b), 35(1), 107â117. Portico.

Authors 2

R. Avarmaa (first)
L. Rebane (additional)

References 22 Referenced 36

{'key': 'e_1_2_1_2_2', 'first-page': '14', 'volume': '37', 'author': 'Rebane L.', 'year': '1968', 'journal-title': 'Trudy IFA Akad. Nauk Est. SSR'} / Trudy IFA Akad. Nauk Est. SSR by Rebane L. (1968)
{'key': 'e_1_2_1_3_2', 'first-page': '118', 'volume': '16', 'author': 'Rebane K.', 'year': '1967', 'journal-title': 'Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem.'} / Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem. by Rebane K. (1967)
{'key': 'e_1_2_1_4_2', 'first-page': '72', 'volume': '17', 'author': 'Rebane L.', 'year': '1968', 'journal-title': 'Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem.'} / Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem. by Rebane L. (1968)
{'key': 'e_1_2_1_5_2', 'first-page': '52', 'volume': '37', 'author': 'Avarmaa R.', 'year': '1968', 'journal-title': 'Trudy IFA Akad. Nauk Est. SSR'} / Trudy IFA Akad. Nauk Est. SSR by Avarmaa R. (1968)
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{'key': 'e_1_2_1_7_2', 'first-page': '78', 'volume': '17', 'author': 'Avarmaa R.', 'year': '1968', 'journal-title': 'Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem.'} / Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem. by Avarmaa R. (1968)
{'key': 'e_1_2_1_8_2', 'first-page': '120', 'volume': '18', 'author': 'Avarmaa R.', 'year': '1969', 'journal-title': 'Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem.'} / Izv. Akad. Nauk Est. SSR, Ser. Fiz. Matem. by Avarmaa R. (1969)
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Dates

Type	When
Created	18 years, 1 month ago (July 9, 2007, 7:16 p.m.)
Deposited	1 year, 11 months ago (Sept. 28, 2023, 9:19 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 9:24 a.m.)
Issued	56 years, 7 months ago (Jan. 1, 1969)
Published	56 years, 7 months ago (Jan. 1, 1969)
Published Online	19 years, 5 months ago (March 30, 2006)
Published Print	56 years, 7 months ago (Jan. 1, 1969)

Funders 0

None

BibTeX

@article{Avarmaa_1969, title={Rotational Structure of Vibronic Absorption and Luminescence Spectra of NO Impurity Molecules in Potassium Halide Crystals}, volume={35}, ISSN={1521-3951}, url={http://dx.doi.org/10.1002/pssb.19690350108}, DOI={10.1002/pssb.19690350108}, number={1}, journal={physica status solidi (b)}, publisher={Wiley}, author={Avarmaa, R. and Rebane, L.}, year={1969}, month=jan, pages={107–117} }

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