DOI: 10.1002/polb.20495. Mechanical properties of the novel organometallic polymer poly(ferrocenyldimethylsilane)

Mechanical properties of the novel organometallic polymer poly(ferrocenyldimethylsilane)

10.1002/polb.20495

Crossref journal-article

Wiley

Journal of Polymer Science Part B: Polymer Physics (311)

Abstract

AbstractA study of the mechanical properties of poly(ferrocenyldimethylsilane) [Fe(η‐C5H4)2SiMe2]n, 3, a novel organometallic polymer, has been performed on thin films of this material. The Young's modulus and Poisson's ratio of film samples (15 × 1 × 1 mm) of 3 were measured in quasi‐static tension using a video extensometer. For 3, the values of the Young's moduli (E) and Poisson's ratios (ν) were similar between axes in the plane and independent of the splicing direction used during sample preparation. The mean and standard deviation of the Young's modulus and Poisson's ratio were 0.78 ± 0.08 GPa and 0.37 ± 0.06 GPa, respectively. Thermomechanical analysis of 3 revealed a steady decrease of E from a room temperature value of approximately 0.70 GPa. Additionally, it was found that at 150 °C, 3 was unable to support even small stresses, consistent with the onset of a melt transition (ca. 135 °C). A mathematical model based on molecular geometry is developed to describe the results. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2280–2288, 2005

Bibliography

Smith, C. W., Tan, K. H., Evans, K. E., Resendes, R., BartoleâScott, A., & Manners, I. (2005). Mechanical properties of the novel organometallic polymer poly(ferrocenyldimethylsilane). Journal of Polymer Science Part B: Polymer Physics, 43(17), 2280â2288. Portico.

Authors 6

Chris W. Smith (first)
Kheng H. Tan (additional)
Ken E. Evans (additional)
Rui Resendes (additional)
Alexandra Bartole‐Scott (additional)
Ian Manners (additional)

References 26 Referenced 4

10.1126/science.1066321
10.1002/9780470166499.ch2
10.1002/3527601686
{'key': 'e_1_2_6_2_5', 'series-title': 'Macromolecules Containing Metal and Metal‐Like Elements', 'author': 'Abd‐El‐Aziz A. S.', 'year': '2004'} / Macromolecules Containing Metal and Metal‐Like Elements by Abd‐El‐Aziz A. S. (2004)
10.1021/ja00041a053
10.1021/ja953805t
10.1021/ja981429h
10.1002/1521-3927(20010701)22:10<711::AID-MARC711>3.0.CO;2-C
10.1021/ma035678o
10.1021/ma9711248
10.1002/(SICI)1521-4095(200003)12:5<327::AID-ADMA327>3.0.CO;2-L
10.1242/jeb.203.19.2933
10.1016/0921-5093(89)90634-5
10.3233/BME-1991-1104
10.1016/0021-9290(70)90055-2
10.1088/0022-3727/22/12/012
10.1007/BF00551939
10.1126/science.235.4792.1038
10.1002/adma.19930050416
10.1007/BF00277087 / J Mater Sci Lett by Neale P. J. (1993)
10.1002/pen.10451
10.1177/0021955X9803400304
{'key': 'e_1_2_6_18_2', 'first-page': '79', 'volume': '18', 'author': 'Smith C. W.', 'year': '1999', 'journal-title': 'Cell Polym'} / Cell Polym by Smith C. W. (1999)
10.1016/S1359-6454(00)00269-X
10.1021/ja962470s
10.1021/ma9816867

Dates

Type	When
Created	20 years, 1 month ago (July 12, 2005, 2:21 p.m.)
Deposited	1 year, 10 months ago (Oct. 8, 2023, 4:30 p.m.)
Indexed	1 year, 9 months ago (Nov. 14, 2023, 3:46 p.m.)
Issued	20 years, 1 month ago (July 12, 2005)
Published	20 years, 1 month ago (July 12, 2005)
Published Online	20 years, 1 month ago (July 12, 2005)
Published Print	20 years ago (Sept. 1, 2005)

Funders 0

None

BibTeX

@article{Smith_2005, title={Mechanical properties of the novel organometallic polymer poly(ferrocenyldimethylsilane)}, volume={43}, ISSN={1099-0488}, url={http://dx.doi.org/10.1002/polb.20495}, DOI={10.1002/polb.20495}, number={17}, journal={Journal of Polymer Science Part B: Polymer Physics}, publisher={Wiley}, author={Smith, Chris W. and Tan, Kheng H. and Evans, Ken E. and Resendes, Rui and Bartole‐Scott, Alexandra and Manners, Ian}, year={2005}, month=jul, pages={2280–2288} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>A study of the mechanical properties of poly(ferrocenyldimethylsilane) [Fe(\u03b7\u2010C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub>SiMe<jats:sub>2</jats:sub>]<jats:sub>n</jats:sub>, <jats:bold>3</jats:bold>, a novel organometallic polymer, has been performed on thin films of this material. The Young's modulus and Poisson's ratio of film samples (15 \u00d7 1 \u00d7 1 mm) of <jats:bold>3</jats:bold> were measured in quasi\u2010static tension using a video extensometer. For <jats:bold>3</jats:bold>, the values of the Young's moduli (<jats:italic>E</jats:italic>) and Poisson's ratios (\u03bd) were similar between axes in the plane and independent of the splicing direction used during sample preparation. The mean and standard deviation of the Young's modulus and Poisson's ratio were 0.78 \u00b1 0.08 GPa and 0.37 \u00b1 0.06 GPa, respectively. Thermomechanical analysis of <jats:bold>3</jats:bold> revealed a steady decrease of <jats:italic>E</jats:italic> from a room temperature value of approximately 0.70 GPa. Additionally, it was found that at 150 \u00b0C, <jats:bold>3</jats:bold> was unable to support even small stresses, consistent with the onset of a melt transition (ca. 135 \u00b0C). A mathematical model based on molecular geometry is developed to describe the results. \u00a9 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2280\u20132288, 2005</jats:p>",
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