DOI: 10.1002/polb.1212. Interaction mechanism of a novel polymer electrolyte composed of poly(acrylonitrile), lithium triflate, and mineral clay

Interaction mechanism of a novel polymer electrolyte composed of poly(acrylonitrile), lithium triflate, and mineral clay

10.1002/polb.1212

Crossref journal-article

Wiley

Journal of Polymer Science Part B: Polymer Physics (311)

Abstract

AbstractThe addition of optimum cetyl pyridium chloride (CPC)–modified montmorillonite (CM) increases the ionic conductivity of poly(acrylonitrile)‐based electrolytes by roughly two orders of magnitude. Specific interactions between the silicate layer, the nitrile group, and the lithium cation were investigated by FTIR, solid‐state NMR, dielectric analyzer, and alternating current impedance. IR and NMR spectra confirm that the negative charges in the silicate layers alter the ionic charge environment of the PAN‐based electrolyte composites, which have the same function as the polar group in PAN. The optimum CM content to achieve the maximum ionic conductivity is 6 phr. However, untreated montmorillonite leads to insignificant polymer intercalation, the negative charges in the silicate layers fail to appreciably disturb the attractive force of the lithium salt, and the resulting conductivity improvement is also less than that of the CM additives. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 2407–2419, 2001

Bibliography

Chen, H., & Chang, F. (2001). Interaction mechanism of a novel polymer electrolyte composed of poly(acrylonitrile), lithium triflate, and mineral clay. Journal of Polymer Science Part B: Polymer Physics, 39(20), 2407â2419. Portico.

Authors 2

Hsien‐Wei Chen (first)
Feng‐Chih Chang (additional)

References 31 Referenced 23

{'key': 'e_1_2_6_2_2', 'first-page': '315', 'volume-title': 'Polymer Electrolyte Reviews', 'author': 'Scrosati B.', 'year': '1989'} / Polymer Electrolyte Reviews by Scrosati B. (1989)
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Dates

Type	When
Created	23 years ago (Aug. 25, 2002, 3:58 p.m.)
Deposited	1 year, 10 months ago (Oct. 9, 2023, 10:06 a.m.)
Indexed	1 year, 7 months ago (Jan. 27, 2024, 7:38 a.m.)
Issued	24 years ago (Aug. 29, 2001)
Published	24 years ago (Aug. 29, 2001)
Published Online	24 years ago (Aug. 29, 2001)
Published Print	23 years, 10 months ago (Oct. 15, 2001)

Funders 0

None

BibTeX

@article{Chen_2001, title={Interaction mechanism of a novel polymer electrolyte composed of poly(acrylonitrile), lithium triflate, and mineral clay}, volume={39}, ISSN={1099-0488}, url={http://dx.doi.org/10.1002/polb.1212}, DOI={10.1002/polb.1212}, number={20}, journal={Journal of Polymer Science Part B: Polymer Physics}, publisher={Wiley}, author={Chen, Hsien‐Wei and Chang, Feng‐Chih}, year={2001}, month=aug, pages={2407–2419} }

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