DOI: 10.1002/pola.24212. Covalent bonded polymer

Covalent bonded polymer–graphene nanocomposites

10.1002/pola.24212

Crossref journal-article

Wiley

Journal of Polymer Science Part A: Polymer Chemistry (311)

Abstract

AbstractThis report describes a new route to covalently bonded polymer–graphene nanocomposites and the subsequent enhancement in thermal and mechanical properties of the resultant nanocomposites. At first, the graphite is oxidized by the modified Hummers method followed by functionalization with Octadecylamine (ODA). The ODA functionalized graphite oxides are reacted with methacryloyl chloride to incorporate polymerizable CC functionality at the nanographene platelet surfaces, which were subsequently employed in in situ polymerization of methylmethacrylate to obtain covalently bonded poly(methyl methacrylate) (PMMA)–graphene nanocomposites. The obtained nanocomposites show significant enhancement in thermal and mechanical properties compared with neat PMMA. Thus, even with 0.5 wt % graphene nanosheets, the Tg increased from 119 °C for neat PMMA to 131 °C for PMMA–graphene nanocomposite, and the respective storage modulus increased from 1.29 to 2 GPa. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4262–4267, 2010

Bibliography

Pramoda, K. P., Hussain, H., Koh, H. M., Tan, H. R., & He, C. B. (2010). Covalent bonded polymerâgraphene nanocomposites. Journal of Polymer Science Part A: Polymer Chemistry, 48(19), 4262â4267. Portico.

Authors 5

K. P. Pramoda (first)
H. Hussain (additional)
H.M. Koh (additional)
H. R. Tan (additional)
C. B. He (additional)

References 23 Referenced 158

10.1023/B:JMSC.0000021439.18202.ea
10.1021/jp9731821
10.1016/j.carbon.2006.06.004
10.1002/adma.200801617
10.1021/ja806499w
10.1021/ja8057327
10.1021/la026525h
10.1126/science.1116994
10.1021/cm010175n
10.1021/ma900845w
10.1002/pola.23802
10.1007/s12274-008-8021-8
10.1039/b919074k
10.1038/nnano.2008.96
10.1002/macp.200800395
Jang J. Y.;Kim M. S.;Lee Y. R.;Cho Y. B.;Anh N. D.;Huong H. T.;Jeong H. M.;Shin C. M.Ifost 2008: Proceeding of the Third International Forum on Strategic Technologies2008 49–52.
10.1002/marc.200900641
10.1039/b919078c
10.1039/b908220d
10.1021/ja01539a017
10.1039/B917103G
10.1021/jp807989b
10.1021/ja076473o

Dates

Type	When
Created	15 years ago (Sept. 3, 2010, 7:13 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 5:53 a.m.)
Indexed	1 month, 2 weeks ago (July 22, 2025, 6:39 a.m.)
Issued	15 years ago (Aug. 24, 2010)
Published	15 years ago (Aug. 24, 2010)
Published Online	15 years ago (Aug. 24, 2010)
Published Print	14 years, 11 months ago (Oct. 1, 2010)

Funders 0

None

BibTeX

@article{Pramoda_2010, title={Covalent bonded polymer–graphene nanocomposites}, volume={48}, ISSN={1099-0518}, url={http://dx.doi.org/10.1002/pola.24212}, DOI={10.1002/pola.24212}, number={19}, journal={Journal of Polymer Science Part A: Polymer Chemistry}, publisher={Wiley}, author={Pramoda, K. P. and Hussain, H. and Koh, H.M. and Tan, H. R. and He, C. B.}, year={2010}, month=aug, pages={4262–4267} }

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