DOI: 10.1002/pola.1995.080330702. Soluble polymer‐supported catalysts containing pendant quaternary onium salts for the addition reaction of oxiranes with carbon dioxide

Soluble polymer‐supported catalysts containing pendant quaternary onium salts for the addition reaction of oxiranes with carbon dioxide

10.1002/pola.1995.080330702

Crossref journal-article

Wiley

Journal of Polymer Science Part A: Polymer Chemistry (311)

Abstract

AbstractThe addition reaction of oxiranes (15a‐d) with carbon dioxide (CO2) was carried out using 1 mol % of soluble polymer‐supported quaternary onium salts as catalysts under atmospheric pressure. The reaction of 15a‐d with CO2 proceeded very smoothly to give the corresponding five‐membered cyclic carbonates (16a‐d) in high yields at 90‐100°C. The catalytic activity of the soluble polymer‐supported quaternary onium salts was strongly affected by the following factors: kind of reaction solvent, degree of introduction of the pendant onium salt residues in the polymer chain, and type of alkyl group on the onium salts due to the balance between lipophilicity and steric hindrance of the onium salt residue. Furthermore, these soluble polymer‐supported quaternary onium salts were found ordinarily to have higher catalytic activity than low molecular weight quaternary onium salts under the same reaction conditions. It was also found that the rate of reaction was proportional both to catalyst concentration and to oxirane concentration. © 1995 John Wiley & Sons, Inc.

Bibliography

Nishikubo, T., Kameyama, A., Yamashita, J., Fukumitsu, T., Maejima, C., & Tomoi, M. (1995). Soluble polymerâsupported catalysts containing pendant quaternary onium salts for the addition reaction of oxiranes with carbon dioxide. Journal of Polymer Science Part A: Polymer Chemistry, 33(7), 1011â1017. Portico.

Authors 6

Tadatomi Nishikubo (first)
Atsushi Kameyama (additional)
Jun Yamashita (additional)
Takahiro Fukumitsu (additional)
Chika Maejima (additional)
Masao Tomoi (additional)

References 21 Referenced 46

10.1021/ja00853a074
10.1021/ja00436a034
10.1021/jo00425a025
10.1021/ja00444a059
10.1002/anie.197904213
10.1039/c39760000394
10.1021/ja00508a033
10.1021/jo00323a029
10.1021/ja00394a021
10.1039/c39760000458
10.1016/S0040-4039(01)86788-5
10.1021/jo00323a029
10.1002/pol.1984.170220403
10.1007/BF00254229 / Polym. Bull. by Capillon J. (1985)
10.1021/jo00295a055
10.1021/ma00216a003
10.1295/polymj.23.1467
10.1002/pola.1993.080310412
10.1295/koron.50.577
{'key': 'e_1_2_1_13_2', 'first-page': '7420', 'volume': '27', 'author': 'Nishikubo T.', 'year': '1994', 'journal-title': 'Macromolecules'} / Macromolecules by Nishikubo T. (1994)
10.1007/BF00798411

Dates

Type	When
Created	22 years, 4 months ago (April 21, 2003, 6:37 a.m.)
Deposited	1 year, 9 months ago (Oct. 26, 2023, 3:36 p.m.)
Indexed	2 weeks, 4 days ago (Aug. 7, 2025, 4:52 a.m.)
Issued	30 years, 3 months ago (May 1, 1995)
Published	30 years, 3 months ago (May 1, 1995)
Published Online	22 years, 5 months ago (March 10, 2003)
Published Print	30 years, 3 months ago (May 1, 1995)

Funders 0

None

BibTeX

@article{Nishikubo_1995, title={Soluble polymer‐supported catalysts containing pendant quaternary onium salts for the addition reaction of oxiranes with carbon dioxide}, volume={33}, ISSN={1099-0518}, url={http://dx.doi.org/10.1002/pola.1995.080330702}, DOI={10.1002/pola.1995.080330702}, number={7}, journal={Journal of Polymer Science Part A: Polymer Chemistry}, publisher={Wiley}, author={Nishikubo, Tadatomi and Kameyama, Atsushi and Yamashita, Jun and Fukumitsu, Takahiro and Maejima, Chika and Tomoi, Masao}, year={1995}, month=may, pages={1011–1017} }

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