DOI: 10.1002/pola.10500. Reversible addition–fragmentation chain‐transfer polymerization: Unambiguous end‐group assignment via electrospray ionization mass spectrometry

Reversible addition–fragmentation chain‐transfer polymerization: Unambiguous end‐group assignment via electrospray ionization mass spectrometry

10.1002/pola.10500

Crossref journal-article

Wiley

Journal of Polymer Science Part A: Polymer Chemistry (311)

Abstract

AbstractElectrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl p‐fluorodithiobenzoate (CPFDB), and 1‐phenylethyl dithiobenzoate (PEDB) mediated reversible addition–fragmentation chain‐transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free‐radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple‐stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4032–4037, 2002

Bibliography

Vana, P., Albertin, L., Barner, L., Davis, T. P., & BarnerâKowollik, C. (2002). Reversible additionâfragmentation chainâtransfer polymerization: Unambiguous endâgroup assignment via electrospray ionization mass spectrometry. Journal of Polymer Science Part A: Polymer Chemistry, 40(22), 4032â4037. Portico.

Authors 5

Philipp Vana (first)
Luca Albertin (additional)
Leonie Barner (additional)
Thomas P. Davis (additional)
Christopher Barner‐Kowollik (additional)

References 31 Referenced 110

{'key': 'e_1_2_6_2_2', 'series-title': 'Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT', 'first-page': '278', 'author': 'Rizzardo E.', 'year': '2000'} / Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT by Rizzardo E. (2000)
10.1021/cr990119u
10.1021/cr9901182
10.1021/cr940534g
10.1002/pola.1256
10.1002/pola.1112
10.1021/ma010349m
10.1071/CH01149
10.1002/pola.10194
10.1021/ma001484m
10.1002/1099-0518(20001101)38:21<3864::AID-POLA30>3.0.CO;2-3
10.1021/ma0009451
10.1002/1099-0518(200012)38:1 <4749::AID-POLA140>3.0.CO;2-D
10.1021/ma0003102
10.1002/pola.10150
10.1002/(SICI)1098-2787(1999)18:5<309::AID-MAS2>3.0.CO;2-L
10.1021/ac9702610
10.1021/cr9901081
10.1016/1044-0305(95)00476-T
10.1039/cc9960001157
10.1002/1097-0231(20001215)14:23<2170::AID-RCM149>3.0.CO;2-S
10.1002/actp.1997.010481201
10.1006/abio.1996.9877
10.1016/S0040-4020(01)93661-0
10.1002/(SICI)1521-3935(19980801)199:8<1721::AID-MACP1721>3.0.CO;2-5
{'key': 'e_1_2_6_27_2', 'first-page': '258', 'volume-title': 'Electrospray Ionization Mass Spectrometry', 'author': 'Bier M. E.', 'year': '1997'} / Electrospray Ionization Mass Spectrometry by Bier M. E. (1997)
10.1016/S0040-4039(00)85234-X
10.1007/BF00811293
{'key': 'e_1_2_6_30_2', 'first-page': '67', 'volume': '132', 'author': 'Carreta F.', 'year': '1995', 'journal-title': 'Bull Soc Chim Fr'} / Bull Soc Chim Fr by Carreta F. (1995)
10.1039/a708244d
We subjected the polymeric material generated by CDB‐mediated polymerization of MA at 80 °C toward MALDI‐TOF analysis (Perseptive Voyager DE STR spectrometer). The resulting spectrum shows multiple peaks within one repeat unit possibly because of complex ionization and fragmentation processes. These observations agree with previously reported spectra obtained via MALDI‐TOF of RAFT polymers.

Dates

Type	When
Created	22 years, 10 months ago (Oct. 9, 2002, 4:40 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 3:18 p.m.)
Indexed	1 year, 1 month ago (July 20, 2024, 3:34 p.m.)
Issued	22 years, 11 months ago (Oct. 3, 2002)
Published	22 years, 11 months ago (Oct. 3, 2002)
Published Online	22 years, 11 months ago (Oct. 3, 2002)
Published Print	22 years, 9 months ago (Nov. 15, 2002)

Funders 0

None

BibTeX

@article{Vana_2002, title={Reversible addition–fragmentation chain‐transfer polymerization: Unambiguous end‐group assignment via electrospray ionization mass spectrometry}, volume={40}, ISSN={1099-0518}, url={http://dx.doi.org/10.1002/pola.10500}, DOI={10.1002/pola.10500}, number={22}, journal={Journal of Polymer Science Part A: Polymer Chemistry}, publisher={Wiley}, author={Vana, Philipp and Albertin, Luca and Barner, Leonie and Davis, Thomas P. and Barner‐Kowollik, Christopher}, year={2002}, month=oct, pages={4032–4037} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        7,
        20
      ]
    ],
    "date-time": "2024-07-20T19:34:57Z",
    "timestamp": 1721504097515
  },
  "reference-count": 31,
  "publisher": "Wiley",
  "issue": "22",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2002,
            10,
            3
          ]
        ],
        "date-time": "2002-10-03T00:00:00Z",
        "timestamp": 1033603200000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2002,
        11,
        15
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Electrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl <jats:italic>p</jats:italic>\u2010fluorodithiobenzoate (CPFDB), and 1\u2010phenylethyl dithiobenzoate (PEDB) mediated reversible addition\u2013fragmentation chain\u2010transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free\u2010radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple\u2010stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers. \u00a9 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4032\u20134037, 2002</jats:p>",
  "DOI": "10.1002/pola.10500",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        10,
        9
      ]
    ],
    "date-time": "2002-10-09T08:40:53Z",
    "timestamp": 1034152853000
  },
  "page": "4032-4037",
  "source": "Crossref",
  "is-referenced-by-count": 110,
  "title": "Reversible addition\u2013fragmentation chain\u2010transfer polymerization: Unambiguous end\u2010group assignment via electrospray ionization mass spectrometry",
  "prefix": "10.1002",
  "volume": "40",
  "author": [
    {
      "given": "Philipp",
      "family": "Vana",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Luca",
      "family": "Albertin",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Leonie",
      "family": "Barner",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Thomas P.",
      "family": "Davis",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Christopher",
      "family": "Barner\u2010Kowollik",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2002,
        10,
        3
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_6_2_2",
      "series-title": "Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT",
      "first-page": "278",
      "author": "Rizzardo E.",
      "year": "2000"
    },
    {
      "key": "e_1_2_6_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr990119u"
    },
    {
      "key": "e_1_2_6_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr9901182"
    },
    {
      "key": "e_1_2_6_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr940534g"
    },
    {
      "key": "e_1_2_6_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pola.1256"
    },
    {
      "key": "e_1_2_6_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pola.1112"
    },
    {
      "key": "e_1_2_6_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma010349m"
    },
    {
      "key": "e_1_2_6_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1071/CH01149"
    },
    {
      "key": "e_1_2_6_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pola.10194"
    },
    {
      "key": "e_1_2_6_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma001484m"
    },
    {
      "key": "e_1_2_6_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1099-0518(20001101)38:21<3864::AID-POLA30>3.0.CO;2-3"
    },
    {
      "key": "e_1_2_6_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma0009451"
    },
    {
      "key": "e_1_2_6_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1099-0518(200012)38:1 <4749::AID-POLA140>3.0.CO;2-D"
    },
    {
      "key": "e_1_2_6_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma0003102"
    },
    {
      "key": "e_1_2_6_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pola.10150"
    },
    {
      "key": "e_1_2_6_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1098-2787(1999)18:5<309::AID-MAS2>3.0.CO;2-L"
    },
    {
      "key": "e_1_2_6_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac9702610"
    },
    {
      "key": "e_1_2_6_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr9901081"
    },
    {
      "key": "e_1_2_6_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/1044-0305(95)00476-T"
    },
    {
      "key": "e_1_2_6_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/cc9960001157"
    },
    {
      "key": "e_1_2_6_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1097-0231(20001215)14:23<2170::AID-RCM149>3.0.CO;2-S"
    },
    {
      "key": "e_1_2_6_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/actp.1997.010481201"
    },
    {
      "key": "e_1_2_6_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/abio.1996.9877"
    },
    {
      "key": "e_1_2_6_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0040-4020(01)93661-0"
    },
    {
      "key": "e_1_2_6_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-3935(19980801)199:8<1721::AID-MACP1721>3.0.CO;2-5"
    },
    {
      "key": "e_1_2_6_27_2",
      "first-page": "258",
      "volume-title": "Electrospray Ionization Mass Spectrometry",
      "author": "Bier M. E.",
      "year": "1997"
    },
    {
      "key": "e_1_2_6_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0040-4039(00)85234-X"
    },
    {
      "key": "e_1_2_6_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00811293"
    },
    {
      "key": "e_1_2_6_30_2",
      "first-page": "67",
      "volume": "132",
      "author": "Carreta F.",
      "year": "1995",
      "journal-title": "Bull Soc Chim Fr"
    },
    {
      "key": "e_1_2_6_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/a708244d"
    },
    {
      "key": "e_1_2_6_32_2",
      "unstructured": "We subjected the polymeric material generated by CDB\u2010mediated polymerization of MA at 80 \u00b0C toward MALDI\u2010TOF analysis (Perseptive Voyager DE STR spectrometer). The resulting spectrum shows multiple peaks within one repeat unit possibly because of complex ionization and fragmentation processes. These observations agree with previously reported spectra obtained via MALDI\u2010TOF of RAFT polymers."
    }
  ],
  "container-title": "Journal of Polymer Science Part A: Polymer Chemistry",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpola.10500",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/pola.10500",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        16
      ]
    ],
    "date-time": "2023-10-16T19:18:17Z",
    "timestamp": 1697483897000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/pola.10500"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2002,
        10,
        3
      ]
    ]
  },
  "references-count": 31,
  "journal-issue": {
    "issue": "22",
    "published-print": {
      "date-parts": [
        [
          2002,
          11,
          15
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/pola.10500"
  ],
  "URL": "http://dx.doi.org/10.1002/pola.10500",
  "relation": {},
  "ISSN": [
    "0887-624X",
    "1099-0518"
  ],
  "subject": [],
  "container-title-short": "J. Polym. Sci. A Polym. Chem.",
  "published": {
    "date-parts": [
      [
        2002,
        10,
        3
      ]
    ]
  }
}