DOI: 10.1002/pol.1968.150060921. Calorimetric investigation of polymerization reactions. I. Diffusion‐controlled polymerization of methyl methacrylate and styrene

Calorimetric investigation of polymerization reactions. I. Diffusion‐controlled polymerization of methyl methacrylate and styrene

10.1002/pol.1968.150060921

Crossref journal-article

Wiley

Journal of Polymer Science Part A-1: Polymer Chemistry (311)

Abstract

AbstractThe rate of bulk polymerization of methyl methacrylate and styrene was determined directly, continuously and over the whole range of conversion with a differential scanning calorimeter (DSC) operated isothermally. At the later stages of the accelerated polymerization of methyl methacrylate, a previously unknown inflection or peak in the rate of polymerization was observed. The variation of the rate after the onset of the gel effect, including this peculiar inflection, was interpreted on the basis of the diffusion behavior of monomer molecules and polymeric radicals in the polymer–monomer system, their diffusion rates being predicted from the free volume theory. The final conversion at which no further polymerization proceeds was determined for both monomers. It was affirmed quantitatively that the final conversion has a close relation with the transition of the polymer–monomer system from a viscous liquid to a glassy state.

Bibliography

Horie, K., Mita, I., & Kambe, H. (1968). Calorimetric investigation of polymerization reactions. I. Diffusionâcontrolled polymerization of methyl methacrylate and styrene. Journal of Polymer Science Part A-1: Polymer Chemistry, 6(9), 2663â2676. Portico.

Authors 3

Kazuyuki Horie (first)
Itaru Mita (additional)
Hirotaro Kambe (additional)

References 35 Referenced 163

10.1002/macp.1947.020010110
10.1002/macp.1948.020010301
10.1002/pol.1960.1204314116
10.1002/pol.1963.100010420
10.1002/macp.1962.020510115
10.1039/tf9524800576
10.1246/bcsj.27.216
10.1039/tf9565200426
10.1002/hlca.6602801218
10.1021/ja00865a011
{'key': 'e_1_2_1_12_2', 'first-page': '883', 'volume': '3', 'author': 'Burkhart R. D.', 'year': '1965', 'journal-title': 'J. Polym. Sci. A'} / J. Polym. Sci. A by Burkhart R. D. (1965)
10.1039/tf9373301225
10.1002/pol.1961.1205015421
10.1039/tf9504600684
10.1039/tf9605600424
10.1039/tf9646000960
10.1002/pol.1966.150040405
10.1021/ac60213a019
10.1246/nikkashi1898.69.9_1808
{'key': 'e_1_2_1_21_2', 'volume-title': 'Tabellen, Kalorische Zustandsgrössen', 'author': 'Landolt‐Börnstein', 'year': '1961'} / Tabellen, Kalorische Zustandsgrössen by Landolt‐Börnstein (1961)
10.1002/pol.1952.120080511
10.1021/ja01128a048
10.1002/pol.1953.120110404
10.1002/pol.1960.1204314101
10.1021/ja01148a081
{'key': 'e_1_2_1_27_2', 'first-page': '87', 'volume-title': 'Reaction Heats and Bond Strengths', 'author': 'Mortimer C. T.', 'year': '1962'} / Reaction Heats and Bond Strengths by Mortimer C. T. (1962)
10.1063/1.1699711
{'key': 'e_1_2_1_29_2', 'first-page': '85', 'volume-title': 'Physical Properties of Polymers', 'author': 'Bueche F.', 'year': '1962'} / Physical Properties of Polymers by Bueche F. (1962)
10.1039/tf9605600744
{'key': 'e_1_2_1_31_2', 'first-page': '1031', 'volume': '63', 'author': 'Chapiro A.', 'year': '1966', 'journal-title': 'J. Chim. Phys.'} / J. Chim. Phys. by Chapiro A. (1966)
10.1021/ja01619a008
10.1021/j100818a081
{'key': 'e_1_2_1_34_2', 'first-page': '1908', 'volume': '8', 'author': 'Chalykh A. E.', 'year': '1966', 'journal-title': 'Vysokomol. Soedin.'} / Vysokomol. Soedin. by Chalykh A. E. (1966)
10.1002/pol.1966.150040914
10.1002/pol.1959.1203412717

Dates

Type	When
Created	22 years, 4 months ago (April 21, 2003, 6:48 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 9:50 a.m.)
Indexed	11 months, 3 weeks ago (Aug. 27, 2024, 5:49 a.m.)
Issued	56 years, 11 months ago (Sept. 1, 1968)
Published	56 years, 11 months ago (Sept. 1, 1968)
Published Online	22 years, 5 months ago (March 10, 2003)
Published Print	56 years, 11 months ago (Sept. 1, 1968)

Funders 0

None

BibTeX

@article{Horie_1968, title={Calorimetric investigation of polymerization reactions. I. Diffusion‐controlled polymerization of methyl methacrylate and styrene}, volume={6}, ISSN={1542-9350}, url={http://dx.doi.org/10.1002/pol.1968.150060921}, DOI={10.1002/pol.1968.150060921}, number={9}, journal={Journal of Polymer Science Part A-1: Polymer Chemistry}, publisher={Wiley}, author={Horie, Kazuyuki and Mita, Itaru and Kambe, Hirotaro}, year={1968}, month=sep, pages={2663–2676} }

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