DOI: 10.1002/poc.1377. Kinetics study of a Diels‐Alder reaction in mixtures of an ionic liquid with molecular solvents

Kinetics study of a Diels‐Alder reaction in mixtures of an ionic liquid with molecular solvents

10.1002/poc.1377

Crossref journal-article

Wiley

Journal of Physical Organic Chemistry (311)

Abstract

AbstractThe second‐order rate constants for cycloaddition reaction of cyclopentadiene with naphthoquinone were determined spectrophotometrically in various compositions of 1‐(1‐butyl)‐3‐methylimidazolium terafluoroborate ([bmim]BF4) with water and methanol at 25 °C. Rate constants of the reaction in pure solvents are in the order of water > [bmim]BF4 > methanol. Rate constants of the reaction decrease sharply with mole fraction of the ionic liquid in aqueous solutions and increase slightly to a maximum in alcoholic mixtures. Multi‐parameter correlation of logk2 versus solute–solvent interaction parameters demonstrated that solvophobicity parameter (Sp), hydrogen‐bond donor acidity (α) and hydrogen‐bond acceptor basicity (β) of media are the main factors influencing the reaction rate constant. The proposed three‐parameter model shows that the reaction rate constant increases with Sp, α and β parameters. Copyright © 2008 John Wiley & Sons, Ltd.

Bibliography

HarifiâMood, A. R., HabibiâYangjeh, A., & Gholami, M. R. (2008). Kinetics study of a DielsâAlder reaction in mixtures of an ionic liquid with molecular solvents. Journal of Physical Organic Chemistry, 21(9), 783â788. Portico.

Authors 3

Ali Reza Harifi‐Mood (first)
Aziz Habibi‐Yangjeh (additional)
Mohammad Reza Gholami (additional)

References 41 Referenced 30

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Dates

Type	When
Created	17 years, 3 months ago (May 29, 2008, 8:17 a.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 6:53 p.m.)
Indexed	1 year, 3 months ago (May 28, 2024, 8:54 p.m.)
Issued	17 years, 3 months ago (May 29, 2008)
Published	17 years, 3 months ago (May 29, 2008)
Published Online	17 years, 3 months ago (May 29, 2008)
Published Print	17 years ago (Sept. 1, 2008)

Funders 0

None

BibTeX

@article{Harifi_Mood_2008, title={Kinetics study of a Diels‐Alder reaction in mixtures of an ionic liquid with molecular solvents}, volume={21}, ISSN={1099-1395}, url={http://dx.doi.org/10.1002/poc.1377}, DOI={10.1002/poc.1377}, number={9}, journal={Journal of Physical Organic Chemistry}, publisher={Wiley}, author={Harifi‐Mood, Ali Reza and Habibi‐Yangjeh, Aziz and Gholami, Mohammad Reza}, year={2008}, month=may, pages={783–788} }

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