DOI: 10.1002/pi.4980010303. Studies of molecular motions and phase transitions in polymers using the rotating frame magnetic resonance method

Studies of molecular motions and phase transitions in polymers using the rotating frame magnetic resonance method

10.1002/pi.4980010303

Crossref journal-article

Wiley

British Polymer Journal (311)

Abstract

AbstractThe concept of the relaxation time in the rotating frame, T1p, is introduced and compared with the more familiar spin‐lattice relaxation time T1. The experimental requirements for measuring T1p are briefly discussed. The relationship between T1 and T1p and molecular correlation times, τc, and activation energies, ΔE, for motions is indicated. T1p data for a number of polymers, i.e. polyethylene oxides, polypropylene oxide, stereoregular forms of polymethyl methacrylate and starch are briefly discussed and compared with other T1p data for polymers in the literature. The advantages of making relaxation measurements in the rotating frame are pointed out and a number of difficulties connected with spin‐diffusion mechanisms and determinations of crystallinity are discussed.

Bibliography

Connor, T. M. (1969). Studies of molecular motions and phase transitions in polymers using the rotating frame magnetic resonance method. British Polymer Journal, 1(3), 116â122. Portico.

Authors 1

T. M. Connor (first)

References 32 Referenced 11

10.1103/PhysRev.135.A1099
10.1103/PhysRev.137.A235
{'key': 'e_1_2_1_4_2', 'first-page': '58', 'volume-title': 'Principles of nuclear magnetism', 'author': 'Abragam A.', 'year': '1961'} / Principles of nuclear magnetism by Abragam A. (1961)
10.1103/PhysRev.128.2042
10.1088/0950-7671/40/5/315
10.1063/1.1718815
10.1063/1.1719357
10.1063/1.1716296
Connor T. M. &Hartland A. J. Polym. Sci. in the press.
10.1088/0950-7671/43/11/417
10.1021/j150556a015
10.1063/1.1730170
10.1103/PhysRev.73.679
10.1103/PhysRev.148.332
10.1039/tf9635901525
10.1016/0032-3861(66)90059-0
10.1016/0032-3861(68)90010-4
Connor T. M. &Blears D. J. in the press.
10.1016/0032-3861(68)90078-5
10.1016/0032-3861(65)90064-9
10.1016/0031-9163(66)90214-9
10.1016/0032-3861(63)90047-8
10.1002/pi.4980010304
10.1002/pol.1968.110061006
10.1002/pol.1968.110060407
10.1039/tf9646001574
10.1063/1.1754231
10.1063/1.1727710
10.1016/0032-3861(63)90056-9
10.1002/pol.1953.120100508
{'issue': '2', 'key': 'e_1_2_1_32_2', 'first-page': '991', 'volume': '5', 'author': 'Blundell D.', 'year': '1967', 'journal-title': 'J. Polym. Sci.'} / J. Polym. Sci. by Blundell D. (1967)
10.1021/j100863a036

Dates

Type	When
Created	18 years, 5 months ago (March 20, 2007, 5:31 p.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 12:26 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 5:21 a.m.)
Issued	56 years, 4 months ago (May 1, 1969)
Published	56 years, 4 months ago (May 1, 1969)
Published Online	18 years, 9 months ago (Dec. 4, 2006)
Published Print	56 years, 4 months ago (May 1, 1969)

Funders 0

None

BibTeX

@article{Connor_1969, title={Studies of molecular motions and phase transitions in polymers using the rotating frame magnetic resonance method}, volume={1}, ISSN={1934-256X}, url={http://dx.doi.org/10.1002/pi.4980010303}, DOI={10.1002/pi.4980010303}, number={3}, journal={British Polymer Journal}, publisher={Wiley}, author={Connor, T. M.}, year={1969}, month=may, pages={116–122} }

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