DOI: 10.1002/pen.760322003. The synthesis and cationic polymerization of novel epoxide monomers

The synthesis and cationic polymerization of novel epoxide monomers

10.1002/pen.760322003

Crossref journal-article

Wiley

Polymer Engineering & Science (311)

Abstract

AbstractThe preparation of a novel series of multifunctional silicon‐containing epoxide monomers, oligomers, and polymers has been carried out. The hydrosilylation method employed was found to be applicable to the design and synthesis of a wide variety of materials with different chemical and mechanical characteristics, which range from hard and brittle to elastomeric. By tailoring the kinds of and number of epoxide groups that are incorporated into these materials, it is possible to substantially modify their reactivity in photoinitiated cationic polymerization. Those monomers and oligomers containing cycloaliphatic epoxide rings undergo polymerization rates considerably more rapid than conventional epoxides. There are many applications of such photocurable monomers in the field of electronic materials.

Bibliography

Crivello, J. V. (1992). The synthesis and cationic polymerization of novel epoxide monomers. Polymer Engineering & Science, 32(20), 1462â1465. Portico.

Authors 1

James V. Crivello (first)

References 10 Referenced 19

{'key': 'e_1_2_1_2_2', 'first-page': '383', 'volume': '56', 'author': 'Crivello J. V.', 'year': '1976', 'journal-title': 'J. Polym. Sci., Polym. Symp.'} / J. Polym. Sci., Polym. Symp. by Crivello J. V. (1976)
{'key': 'e_1_2_1_3_2', 'first-page': '2', 'volume': '4', 'author': 'Crivello J. V.', 'year': '1977', 'journal-title': 'J. Rad. Curing'} / J. Rad. Curing by Crivello J. V. (1977)
{'key': 'e_1_2_1_4_2', 'first-page': '2', 'volume': '17', 'author': 'Crivello J. V.', 'year': '1979', 'journal-title': 'J. Polym. Sci., Polym. Chem. Ed.'} / J. Polym. Sci., Polym. Chem. Ed. by Crivello J. V. (1979)
10.1007/BFb0024034
{'key': 'e_1_2_1_6_2', 'series-title': 'ACS Symp. Ser. 114', 'first-page': '1', 'author': 'Crivello J. V.', 'year': '1978'} / ACS Symp. Ser. 114 by Crivello J. V. (1978)
F.Sitek Soc. Mfg. Eng. Radcure Europe '87 Conference Tech. Paper FC87–274 (1987).
10.1021/je60005a016
10.1021/ja01520a008
10.1002/pola.1990.080280303
{'key': 'e_1_2_1_11_2', 'first-page': '1', 'volume-title': 'UV Curing Science and Technology', 'author': 'Moore J. E.', 'year': '1978'} / UV Curing Science and Technology by Moore J. E. (1978)

Dates

Type	When
Created	20 years, 8 months ago (Dec. 28, 2004, 6:07 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 12:46 p.m.)
Indexed	1 year, 1 month ago (July 3, 2024, 8:40 a.m.)
Issued	32 years, 10 months ago (Oct. 1, 1992)
Published	32 years, 10 months ago (Oct. 1, 1992)
Published Online	21 years ago (Aug. 26, 2004)
Published Print	32 years, 10 months ago (Oct. 1, 1992)

Funders 0

None

BibTeX

@article{Crivello_1992, title={The synthesis and cationic polymerization of novel epoxide monomers}, volume={32}, ISSN={1548-2634}, url={http://dx.doi.org/10.1002/pen.760322003}, DOI={10.1002/pen.760322003}, number={20}, journal={Polymer Engineering & Science}, publisher={Wiley}, author={Crivello, James V.}, year={1992}, month=oct, pages={1462–1465} }

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