DOI: 10.1002/masy.200351413. Electrochemical reduction of carbon dioxide catalyzed by cofacial dinuclear metalloporphyrin

Electrochemical reduction of carbon dioxide catalyzed by cofacial dinuclear metalloporphyrin

10.1002/masy.200351413

Crossref journal-article

Wiley

Macromolecular Symposia (311)

Abstract

AbstractCofacial dinuclear metalloporphyrins exhibited a catalytic activity for the electrochemical reduction of carbon dioxide. The cofacial dinuclear porphyrin was automatically generated by mixing a cationic cobalt porphyrin (CoTMPyP) and an anionic metalloporphyrin (MTPPS) in solution. The redox system of this complex was examined by electrochemical methods. According to the cyclic voltammogram, the catalytic active species was generated at −1.8V vs. Ag/Ag+, which was considered to be a monovalent cobalt porphyrin, Co(I)TMPyP. The catalytic activity of the dinuclear complex was two times greater than that of the mononuclear one because the anionic porphyrin acted as an electron mediator.

Bibliography

Enoki, O., Imaoka, T., & Yamamoto, K. (2003). Electrochemical reduction of carbon dioxide catalyzed by cofacial dinuclear metalloporphyrin. Macromolecular Symposia, 204(1), 151â158. Portico.

Authors 3

Osamu Enoki (first)
Takane Imaoka (additional)
Kimihisa Yamamoto (additional)

References 0 Referenced 21

None

Dates

Type	When
Created	21 years, 8 months ago (Dec. 11, 2003, 6 a.m.)
Deposited	1 year, 11 months ago (Sept. 13, 2023, 10:28 a.m.)
Indexed	11 months, 3 weeks ago (Sept. 9, 2024, 11:17 a.m.)
Issued	21 years, 10 months ago (Nov. 1, 2003)
Published	21 years, 10 months ago (Nov. 1, 2003)
Published Online	21 years, 8 months ago (Dec. 9, 2003)
Published Print	21 years, 10 months ago (Nov. 1, 2003)

Funders 0

None

BibTeX

@article{Enoki_2003, title={Electrochemical reduction of carbon dioxide catalyzed by cofacial dinuclear metalloporphyrin}, volume={204}, ISSN={1521-3900}, url={http://dx.doi.org/10.1002/masy.200351413}, DOI={10.1002/masy.200351413}, number={1}, journal={Macromolecular Symposia}, publisher={Wiley}, author={Enoki, Osamu and Imaoka, Takane and Yamamoto, Kimihisa}, year={2003}, month=nov, pages={151–158} }

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