DOI: 10.1002/masy.19920590123. Preparation of polymer‐protected gold/platinum bimetallic clusters and their application to visible light‐induced hydrogen evolution

Preparation of polymer‐protected gold/platinum bimetallic clusters and their application to visible light‐induced hydrogen evolution

10.1002/masy.19920590123

Crossref journal-article

Wiley

Makromolekulare Chemie. Macromolecular Symposia (311)

Abstract

AbstractThe dispersions of polymer‐protected gold/platinum bimetallic clusters were easily and reproducibly prepared by refluxing the mixed solutions of tetrachloroaureic(III) acid and hexachloroplatinic(IV) acid in ethanol/water (1/1) at 90 ∼ 95 °C for 2 h in the presence of a protective polymer such as poly(N‐vinyl‐2‐pyrrolidone) (PVP). The gold/platinum bimetallic clusters thus obtained were very small, well dispersed and very stable. The UV‐Vis spectra and the transmission electron micrographs have indicated that each bimetallic particle has an alloy structure consisting of both gold and platinum atoms, and that the surface of the cluster particle is rich in platinum atoms and the inner core in gold atoms. The gold/platinum bimetallic clusters were used as the multi‐electron redox catalysts for visible light‐induced hydrogen evolution from water. The rate of hydrogen evolution depended on the mole ratio of the gold/platinum bimetallic clusters. The bimetallic clusters at the mole ratio of Au/Pt = 2/3 were the most active catalyst. The in‐situ UV‐Vis spectra during the reaction have indicated that the order of the aggregation in the two kinds of metal atoms is very important for structure determination of the Au/Pt bimetallic clusters. The protective polymer PVP plays a role not only in protecting hydrophobic colloidal particles in an aqueous solution, but also in determining the metal composition of the cluster surface.

Bibliography

Toshima, N., & Yonezawa, T. (1992). Preparation of polymerâprotected gold/platinum bimetallic clusters and their application to visible lightâinduced hydrogen evolution. Makromolekulare Chemie. Macromolecular Symposia, 59(1), 281â295. Portico.

Authors 2

Naoki Toshima (first)
Tetsu Yonezawa (additional)

References 43 Referenced 30

10.1143/JPSJ.9.359
10.1103/RevModPhys.58.533
10.1021/ja01855a070
10.1016/0166-6622(82)80079-6
{'key': 'e_1_2_1_6_2', 'volume': '633', 'author': 'Hirai H.', 'year': '1979', 'journal-title': 'J.Macromol.Sci.‐Chem. A13'} / J.Macromol.Sci.‐Chem. A13 by Hirai H. (1979)
10.1021/ja00406a004
10.1021/j150662a029
10.1021/j100253a037
10.1126/science.180.4087.745
10.1246/bcsj.58.682
{'key': 'e_1_2_1_12_2', 'first-page': '127', 'volume': '3', 'author': 'Hirai H.', 'year': '1985', 'journal-title': 'Reactive Polym.'} / Reactive Polym. by Hirai H. (1985)
10.1295/koron.46.551
10.1007/978-94-009-5261-4_2
{'key': 'e_1_2_1_15_2', 'volume': '1117', 'author': 'Hirai H.', 'year': '1978', 'journal-title': 'J.Macromol.Sci.‐Chem. A12'} / J.Macromol.Sci.‐Chem. A12 by Hirai H. (1978)
{'key': 'e_1_2_1_16_2', 'volume': '727', 'author': 'Hirai H.', 'year': '1979', 'journal-title': 'J.Macromol.Sci.‐Chem. A13'} / J.Macromol.Sci.‐Chem. A13 by Hirai H. (1979)
10.1021/ar00072a003
10.1021/ja00187a056
N.Toshima M.Kuriyama Y.Yamada H.Hirai Chem.Lett.1981 793; (10.1246/cl.1981.793)
N.Toshima T.Takahashi Chem.Lett.1988 573; (10.1246/cl.1988.573)
{'key': 'e_1_2_1_21_2', 'volume': '669', 'author': 'Toshima N.', 'year': '1988', 'journal-title': 'J.Macromol.Sci.‐Chem. A25'} / J.Macromol.Sci.‐Chem. A25 by Toshima N. (1988)
N.Toshima T.Takahashi H.Hirai Chem.Lett.1985 1245. (10.1246/cl.1985.1245)
N.Toshima M.Ohtaki T.Teranishi Reactive Polym. in press;
{'key': 'e_1_2_1_24_2', 'first-page': '338', 'volume-title': 'Macromolecular Complexes', 'author': 'Toshima N.', 'year': '1991'} / Macromolecular Complexes by Toshima N. (1991)
10.1016/0021-9517(73)90234-0
10.1021/ar00136a002
N.Toshima K.Kushihashi T.Yonezawa H.Hirai Chem.Lett.1989 1769; (10.1246/cl.1989.1769)
{'key': 'e_1_2_1_28_2', 'volume': '1225', 'author': 'Toshima N.', 'year': '1990', 'journal-title': 'J.Macromol.Sci.‐Chem. A27'} / J.Macromol.Sci.‐Chem. A27 by Toshima N. (1990)
N.Toshima T.Yonezawa M.Harada K.Asakura Y.Iwasawa Chem.Lett.1990 815; (10.1246/cl.1990.815)
N.Toshima M.Harada T.Yonezawa K.Kushihashi K.Asakura J.Phys.Chem. in press.
{'key': 'e_1_2_1_31_2', 'first-page': '721', 'volume': '5', 'author': 'Zhao B.', 'year': '1990', 'journal-title': 'Chem.Express'} / Chem.Express by Zhao B. (1990)
10.1103/PhysRevLett.20.1441
10.1103/PhysRev.156.809
10.1007/BF00338911 / Polym.Bull. by Wang Y. (1991)
A.Harriman J.Chem.Soc. Chem.Commun.1990 24. (10.1039/C39900000024)
10.1021/ic50039a034
10.1002/bbpc.19720760207 / Ber.Bunsenges.Phys.Chem. by Fujita I. (1972)
10.1021/j150602a015
10.1021/j100226a008
{'key': 'e_1_2_1_40_2', 'volume-title': 'CRC Handbook for Chemistry and Physics', 'author': 'Vanysek P.', 'year': '1991'} / CRC Handbook for Chemistry and Physics by Vanysek P. (1991)
10.1016/S0167-2991(08)65445-2
10.1016/0039-6028(74)90177-0
10.1016/0021-9517(73)90161-9
10.1016/0021-9517(72)90237-0

Dates

Type	When
Created	14 years, 5 months ago (March 5, 2011, 3:16 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 2:58 p.m.)
Indexed	1 year, 6 months ago (Feb. 6, 2024, 9 p.m.)
Issued	33 years, 3 months ago (June 1, 1992)
Published	33 years, 3 months ago (June 1, 1992)
Published Online	14 years, 6 months ago (March 2, 2011)
Published Print	33 years, 3 months ago (June 1, 1992)

Funders 0

None

BibTeX

@article{Toshima_1992, title={Preparation of polymer‐protected gold/platinum bimetallic clusters and their application to visible light‐induced hydrogen evolution}, volume={59}, ISSN={0258-0322}, url={http://dx.doi.org/10.1002/masy.19920590123}, DOI={10.1002/masy.19920590123}, number={1}, journal={Makromolekulare Chemie. Macromolecular Symposia}, publisher={Wiley}, author={Toshima, Naoki and Yonezawa, Tetsu}, year={1992}, month=jun, pages={281–295} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        7
      ]
    ],
    "date-time": "2024-02-07T02:00:40Z",
    "timestamp": 1707271240832
  },
  "reference-count": 43,
  "publisher": "Wiley",
  "issue": "1",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2011,
            3,
            2
          ]
        ],
        "date-time": "2011-03-02T00:00:00Z",
        "timestamp": 1299024000000
      },
      "content-version": "vor",
      "delay-in-days": 6848,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1992,
        6
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>The dispersions of polymer\u2010protected gold/platinum bimetallic clusters were easily and reproducibly prepared by refluxing the mixed solutions of tetrachloroaureic(III) acid and hexachloroplatinic(IV) acid in ethanol/water (1/1) at 90 \u223c 95 \u00b0C for 2 h in the presence of a protective polymer such as poly(N\u2010vinyl\u20102\u2010pyrrolidone) (PVP). The gold/platinum bimetallic clusters thus obtained were very small, well dispersed and very stable. The UV\u2010Vis spectra and the transmission electron micrographs have indicated that each bimetallic particle has an alloy structure consisting of both gold and platinum atoms, and that the surface of the cluster particle is rich in platinum atoms and the inner core in gold atoms. The gold/platinum bimetallic clusters were used as the multi\u2010electron redox catalysts for visible light\u2010induced hydrogen evolution from water. The rate of hydrogen evolution depended on the mole ratio of the gold/platinum bimetallic clusters. The bimetallic clusters at the mole ratio of Au/Pt = 2/3 were the most active catalyst. The in\u2010situ UV\u2010Vis spectra during the reaction have indicated that the order of the aggregation in the two kinds of metal atoms is very important for structure determination of the Au/Pt bimetallic clusters. The protective polymer PVP plays a role not only in protecting hydrophobic colloidal particles in an aqueous solution, but also in determining the metal composition of the cluster surface.</jats:p>",
  "DOI": "10.1002/masy.19920590123",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2011,
        3,
        5
      ]
    ],
    "date-time": "2011-03-05T20:16:06Z",
    "timestamp": 1299356166000
  },
  "page": "281-295",
  "source": "Crossref",
  "is-referenced-by-count": 30,
  "title": "Preparation of polymer\u2010protected gold/platinum bimetallic clusters and their application to visible light\u2010induced hydrogen evolution",
  "prefix": "10.1002",
  "volume": "59",
  "author": [
    {
      "given": "Naoki",
      "family": "Toshima",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Tetsu",
      "family": "Yonezawa",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2011,
        3,
        2
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1143/JPSJ.9.359"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/RevModPhys.58.533"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01855a070"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0166-6622(82)80079-6"
    },
    {
      "key": "e_1_2_1_6_2",
      "volume": "633",
      "author": "Hirai H.",
      "year": "1979",
      "journal-title": "J.Macromol.Sci.\u2010Chem. A13"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00406a004"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150662a029"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100253a037"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.180.4087.745"
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.58.682"
    },
    {
      "key": "e_1_2_1_12_2",
      "first-page": "127",
      "volume": "3",
      "author": "Hirai H.",
      "year": "1985",
      "journal-title": "Reactive Polym."
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1295/koron.46.551"
    },
    {
      "key": "e_1_2_1_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-94-009-5261-4_2"
    },
    {
      "key": "e_1_2_1_15_2",
      "volume": "1117",
      "author": "Hirai H.",
      "year": "1978",
      "journal-title": "J.Macromol.Sci.\u2010Chem. A12"
    },
    {
      "key": "e_1_2_1_16_2",
      "volume": "727",
      "author": "Hirai H.",
      "year": "1979",
      "journal-title": "J.Macromol.Sci.\u2010Chem. A13"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar00072a003"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00187a056"
    },
    {
      "key": "e_1_2_1_19_2",
      "doi-asserted-by": "crossref",
      "unstructured": "N.Toshima M.Kuriyama Y.Yamada H.Hirai Chem.Lett.1981 793;",
      "DOI": "10.1246/cl.1981.793"
    },
    {
      "key": "e_1_2_1_20_2",
      "doi-asserted-by": "crossref",
      "unstructured": "N.Toshima T.Takahashi Chem.Lett.1988 573;",
      "DOI": "10.1246/cl.1988.573"
    },
    {
      "key": "e_1_2_1_21_2",
      "volume": "669",
      "author": "Toshima N.",
      "year": "1988",
      "journal-title": "J.Macromol.Sci.\u2010Chem. A25"
    },
    {
      "key": "e_1_2_1_22_2",
      "doi-asserted-by": "crossref",
      "unstructured": "N.Toshima T.Takahashi H.Hirai Chem.Lett.1985 1245.",
      "DOI": "10.1246/cl.1985.1245"
    },
    {
      "key": "e_1_2_1_23_2",
      "unstructured": "N.Toshima M.Ohtaki T.Teranishi Reactive Polym. in press;"
    },
    {
      "key": "e_1_2_1_24_2",
      "first-page": "338",
      "volume-title": "Macromolecular Complexes",
      "author": "Toshima N.",
      "year": "1991"
    },
    {
      "key": "e_1_2_1_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(73)90234-0"
    },
    {
      "key": "e_1_2_1_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar00136a002"
    },
    {
      "key": "e_1_2_1_27_2",
      "doi-asserted-by": "crossref",
      "unstructured": "N.Toshima K.Kushihashi T.Yonezawa H.Hirai Chem.Lett.1989 1769;",
      "DOI": "10.1246/cl.1989.1769"
    },
    {
      "key": "e_1_2_1_28_2",
      "volume": "1225",
      "author": "Toshima N.",
      "year": "1990",
      "journal-title": "J.Macromol.Sci.\u2010Chem. A27"
    },
    {
      "key": "e_1_2_1_29_2",
      "doi-asserted-by": "crossref",
      "unstructured": "N.Toshima T.Yonezawa M.Harada K.Asakura Y.Iwasawa Chem.Lett.1990 815;",
      "DOI": "10.1246/cl.1990.815"
    },
    {
      "key": "e_1_2_1_30_2",
      "unstructured": "N.Toshima M.Harada T.Yonezawa K.Kushihashi K.Asakura J.Phys.Chem. in press."
    },
    {
      "key": "e_1_2_1_31_2",
      "first-page": "721",
      "volume": "5",
      "author": "Zhao B.",
      "year": "1990",
      "journal-title": "Chem.Express"
    },
    {
      "key": "e_1_2_1_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.20.1441"
    },
    {
      "key": "e_1_2_1_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRev.156.809"
    },
    {
      "key": "e_1_2_1_34_2",
      "doi-asserted-by": "crossref",
      "first-page": "139",
      "DOI": "10.1007/BF00338911",
      "volume": "25",
      "author": "Wang Y.",
      "year": "1991",
      "journal-title": "Polym.Bull."
    },
    {
      "key": "e_1_2_1_35_2",
      "doi-asserted-by": "crossref",
      "unstructured": "A.Harriman J.Chem.Soc. Chem.Commun.1990 24.",
      "DOI": "10.1039/C39900000024"
    },
    {
      "key": "e_1_2_1_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50039a034"
    },
    {
      "key": "e_1_2_1_37_2",
      "doi-asserted-by": "crossref",
      "first-page": "115",
      "DOI": "10.1002/bbpc.19720760207",
      "volume": "76",
      "author": "Fujita I.",
      "year": "1972",
      "journal-title": "Ber.Bunsenges.Phys.Chem."
    },
    {
      "key": "e_1_2_1_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150602a015"
    },
    {
      "key": "e_1_2_1_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100226a008"
    },
    {
      "key": "e_1_2_1_40_2",
      "volume-title": "CRC Handbook for Chemistry and Physics",
      "author": "Vanysek P.",
      "year": "1991"
    },
    {
      "key": "e_1_2_1_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0167-2991(08)65445-2"
    },
    {
      "key": "e_1_2_1_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0039-6028(74)90177-0"
    },
    {
      "key": "e_1_2_1_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(73)90161-9"
    },
    {
      "key": "e_1_2_1_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(72)90237-0"
    }
  ],
  "container-title": "Makromolekulare Chemie. Macromolecular Symposia",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmasy.19920590123",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmasy.19920590123",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/masy.19920590123",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        23
      ]
    ],
    "date-time": "2023-10-23T18:58:23Z",
    "timestamp": 1698087503000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/masy.19920590123"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1992,
        6
      ]
    ]
  },
  "references-count": 43,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1992,
          6
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/masy.19920590123"
  ],
  "URL": "http://dx.doi.org/10.1002/masy.19920590123",
  "relation": {},
  "ISSN": [
    "0258-0322"
  ],
  "subject": [],
  "container-title-short": "Makromolekulare Chemie. Macromolecular Symposia",
  "published": {
    "date-parts": [
      [
        1992,
        6
      ]
    ]
  }
}