DOI: 10.1002/masy.19910450128. Nuclear reaction analysis: A study on the interface formation in polymer mixtures below the critical point

Nuclear reaction analysis: A study on the interface formation in polymer mixtures below the critical point

10.1002/masy.19910450128

Crossref journal-article

Wiley

Makromolekulare Chemie. Macromolecular Symposia (311)

Abstract

AbstractWe describe a method for directly determining the composition profile of deuterated polymer chains in polymer mixtures. Our technique, nuclear reaction analysis, is based on the 2H(3He, 4He)1H nuclear reaction. By detecting 4He in a forward geometry, we achieve a spatial resolution of 14 nm (FWHM). We use this technique to probe the broadening of the interface between two partially miscible polymers. We found that such a system attains a finite interfacial width in equilibrium. For short times, we monitor the dynamics of interface formation. We found that the interfacial width increases significantly slower than in the case of free diffusion.

Bibliography

Steiner, U., Chaturvedi, U. K., Zak, O., Krausch, G., Schatz, G., & Klein, J. (1991). Nuclear reaction analysis: A study on the interface formation in polymer mixtures below the critical point. Makromolekulare Chemie. Macromolecular Symposia, 45(1), 283â288. Portico.

Authors 6

U. Steiner (first)
U. K. Chaturvedi (additional)
O. Zak (additional)
G. Krausch (additional)
G. Schatz (additional)
J. Klein (additional)

References 14 Referenced 5

10.1021/ma00184a066
10.1209/0295-5075/5/7/015
10.1016/S0168-583X(86)80013-1
10.1021/ma00196a006
10.1063/1.103332
10.1103/PhysRevLett.55.2425
10.1103/PhysRevLett.63.616
10.1103/PhysRevLett.64.1119
for a detailed description of NRA see:U.Steiner Diplomarbeit Konstanz University (1989)
{'key': 'e_1_2_1_11_2', 'volume-title': 'Backscattering Specroscopy', 'author': 'Chu W. K.', 'year': '1978'} / Backscattering Specroscopy by Chu W. K. (1978)
10.1016/0168-583X(89)90018-9
U.Steiner G.Krausch U. K.Chaturevedi O.Zak G.SchatzandJ.Klein to be published
{'key': 'e_1_2_1_14_2', 'first-page': '13', 'volume': '308', 'author': 'de Gennes P. G.', 'year': '1989', 'journal-title': 'C. R. Acad. Sci. (Paris)'} / C. R. Acad. Sci. (Paris) by de Gennes P. G. (1989)
10.1051/jphys:0199000510160177700

Dates

Type	When
Created	14 years, 5 months ago (March 5, 2011, 2:59 p.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 9:45 p.m.)
Indexed	1 year, 10 months ago (Oct. 23, 2023, 10:40 a.m.)
Issued	34 years, 3 months ago (May 1, 1991)
Published	34 years, 3 months ago (May 1, 1991)
Published Online	14 years, 5 months ago (March 2, 2011)
Published Print	34 years, 3 months ago (May 1, 1991)

Funders 0

None

BibTeX

@article{Steiner_1991, title={Nuclear reaction analysis: A study on the interface formation in polymer mixtures below the critical point}, volume={45}, ISSN={0258-0322}, url={http://dx.doi.org/10.1002/masy.19910450128}, DOI={10.1002/masy.19910450128}, number={1}, journal={Makromolekulare Chemie. Macromolecular Symposia}, publisher={Wiley}, author={Steiner, U. and Chaturvedi, U. K. and Zak, O. and Krausch, G. and Schatz, G. and Klein, J.}, year={1991}, month=may, pages={283–288} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2023,
        10,
        23
      ]
    ],
    "date-time": "2023-10-23T14:40:12Z",
    "timestamp": 1698072012296
  },
  "reference-count": 14,
  "publisher": "Wiley",
  "issue": "1",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2011,
            3,
            2
          ]
        ],
        "date-time": "2011-03-02T00:00:00Z",
        "timestamp": 1299024000000
      },
      "content-version": "vor",
      "delay-in-days": 7245,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1991,
        5
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>We describe a method for directly determining the composition profile of deuterated polymer chains in polymer mixtures. Our technique, nuclear reaction analysis, is based on the <jats:sup>2</jats:sup>H(<jats:sup>3</jats:sup>He, <jats:sup>4</jats:sup>He)<jats:sup>1</jats:sup>H nuclear reaction. By detecting <jats:sup>4</jats:sup>He in a forward geometry, we achieve a spatial resolution of 14 nm (FWHM). We use this technique to probe the broadening of the interface between two partially miscible polymers. We found that such a system attains a finite interfacial width in equilibrium. For short times, we monitor the dynamics of interface formation. We found that the interfacial width increases significantly slower than in the case of free diffusion.</jats:p>",
  "DOI": "10.1002/masy.19910450128",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2011,
        3,
        5
      ]
    ],
    "date-time": "2011-03-05T19:59:11Z",
    "timestamp": 1299355151000
  },
  "page": "283-288",
  "source": "Crossref",
  "is-referenced-by-count": 5,
  "title": "Nuclear reaction analysis: A study on the interface formation in polymer mixtures below the critical point",
  "prefix": "10.1002",
  "volume": "45",
  "author": [
    {
      "given": "U.",
      "family": "Steiner",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "U. K.",
      "family": "Chaturvedi",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "O.",
      "family": "Zak",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "G.",
      "family": "Krausch",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "G.",
      "family": "Schatz",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "J.",
      "family": "Klein",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2011,
        3,
        2
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma00184a066"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1209/0295-5075/5/7/015"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0168-583X(86)80013-1"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma00196a006"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.103332"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.55.2425"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.63.616"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.64.1119"
    },
    {
      "key": "e_1_2_1_10_2",
      "unstructured": "for a detailed description of NRA see:U.Steiner Diplomarbeit Konstanz University (1989)"
    },
    {
      "key": "e_1_2_1_11_2",
      "volume-title": "Backscattering Specroscopy",
      "author": "Chu W. K.",
      "year": "1978"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0168-583X(89)90018-9"
    },
    {
      "key": "e_1_2_1_13_2",
      "unstructured": "U.Steiner G.Krausch U. K.Chaturevedi O.Zak G.SchatzandJ.Klein to be published"
    },
    {
      "key": "e_1_2_1_14_2",
      "first-page": "13",
      "volume": "308",
      "author": "de Gennes P. G.",
      "year": "1989",
      "journal-title": "C. R. Acad. Sci. (Paris)"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1051/jphys:0199000510160177700"
    }
  ],
  "container-title": "Makromolekulare Chemie. Macromolecular Symposia",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmasy.19910450128",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmasy.19910450128",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/masy.19910450128",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        23
      ]
    ],
    "date-time": "2023-10-23T01:45:12Z",
    "timestamp": 1698025512000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/masy.19910450128"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1991,
        5
      ]
    ]
  },
  "references-count": 14,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1991,
          5
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/masy.19910450128"
  ],
  "URL": "http://dx.doi.org/10.1002/masy.19910450128",
  "relation": {},
  "ISSN": [
    "0258-0322"
  ],
  "subject": [],
  "container-title-short": "Makromolekulare Chemie. Macromolecular Symposia",
  "published": {
    "date-parts": [
      [
        1991,
        5
      ]
    ]
  }
}