DOI: 10.1002/marc.200800346. “Click” Dielectrics: Use of 1,3‐Dipolar Cycloadditions to Generate Diverse Core‐Shell Nanoparticle Structures with Applications to Flexible Electronics

“Click” Dielectrics: Use of 1,3‐Dipolar Cycloadditions to Generate Diverse Core‐Shell Nanoparticle Structures with Applications to Flexible Electronics

10.1002/marc.200800346

Crossref journal-article

Wiley

Macromolecular Rapid Communications (311)

Abstract

AbstractWe have synthesized a “universal ligand” incorporating a phosphonate surface anchor and a terminal alkyne moiety which binds to TiO2 nanoparticles and exhibits excellent dispersity in organic solvents. The alkyne functionality permits attachment of azide terminated polymer shells using “click” chemistry. Thus TiO2 core nanoparticles have been encapsulated with both polystyrene and poly(t‐butyl acrylate) shells. The TiO2‐poly(t‐butyl acrylate) core shell nanoparticles are amenable to further chemical transformation into TiO2‐poly(acrylic acid) nanoparticles through ester hydrolysis. These TiO2‐polyacrylic acid nanoparticles are dispersible in aqueous solution. The resulting core‐shell nanoparticles have been incorporated as high K dielectric films in capacitor and organic thin film transistor devices and are promising new materials for flexible electronics applications.magnified image

Bibliography

White, M. A., Maliakal, A., Turro, N. J., & Koberstein, J. (2008). âClickâ Dielectrics: Use of 1,3âDipolar Cycloadditions to Generate Diverse CoreâShell Nanoparticle Structures with Applications to Flexible Electronics. Macromolecular Rapid Communications, 29(18), 1544â1548. Portico.

Authors 4

Meghann A. White (first)
Ashok Maliakal (additional)
Nicholas J. Turro (additional)
Jeff Koberstein (additional)

References 34 Referenced 29

10.1021/ja0266621
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10.1021/ja052035a
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10.1021/jo011148j
10.1002/1521-3773(20020715)41:14<2596::AID-ANIE2596>3.0.CO;2-4
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10.1002/marc.200600625
10.1002/adma.200602739
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10.1021/la0362977
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10.1021/nl070698f
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10.1021/la7018742
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10.1021/cm991125
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{'key': 'e_1_2_6_28_2', 'first-page': '227', 'volume': '96', 'author': 'Vojtova L.', 'year': '2002', 'journal-title': 'Chem. Listy'} / Chem. Listy by Vojtova L. (2002)
10.1021/ja036505h
10.1021/ma051566g
10.1021/ja0612910
{'key': 'e_1_2_6_32_2', 'volume-title': 'Infrared Absorption Spectroscopy', 'author': 'Nakanishi K.', 'year': '1977'} / Infrared Absorption Spectroscopy by Nakanishi K. (1977)
10.1063/1.2450660
{'key': 'e_1_2_6_34_2', 'volume-title': 'Polymer Handbook', 'author': 'Brandrup J.', 'year': '1989'} / Polymer Handbook by Brandrup J. (1989)

Dates

Type	When
Created	17 years ago (Aug. 8, 2008, 8:17 a.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 7:42 a.m.)
Indexed	1 year, 4 months ago (April 5, 2024, 10:22 a.m.)
Issued	16 years, 11 months ago (Sept. 9, 2008)
Published	16 years, 11 months ago (Sept. 9, 2008)
Published Online	16 years, 11 months ago (Sept. 9, 2008)
Published Print	16 years, 11 months ago (Sept. 17, 2008)

Funders 0

None

BibTeX

@article{White_2008, title={“Click” Dielectrics: Use of 1,3‐Dipolar Cycloadditions to Generate Diverse Core‐Shell Nanoparticle Structures with Applications to Flexible Electronics}, volume={29}, ISSN={1521-3927}, url={http://dx.doi.org/10.1002/marc.200800346}, DOI={10.1002/marc.200800346}, number={18}, journal={Macromolecular Rapid Communications}, publisher={Wiley}, author={White, Meghann A. and Maliakal, Ashok and Turro, Nicholas J. and Koberstein, Jeff}, year={2008}, month=sep, pages={1544–1548} }

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