DOI: 10.1002/marc.200390069. Spatially Confined Tungstate Ion Polymerization in Microcapsules

Spatially Confined Tungstate Ion Polymerization in Microcapsules

10.1002/marc.200390069

Crossref journal-article

Wiley

Macromolecular Rapid Communications (311)

Abstract

AbstractA new approach for performing the WO42− polymerization reaction exclusively inside polyelectrolyte capsules of a micron scale size is demonstrated. This approach is based upon a pH gradient across the capsule shell (2.5 inside the capsule volume and 6.5 outside the capsule) caused by encapsulated poly(styrene sulfonate) molecules. During the first stage of the reaction, different polytungstate anions were synthesized. Crystalline WO3 nanoparticles were formed inside the capsule as the final polymerization product.The tungstate ion polymerization confined within a micron‐sized polyelectrolyte capsule described herein.magnified imageThe tungstate ion polymerization confined within a micron‐sized polyelectrolyte capsule described herein.

Bibliography

Shchukin, D. G., Dong, W., & Sukhorukov, G. B. (2003). Spatially Confined Tungstate Ion Polymerization in Microcapsules. Macromolecular Rapid Communications, 24(7), 462â466. Portico.

Authors 3

Dmitry G. Shchukin (first)
Wenfei Dong (additional)
Gleb B. Sukhorukov (additional)

References 18 Referenced 21

10.1016/0021-9797(90)90023-H
10.1021/cm980762h
10.1016/S0379-6779(01)00328-9
10.1021/nl0100015
10.1002/1521-3927(20010101)22:1<44::AID-MARC44>3.0.CO;2-U
10.1002/(SICI)1099-1581(1998100)9:10/11<759::AID-PAT846>3.0.CO;2-Q
10.1002/(SICI)1521-3773(19980904)37:16<2201::AID-ANIE2201>3.0.CO;2-E
10.1016/S1383-7303(01)80035-1
10.1002/marc.200390041
10.1021/jp990095v
10.1016/S0167-577X(02)01061-3
10.1021/jp0265236
{'key': 'e_1_2_6_13_2', 'first-page': '180', 'volume-title': 'Heteropoly and Isopoly Oxometalates', 'author': 'Pope M. T.', 'year': '1993'} / Heteropoly and Isopoly Oxometalates by Pope M. T. (1993)
10.1016/0021-9797(87)90470-X
{'key': 'e_1_2_6_15_2', 'first-page': '321', 'volume-title': 'Metal Oxide Chemistry and Synthesis: from Solution to Solid State', 'author': 'Jolivet J.‐P.', 'year': '2000'} / Metal Oxide Chemistry and Synthesis: from Solution to Solid State by Jolivet J.‐P. (2000)
10.1006/jcat.1996.0087
10.1016/0379-6779(96)80199-8
10.1023/A:1008775318802

Dates

Type	When
Created	22 years, 3 months ago (May 5, 2003, 11:01 a.m.)
Deposited	1 year, 10 months ago (Oct. 13, 2023, 3:32 a.m.)
Indexed	1 year, 9 months ago (Nov. 20, 2023, 2:45 p.m.)
Issued	22 years, 4 months ago (April 28, 2003)
Published	22 years, 4 months ago (April 28, 2003)
Published Online	22 years, 4 months ago (April 28, 2003)
Published Print	22 years, 3 months ago (May 7, 2003)

Funders 0

None

BibTeX

@article{Shchukin_2003, title={Spatially Confined Tungstate Ion Polymerization in Microcapsules}, volume={24}, ISSN={1521-3927}, url={http://dx.doi.org/10.1002/marc.200390069}, DOI={10.1002/marc.200390069}, number={7}, journal={Macromolecular Rapid Communications}, publisher={Wiley}, author={Shchukin, Dmitry G. and Dong, Wenfei and Sukhorukov, Gleb B.}, year={2003}, month=apr, pages={462–466} }

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