DOI: 10.1002/marc.1995.030160604. Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization

Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization

10.1002/marc.1995.030160604

Crossref journal-article

Wiley

Macromolecular Rapid Communications (311)

Abstract

AbstractThe choice of the photoinitiator is not usually regarded as being as important consideration in attempting to determine the value of the propagation rate coefficient kp from a pulsed laser‐initiated polymerization (PLP). It is shown that in fact the choice of the photoinitiator can profoundly influence the success of such experiments. Specially, for a number of monomers it was found that the successful determination of kp is essentially impossible when 1,1‐azodicyclohexanecarbonitrile is employed as a photoinitiator. The likely reason for this phenomenon is discussed from which it would seem appropriate to be wary in using any azo compound as a PLP photoinitiator. From PLP experiments with a non‐azo photoinitiator, ambient pressure kp has been determined for bulk polymerization of methyl methacrylate over an extended temperature range.

Bibliography

Bergert, U., Beuermann, S., Buback, M., Kurz, C. H., Russell, G. T., & Schmaltz, C. (1995). Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization. Macromolecular Rapid Communications, 16(6), 425â434. Portico.

Authors 6

Ute Bergert (first)
Sabine Beuermann (additional)
Michael Buback (additional)
Caroline H. Kurz (additional)
Gregory T. Russell (additional)
Claudia Schmaltz (additional)

References 29 Referenced 22

10.1002/macp.1987.021880716
M.Buback R. G.Gilbert R. A.Hutchinson B.Klumperman F.‐D.Kuchta B. G.Manders K. F.O'Driscoll G. T.Russell J.Schweer Macromol. Chem. Phys. in press
10.1007/978-3-642-78759-1_17
10.1002/pi.4990240202
10.1021/ma00094a016
10.1021/ma00076a017
10.1016/0014-3057(89)90022-0
J.Sarnecki J.Schweer Macromolecules in press
10.1002/ange.19911030606
10.1002/anie.199106411
10.1002/macp.1978.021791115
B. G.Manders G.Chambard W. J.Kingma B.Klumperman A. M.van Herk A. L.German J. Polym. Sci. Polym. Chem. Ed. submitted (1995)
C. H.Kurz DissertationGöttingen (1995)
10.1002/pola.1992.080300516
10.1021/ja00856a026
10.1021/cr60324a001
10.1016/S0040-4039(01)88030-8
10.1016/S0040-4039(01)92771-6
10.1002/mats.1992.040010203
10.1002/marc.1988.030091110
10.1002/marc.1991.030120612
{'key': 'e_1_2_1_21_2', 'volume-title': 'Polymer Handbook', 'author': 'Masson J. C.', 'year': '1989'} / Polymer Handbook by Masson J. C. (1989)
10.1016/0144-2880(84)90022-8
10.1524/zpch.1989.161.Part_1_2.153
10.1002/marc.1986.030070505
C.Schmaltz DiplomarbeitGöttingen (1994)
10.1002/marc.1994.030150408
10.1002/marc.1994.030150805
10.1002/macp.1990.021911027

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 9:02 a.m.)
Deposited	1 year, 10 months ago (Oct. 25, 2023, 5:54 p.m.)
Indexed	1 year, 5 months ago (March 31, 2024, 7:47 a.m.)
Issued	30 years, 3 months ago (June 1, 1995)
Published	30 years, 3 months ago (June 1, 1995)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	30 years, 3 months ago (June 1, 1995)

Funders 0

None

BibTeX

@article{Bergert_1995, title={Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization}, volume={16}, ISSN={1521-3927}, url={http://dx.doi.org/10.1002/marc.1995.030160604}, DOI={10.1002/marc.1995.030160604}, number={6}, journal={Macromolecular Rapid Communications}, publisher={Wiley}, author={Bergert, Ute and Beuermann, Sabine and Buback, Michael and Kurz, Caroline H. and Russell, Gregory T. and Schmaltz, Claudia}, year={1995}, month=jun, pages={425–434} }

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