DOI: 10.1002/marc.1995.030160202. Structural correlation between the columnar mesophase and the melt in poly(di‐<i>n</i>‐alkylsiloxane)s

Structural correlation between the columnar mesophase and the melt in poly(di‐n‐alkylsiloxane)s

10.1002/marc.1995.030160202

Crossref journal-article

Wiley

Macromolecular Rapid Communications (311)

Abstract

AbstractPhase transitions of poly(dialkylsiloxane)s substituted with propyl and butyl groups are reported based on X‐ray diffractometry. The structure in the mesophase and in the melt of polymers with 2 to 10 carbon atoms in each side chain is compared. Both phases display a linear dependence of the molecular cross‐section on the length of the alkyl group demonstrating their structural similarity. By means of differential scanning calorimetry it is shown that the temperature range of the mesophase remains practically unchanged in width as well as in absolute temperature for dibutyl up to dihexyl substituted polysiloxanes.

Bibliography

Out, G. J. J., Turetskii, A. A., & MÃ¶ller, M. (1995). Structural correlation between the columnar mesophase and the melt in poly(diânâalkylsiloxane)s. Macromolecular Rapid Communications, 16(2), 107â112. Portico.

Authors 3

Gerardus J. J. Out (first)
Alexei A. Turetskii (additional)
Martin Möller (additional)

References 15 Referenced 16

10.1002/pol.1985.170230409
10.1007/BFb0017966
10.1002/marc.1985.030060613
10.1002/masy.19900340111
10.1021/ma00090a026
10.1021/ma00067a032
10.1002/macp.1991.021920901
10.1021/ma00033a030
10.1002/macp.1995.021960113
10.1080/00222346908217104
A. A.Turetskii G. J. J.Out H.‐A.Klok M.Möller Polymer submitted
10.1007/BF00657986
G. J. J.Out PhD Dissertation Universiteit Twente The Netherlands 1994 ISBN 90‐9007040‐0N
10.1021/ma00201a009
{'key': 'e_1_2_1_15_2', 'volume-title': 'X‐ray Diffraction Procedures', 'author': 'Klug H. P.', 'year': '1974'} / X‐ray Diffraction Procedures by Klug H. P. (1974)

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 9:02 a.m.)
Deposited	1 year, 10 months ago (Oct. 26, 2023, 9:31 a.m.)
Indexed	2 days, 3 hours ago (Aug. 30, 2025, 1:16 p.m.)
Issued	30 years, 7 months ago (Feb. 1, 1995)
Published	30 years, 7 months ago (Feb. 1, 1995)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	30 years, 7 months ago (Feb. 1, 1995)

Funders 0

None

BibTeX

@article{Out_1995, title={Structural correlation between the columnar mesophase and the melt in poly(di‐n‐alkylsiloxane)s}, volume={16}, ISSN={1521-3927}, url={http://dx.doi.org/10.1002/marc.1995.030160202}, DOI={10.1002/marc.1995.030160202}, number={2}, journal={Macromolecular Rapid Communications}, publisher={Wiley}, author={Out, Gerardus J. J. and Turetskii, Alexei A. and Möller, Martin}, year={1995}, month=feb, pages={107–112} }

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