DOI: 10.1002/macp.1997.021980518. Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate

Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate

10.1002/macp.1997.021980518

Crossref journal-article

Wiley

Macromolecular Chemistry and Physics (311)

Abstract

AbstractPulsed‐laser polymerization (PLP) in conjunction with molar mass distribution (MMD) measurement is the method of choice for determining the propagation rate coefficient kp in free‐radical polymerizations. The authors, members of the IUPAC Working Party on Modeling of kinetics and processes of polymerization, collate results from using PLP‐MMD to determine kp as a function of temperature T for bulk free‐radical polymerization of methyl methacrylate at low conversions and ambient pressure. Despite coming from several different laboratories, the values of kp are in excellent agreement and obey consistency checks. These values are therefore recommended as constituting a benchmark data set, one that is best fitted by The 95% joint confidence interval for these Arrhenius parameters is also given. In so doing, we describe the most appropriate statistical methods for fitting kp(T) data and then obtaining a joint confidence interval for the fitted Arrhenius parameters. As well, we outline factors which impose slight limitations on the accuracy of the PLP‐MMD technique for determining kp, factors which may apply even when this technique is functioning well. At the same time we discuss how such systematic errors in kp can be minimized.

Bibliography

Beuermann, S., Buback, M., Davis, T. P., Gilbert, R. G., Hutchinson, R. A., Olaj, O. F., Russell, G. T., Schweer, J., & van Herk, A. M. (1997). Critically evaluated rate coefficients for freeâradical polymerization, 2.. Propagation rate coefficients for methyl methacrylate. Macromolecular Chemistry and Physics, 198(5), 1545â1560. Portico.

Authors 9

Sabine Beuermann (first)
Michael Buback (additional)
Thomas P. Davis (additional)
Robert G. Gilbert (additional)
Robin A. Hutchinson (additional)
Oskar Friedrich Olaj (additional)
Gregory T. Russell (additional)
Johannes Schweer (additional)
Alex M. van Herk (additional)

References 39 Referenced 536

10.1002/macp.1995.021961016
{'key': 'e_1_2_1_2_2', 'first-page': '467', 'volume': '131', 'author': 'Hutchinson R. A.', 'year': '1995', 'journal-title': 'DECHEMA Monogr.'} / DECHEMA Monogr. by Hutchinson R. A. (1995)
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Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 7:04 a.m.)
Deposited	1 year, 10 months ago (Oct. 28, 2023, 5:42 a.m.)
Indexed	1 day ago (Aug. 28, 2025, 8:29 a.m.)
Issued	28 years, 3 months ago (May 1, 1997)
Published	28 years, 3 months ago (May 1, 1997)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	28 years, 3 months ago (May 1, 1997)

Funders 0

None

BibTeX

@article{Beuermann_1997, title={Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate}, volume={198}, ISSN={1521-3935}, url={http://dx.doi.org/10.1002/macp.1997.021980518}, DOI={10.1002/macp.1997.021980518}, number={5}, journal={Macromolecular Chemistry and Physics}, publisher={Wiley}, author={Beuermann, Sabine and Buback, Michael and Davis, Thomas P. and Gilbert, Robert G. and Hutchinson, Robin A. and Olaj, Oskar Friedrich and Russell, Gregory T. and Schweer, Johannes and van Herk, Alex M.}, year={1997}, month=may, pages={1545–1560} }

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