DOI: 10.1002/macp.1996.021970501. Synthesis and properties of new segmented block poly(urethane‐urea)s containing phosphatidylcholine analogues and polybutadienes

Synthesis and properties of new segmented block poly(urethane‐urea)s containing phosphatidylcholine analogues and polybutadienes

10.1002/macp.1996.021970501

Crossref journal-article

Wiley

Macromolecular Chemistry and Physics (311)

Abstract

AbstractNew hydrophobic‐hydrophilic microphase‐separated block segmented copoly(urethane‐urea)s were synthesized by introducing hydrophobic polybutadienes as the soft segments and 4,4′‐methylenediphenyl diisocyanate, hexamethylene diisocyanate, ethylenediamine, and a hydrophilic phosphatidylcholine analogue as the hard segments in the backbones of these polymers. The results of ATR‐IR and XPS show the coexistence of phosphatidylcholine analogues and polybutadienes on the surface of cast films of the synthesized poly(urethane‐urea)s. Furthermore, TEM cross sectional observation of the cast film PBDP‐1370 indicates that it possesses a hydrophilic‐hydrophobic microphase‐separated domain structure.

Bibliography

Chen, T., Wang, Y., Li, Y., Kitamura, M., & Nakaya, T. (1996). Synthesis and properties of new segmented block poly(urethaneâurea)s containing phosphatidylcholine analogues and polybutadienes. Macromolecular Chemistry and Physics, 197(5), 1587â1597. Portico.

Authors 5

Tian‐Ming Chen (first)
Yan‐Feng Wang (additional)
Yu‐Jun Li (additional)
Masaya Kitamura (additional)
Tadao Nakaya (additional)

References 23 Referenced 8

{'key': 'e_1_2_1_1_2', 'volume-title': 'Polyurethanes in Medicine', 'author': 'Lelah M. D.', 'year': '1986'} / Polyurethanes in Medicine by Lelah M. D. (1986)
10.1016/0021-9797(81)90203-4
10.1021/ma60073a023
10.1016/0032-3861(85)90218-6
10.1016/0928-4931(94)90029-9 / Mater. Sci. Eng. by Matthews K. H. (1995)
10.1016/0142-9612(92)90137-D
10.1002/jbm.820150310
10.1002/macp.1977.021781021
10.1021/ja00367a023
10.1002/marc.1982.030030701
10.1021/ma00052a029
10.1002/pola.1994.080320805
{'key': 'e_1_2_1_13_2', 'volume-title': 'A Textbook of Biochemistry: with Clinical Correlations', 'author': 'Devlin T. M.', 'year': '1992'} / A Textbook of Biochemistry: with Clinical Correlations by Devlin T. M. (1992)
10.1002/pola.1991.080291001
10.1016/0142-9612(86)90068-2
10.1002/marc.1995.030160105
10.1002/macp.1995.021961006
10.1021/ja01168a032
R. E.Edmundson Chem. Ind. (London)1828(1962)
N. T.Thoung P.Chabrier Bull. Soc. Chim. Fr.667(1974)
10.1002/(SICI)1099-0518(199602)34:3<449::AID-POLA14>3.0.CO;2-P
10.1021/ma00127a017
10.1295/polymj.27.65

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 6:08 a.m.)
Deposited	1 year, 11 months ago (Sept. 27, 2023, 7:16 p.m.)
Indexed	11 months, 2 weeks ago (Sept. 12, 2024, 11:11 a.m.)
Issued	29 years, 3 months ago (May 1, 1996)
Published	29 years, 3 months ago (May 1, 1996)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	29 years, 3 months ago (May 1, 1996)

Funders 0

None

BibTeX

@article{Chen_1996, title={Synthesis and properties of new segmented block poly(urethane‐urea)s containing phosphatidylcholine analogues and polybutadienes}, volume={197}, ISSN={1521-3935}, url={http://dx.doi.org/10.1002/macp.1996.021970501}, DOI={10.1002/macp.1996.021970501}, number={5}, journal={Macromolecular Chemistry and Physics}, publisher={Wiley}, author={Chen, Tian‐Ming and Wang, Yan‐Feng and Li, Yu‐Jun and Kitamura, Masaya and Nakaya, Tadao}, year={1996}, month=may, pages={1587–1597} }

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