DOI: 10.1002/macp.1996.021970324. Towards the propagation rate coefficient for the free‐radical polymerization of 1,3‐butadiene

Towards the propagation rate coefficient for the free‐radical polymerization of 1,3‐butadiene

10.1002/macp.1996.021970324

Crossref journal-article

Wiley

Macromolecular Chemistry and Physics (311)

Abstract

AbstractThe propagation rate coefficient kp for the free‐radical polymerization of 1,3‐butadiene was determined as a function of temperature in the range of 30–60°C in bulk and as a function of the concentration of 1,3‐butadiene in chlorobenzene at 50°C using a combination of a UV flash‐lamp induced polymerization and a measurement of the molecular weight distribution of the produced polymer by size exclusion chromamgraphy. Differences of up to around 45% resulted even for the same concentrations and temperatures when these measurements were compared with recent determinations of kp of 1,3‐butadiene in chlorobenzene in which just such an experimental setup was used. This finding was essentially attributed to large differences in the radical termination rates which prevailed in the reaction volumes under the current conditions of the pulse‐induced polymerization experiments. Moreover, in the vicinity of bulk concentrations of 1,3‐butadiene in chlorobenzene, kp apparently decreases with concentration.

Authors 3

Friedhelm Bandermann (first)
Claus Günther (additional)
Johannes Schweer (additional)

References 41 Referenced 22

10.1002/macp.1987.021880716
10.1002/macp.1995.021961016
{'key': 'e_1_2_1_3_2', 'first-page': '976', 'volume': '4', 'author': 'Aleksandrov A. P.', 'year': '1977', 'journal-title': 'Kvantovaja Electron.'} / Kvantovaja Electron. by Aleksandrov A. P. (1977)
10.1070/QE1977v007n05ABEH012534
10.1021/ma00116a006
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10.1002/macp.1995.021960608
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10.1002/marc.1994.030150805
10.1002/marc.1995.030160408
R. A.Hutchinson private communication
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10.1007/978-3-642-78759-1_17
10.1021/ma00098a010
10.1002/mats.1994.040030214
10.1016/1010-6030(94)80001-4
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10.1002/mats.1993.040020511
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10.1021/ma00069a024
10.1021/ma00068a046
10.1002/marc.1993.030140311
10.1002/pola.1992.080300516
10.1002/macp.1990.021911027
10.1021/ma00226a024
10.1002/marc.1990.030110908
10.1021/ma00210a003
10.1016/0014-3057(89)90022-0
10.1021/ma00196a043
10.1002/pol.1989.140270601
10.1002/marc.1988.030091110
10.1002/marc.1992.030130703
DE 40 41 139 (1991) Bayer AG inv.: (10.1016/0026-2862(91)90015-4)
{'key': 'e_1_2_1_35_3', 'first-page': '42230u', 'volume': '116', 'author': 'Schweer J.', 'year': '1992', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. by Schweer J. (1992)
10.1021/ie50448a022
{'key': 'e_1_2_1_37_2', 'first-page': 'II/67', 'volume-title': 'Polymer Handbook', 'author': 'Berger K. C.', 'year': '1989'} / Polymer Handbook by Berger K. C. (1989)
10.1002/pol.1952.120080207
J. B. L.deKock Graduation Thesis Eindhoven University of Technology (1994)

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 6:08 a.m.)
Deposited	1 year, 10 months ago (Oct. 27, 2023, 2:33 a.m.)
Indexed	11 months, 2 weeks ago (Sept. 13, 2024, 5:12 a.m.)
Issued	29 years, 5 months ago (March 1, 1996)
Published	29 years, 5 months ago (March 1, 1996)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	29 years, 5 months ago (March 1, 1996)

Funders 0

None

BibTeX

@article{Bandermann_1996, title={Towards the propagation rate coefficient for the free‐radical polymerization of 1,3‐butadiene}, volume={197}, ISSN={1521-3935}, url={http://dx.doi.org/10.1002/macp.1996.021970324}, DOI={10.1002/macp.1996.021970324}, number={3}, journal={Macromolecular Chemistry and Physics}, publisher={Wiley}, author={Bandermann, Friedhelm and Günther, Claus and Schweer, Johannes}, year={1996}, month=mar, pages={1055–1069} }

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