DOI: 10.1002/macp.1995.021961016. Critically evaluated rate coefficients for free‐radical polymerization, 1. Propagation rate coefficient for styrene

Critically evaluated rate coefficients for free‐radical polymerization, 1. Propagation rate coefficient for styrene

10.1002/macp.1995.021961016

Crossref journal-article

Wiley

Macromolecular Chemistry and Physics (311)

Abstract

AbstractPulsed‐laser polymerization (PLP) in conjugation with molecular weight distribution (MWD) measurement has emerged as the method of choice for determining the propagation rate coefficient kp in free‐radical polymerizations. Detailed guidelines for using this technique (including essential internal consistency checks) and reporting the results therefrom are given by the authors, members of the IUPAC Working Party on Modeling of kinetics and processes of polymerization. The results for PLP‐MWD kp measurements from many laboratories for bulk free‐radical polymerization of styrene at low conversions and ambient pressure are collated, and are in excellent agreement. They are therefore recommended as constituting a benchmark data set, one that is best fitted by (the confidence ellipsoid for the Arrhenius parameters is also given). These benchmark data are also used to evaluate the merits of several other methods for determining kp; it is found that appropriately calibrated electron paramagnetic resonance spectroscopy appears to yield reliable values of kp for styrene.

Bibliography

Buback, M., Gilbert, R. G., Hutchinson, R. A., Klumperman, B., Kuchta, F., Manders, B. G., OâDriscoll, K. F., Russell, G. T., & Schweer, J. (1995). Critically evaluated rate coefficients for freeâradical polymerization, 1. Propagation rate coefficient for styrene. Macromolecular Chemistry and Physics, 196(10), 3267â3280. Portico.

Authors 9

Michael Buback (first)
Robert G. Gilbert (additional)
Robin A. Hutchinson (additional)
Bert Klumperman (additional)
Frank‐Dieter Kuchta (additional)
Bart G. Manders (additional)
Kenneth F. O'Driscoll (additional)
Gregory T. Russell (additional)
Johannes Schweer (additional)

References 39 Referenced 630

10.1002/pol.1988.140260704
10.1002/pola.1992.080300516
10.1021/ma00196a043
10.1002/apmc.1987.051550115
10.1002/macp.1993.021940617
10.1002/mats.1994.040030214
10.1002/macp.1987.021880716
10.1021/ma00076a064
10.1002/macp.1993.021940710
10.1016/0003-2670(93)80373-S
10.1021/bk-1993-0521.ch010
10.1016/0032-3861(93)90339-C
10.1002/app.1993.070520010
10.1002/marc.1994.030150315
10.1021/bk-1993-0521.ch008
10.1002/macp.1990.021911027
10.1002/mats.1993.040020511
10.1002/mats.1992.040010203
10.1021/ma00076a017
10.1021/ma00094a016
10.1021/ma00116a006
10.1080/10826079308019695
10.1021/ma00106a021
10.1007/978-3-642-78759-1_17
10.1002/pi.4990240202
10.1016/0014-3057(89)90022-0
10.1021/ma00068a046
10.1021/ma00210a003
10.1002/macp.1995.021960608
10.1021/ma00098a010
B. G.Manders G.Chambard W. J.Kingma B.Klumperman A. M.van Herk A. L.German J. Polym. Sci. Part A: Polym. Chem. submitted
10.1002/pol.1984.170221161
10.1021/ma00206a037
10.1002/macp.1994.021950914
10.1007/BF00944835
10.1039/f19807601323
10.1039/f19807601344
10.1080/00222337708061301
10.1002/pol.1976.170140408

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 6:02 a.m.)
Deposited	1 year, 10 months ago (Oct. 26, 2023, 6:52 p.m.)
Indexed	3 weeks, 6 days ago (Aug. 6, 2025, 8:55 a.m.)
Issued	29 years, 11 months ago (Oct. 1, 1995)
Published	29 years, 11 months ago (Oct. 1, 1995)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	29 years, 11 months ago (Oct. 1, 1995)

Funders 0

None

BibTeX

@article{Buback_1995, title={Critically evaluated rate coefficients for free‐radical polymerization, 1. Propagation rate coefficient for styrene}, volume={196}, ISSN={1521-3935}, url={http://dx.doi.org/10.1002/macp.1995.021961016}, DOI={10.1002/macp.1995.021961016}, number={10}, journal={Macromolecular Chemistry and Physics}, publisher={Wiley}, author={Buback, Michael and Gilbert, Robert G. and Hutchinson, Robin A. and Klumperman, Bert and Kuchta, Frank‐Dieter and Manders, Bart G. and O’Driscoll, Kenneth F. and Russell, Gregory T. and Schweer, Johannes}, year={1995}, month=oct, pages={3267–3280} }

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