DOI: 10.1002/macp.1994.021951008. Raman spectroscopic study of hydrogen bonding of poly(<i>N</i>‐vinyl‐2‐pyrrolidone) in heavy water and dimethyl sulfoxide

Raman spectroscopic study of hydrogen bonding of poly(N‐vinyl‐2‐pyrrolidone) in heavy water and dimethyl sulfoxide

10.1002/macp.1994.021951008

Crossref journal-article

Wiley

Macromolecular Chemistry and Physics (311)

Abstract

AbstractThe Raman spectra of solutions of poly(N‐vinyl‐2‐pyrrolidone) (PVP; M̄w = 1 000, 10 000, 40 000 and 360 000) in D2O and dimethyl sulfoxide (DMSO) were measured at various concentrations. PVP is hydrated by D2O in a manner different from N‐ethyl‐2‐pyrrolidone (NEP) and N‐methyl‐2‐pyrrolidone (NMP), monomer analogues of PVP. The self‐association of DMSO molecules in the solution of PVP was found to be different from that in the solution of NMP by using difference spectroscopy. These phenomena were attributed to a net‐like structure of concentrated solutions of PVP.

Bibliography

Tanaka, N., Ito, K., & Kitano, H. (1994). Raman spectroscopic study of hydrogen bonding of poly(Nâvinylâ2âpyrrolidone) in heavy water and dimethyl sulfoxide. Macromolecular Chemistry and Physics, 195(10), 3369â3380. Portico.

Authors 3

Naoki Tanaka (first)
Kensaku Ito (additional)
Hiromi Kitano (additional)

References 29 Referenced 22

10.1016/0584-8539(92)80029-V
10.1246/bcsj.52.2871
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10.1246/bcsj.58.1495
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10.1002/macp.1981.021821119
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10.1002/macp.1973.021690120
10.1021/ma00010a060
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{'key': 'e_1_2_1_14_2', 'first-page': '354', 'volume': '44', 'author': 'Huttenruch R.', 'year': '1989', 'journal-title': 'Pharmazie'} / Pharmazie by Huttenruch R. (1989)
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J. B.Gill D. C.Goodall B.Jeffreys P.Gans J. Chem. Soc. Dalton Trans.2597(1986) (10.1039/dt9860002597)
10.1002/jrs.1250210806

Dates

Type	When
Created	22 years, 4 months ago (April 17, 2003, 7:02 a.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 10:57 p.m.)
Indexed	2 months ago (July 2, 2025, 3:27 p.m.)
Issued	30 years, 11 months ago (Oct. 1, 1994)
Published	30 years, 11 months ago (Oct. 1, 1994)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	30 years, 11 months ago (Oct. 1, 1994)

Funders 0

None

BibTeX

@article{Tanaka_1994, title={Raman spectroscopic study of hydrogen bonding of poly(N‐vinyl‐2‐pyrrolidone) in heavy water and dimethyl sulfoxide}, volume={195}, ISSN={1521-3935}, url={http://dx.doi.org/10.1002/macp.1994.021951008}, DOI={10.1002/macp.1994.021951008}, number={10}, journal={Macromolecular Chemistry and Physics}, publisher={Wiley}, author={Tanaka, Naoki and Ito, Kensaku and Kitano, Hiromi}, year={1994}, month=oct, pages={3369–3380} }

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