DOI: 10.1002/macp.1992.021930511. Polyarylenes and poly(arylenevinylene)s, 9 The oxidized states of a (1,4‐phenylene) ladder polymer

Polyarylenes and poly(arylenevinylene)s, 9 The oxidized states of a (1,4‐phenylene) ladder polymer

10.1002/macp.1992.021930511

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractThe oxidized states of double‐stranded, planar (1,4‐phenylene)‐type ladder polymers are characterized by means of UV/VIS/NIRNIR: Near infrared. spectroscopy and cyclic voltammetry. The oxidation with antimony pentachloride or iron trichloride proceeds as a two‐step process; first, radical cationic (polaronic) species are generated, followed by the formation of dicationic (bipolaronic) ones. Especially the polymeric radical cations formed possess an outstanding chemical stability. The findings of cyclovoltammetric investigations are in full agreement with the chemical oxidation experiments.

Bibliography

Scherf, U., Bohnen, A., & MÃ¼llen, K. (1992). Polyarylenes and poly(arylenevinylene)s, 9 The oxidized states of a (1,4âphenylene) ladder polymer. Die Makromolekulare Chemie, 193(5), 1127â1133. Portico.

Authors 3

Ullrich Scherf (first)
Angelika Bohnen (additional)
Klaus Müllen (additional)

References 10 Referenced 115

10.1002/marc.1991.030120806
{'key': 'e_1_2_1_2_2', 'first-page': '213', 'volume-title': 'Handbook of Conducting Polymers', 'author': 'Elsenbaumer R. L.', 'year': '1986'} / Handbook of Conducting Polymers by Elsenbaumer R. L. (1986)
10.1063/1.440596
10.1016/0032-3861(89)90078-5
10.1016/0032-3861(89)90079-7
10.1007/978-94-009-6440-2_50
10.1080/00268948108075251
10.1016/0379-6779(91)91206-P
10.1021/ac00235a057
10.1002/macp.1991.021920802

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:09 a.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 10:26 a.m.)
Indexed	2 months, 3 weeks ago (June 12, 2025, 10:05 p.m.)
Issued	33 years, 4 months ago (May 1, 1992)
Published	33 years, 4 months ago (May 1, 1992)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	33 years, 4 months ago (May 1, 1992)

Funders 0

None

BibTeX

@article{Scherf_1992, title={Polyarylenes and poly(arylenevinylene)s, 9 The oxidized states of a (1,4‐phenylene) ladder polymer}, volume={193}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1992.021930511}, DOI={10.1002/macp.1992.021930511}, number={5}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Scherf, Ullrich and Bohnen, Angelika and Müllen, Klaus}, year={1992}, month=may, pages={1127–1133} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        6,
        13
      ]
    ],
    "date-time": "2025-06-13T02:05:28Z",
    "timestamp": 1749780328204
  },
  "reference-count": 10,
  "publisher": "Wiley",
  "issue": "5",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2003,
            3,
            12
          ]
        ],
        "date-time": "2003-03-12T00:00:00Z",
        "timestamp": 1047427200000
      },
      "content-version": "vor",
      "delay-in-days": 3967,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1992,
        5
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>The oxidized states of double\u2010stranded, planar (1,4\u2010phenylene)\u2010type ladder polymers are characterized by means of UV/VIS/NIR<jats:ext-link xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"#note1\" /><jats:fn><jats:p>NIR: Near infrared.</jats:p></jats:fn>\n spectroscopy and cyclic voltammetry. The oxidation with antimony pentachloride or iron trichloride proceeds as a two\u2010step process; first, radical cationic (polaronic) species are generated, followed by the formation of dicationic (bipolaronic) ones. Especially the polymeric radical cations formed possess an outstanding chemical stability. The findings of cyclovoltammetric investigations are in full agreement with the chemical oxidation experiments.</jats:p>",
  "DOI": "10.1002/macp.1992.021930511",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        4,
        16
      ]
    ],
    "date-time": "2003-04-16T10:09:37Z",
    "timestamp": 1050487777000
  },
  "page": "1127-1133",
  "source": "Crossref",
  "is-referenced-by-count": 115,
  "title": "Polyarylenes and poly(arylenevinylene)s, 9 The oxidized states of a (1,4\u2010phenylene) ladder polymer",
  "prefix": "10.1002",
  "volume": "193",
  "author": [
    {
      "given": "Ullrich",
      "family": "Scherf",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Angelika",
      "family": "Bohnen",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Klaus",
      "family": "M\u00fcllen",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2003,
        3,
        12
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/marc.1991.030120806"
    },
    {
      "key": "e_1_2_1_2_2",
      "first-page": "213",
      "volume-title": "Handbook of Conducting Polymers",
      "author": "Elsenbaumer R. L.",
      "year": "1986"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.440596"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0032-3861(89)90078-5"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0032-3861(89)90079-7"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-94-009-6440-2_50"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00268948108075251"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0379-6779(91)91206-P"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac00235a057"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/macp.1991.021920802"
    }
  ],
  "container-title": "Die Makromolekulare Chemie",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1992.021930511",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1992.021930511",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        23
      ]
    ],
    "date-time": "2023-10-23T14:26:47Z",
    "timestamp": 1698071207000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/macp.1992.021930511"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1992,
        5
      ]
    ]
  },
  "references-count": 10,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1992,
          5
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/macp.1992.021930511"
  ],
  "URL": "http://dx.doi.org/10.1002/macp.1992.021930511",
  "relation": {},
  "ISSN": [
    "0025-116X",
    "0025-116X"
  ],
  "subject": [],
  "container-title-short": "Makromol. Chem.",
  "published": {
    "date-parts": [
      [
        1992,
        5
      ]
    ]
  }
}