DOI: 10.1002/macp.1990.021910511. Model reactions for the synthesis of poly(1,4‐phenylenevinylene). The palladium‐catalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides

Model reactions for the synthesis of poly(1,4‐phenylenevinylene). The palladium‐catalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides

10.1002/macp.1990.021910511

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractPoly(1,4‐phenylenevinylene) was obtained by reacting dibromoarenes with ethylene in a palladium‐catalyzed reaction. Defects of the polymer structure were elucidated by model reactions. Side reactions in the reaction of halogenated arenes and ethylene or styrene, catalyzed by Pd, could be minimized by low catalyst concentrations and low reaction temperatures. The Pdcatalyzed reaction of aroyl chlorides with ethylene or styrene was probed by model reactions.

Bibliography

Brenda, M., Greiner, A., & Heitz, W. (1990). Model reactions for the synthesis of poly(1,4âphenylenevinylene). The palladiumâcatalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides. Die Makromolekulare Chemie, 191(5), 1083â1100. Portico.

Authors 3

Martin Brenda (first)
Andreas Greiner (additional)
Walter Heitz (additional)

References 15 Referenced 48

{'key': 'e_1_2_1_1_2', 'first-page': '345', 'volume': '27', 'author': 'Heck R. H.', 'year': '1981', 'journal-title': 'Org. React.'} / Org. React. by Heck R. H. (1981)
Jpn. 57207618 (1981) Ashai Glass Co. Ltd.;
{'key': 'e_1_2_1_2_3', 'first-page': '23 139 k', 'volume': '99', 'year': '1983', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1983)
10.1002/macp.1988.021890112
10.1002/marc.1988.030090813
10.1016/S0022-328X(00)82707-2
10.1016/S0022-328X(00)82516-4
10.1016/S0022-328X(00)98836-3
Eur. Pat. Appl. EP 62005 A1 (1982) Ciba‐Geigy AG inv.:A.Spencer
10.1021/jo00409a001
10.1021/jo00406a033
{'key': 'e_1_2_1_11_2', 'volume-title': 'Lehrbuch der Physikalischen Chemie', 'author': 'Wedler G.', 'year': '1985'} / Lehrbuch der Physikalischen Chemie by Wedler G. (1985)
10.1021/jo00430a041
10.1351/pac197850080691
Unpublished resultsA.Greiner W.Heitz

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:07 a.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 2:59 p.m.)
Indexed	1 year, 9 months ago (Nov. 20, 2023, 6:27 p.m.)
Issued	35 years, 4 months ago (May 1, 1990)
Published	35 years, 4 months ago (May 1, 1990)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	35 years, 4 months ago (May 1, 1990)

Funders 0

None

BibTeX

@article{Brenda_1990, title={Model reactions for the synthesis of poly(1,4‐phenylenevinylene). The palladium‐catalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides}, volume={191}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1990.021910511}, DOI={10.1002/macp.1990.021910511}, number={5}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Brenda, Martin and Greiner, Andreas and Heitz, Walter}, year={1990}, month=may, pages={1083–1100} }

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