DOI: 10.1002/macp.1990.021910413. Soluble poly(1,4‐phenyleneethynylene)s

10.1002/macp.1990.021910413

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractNew monomers are described for the synthesis of rod‐like poly(1,4‐phenyleneethynylene)s with long flexible aliphatic side chains. By palladium catalyzed polycondensation soluble polymers with melting points around 100°C could be obtained. The molecular weight was estimated by GPC, VPO and elemental analysis: GPC showed a multimodale distribution with Pn = 9–15. NMR spectra were found to be in agreement with the assumed polymer structure, but signals of the acetylenic carbons could not be detected. A broad, structureless absorption with a maximum at λ = 410 nm is seen in the UV‐VIS‐spectra. The thermal decomposition of the substituted PPE's starts at about 400°C and is comparable to that of unsubstituted PPE in air.

Bibliography

Giesa, R., & Schulz, R. C. (1990). Soluble poly(1,4âphenyleneethynylene)s. Die Makromolekulare Chemie, 191(4), 857â867. Portico.

Authors 2

Reiner Giesa (first)
Rolf C. Schulz (additional)

References 25 Referenced 96

10.1021/cr00078a005
10.1002/zfch.19870270403
10.1063/1.443405
{'issue': '2', 'key': 'e_1_2_1_4_2', 'first-page': '75', 'volume': '24', 'author': 'Lakshmikantham M. V.', 'year': '1983', 'journal-title': 'Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.)'} / Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) by Lakshmikantham M. V. (1983)
10.1246/bcsj.57.752
10.1002/pola.1986.080240924
M.Tateishi K.Aramaki H.Nishihara Chem. Lett.1987 1727(1986) (10.1246/cl.1987.1727)
{'issue': '1', 'key': 'e_1_2_1_8_2', 'first-page': '294', 'volume': '29', 'author': 'Wright M. E.', 'year': '1988', 'journal-title': 'Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.)'} / Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) by Wright M. E. (1988)
10.1021/ma00198a011
10.1002/macp.1987.021880619
10.1002/marc.1987.030080206
10.1002/macp.1987.021881209
10.1002/marc.1988.030090910
10.1002/anie.198902533
10.1002/jlac.19134010103
10.1002/jlac.18812090108
10.1080/00268948808084451
S.Takahashi Y.Kuroyama K.Sonogashira N.Hagihara Synthesis1980 627 (10.1055/s-1980-29145)
10.1021/jo00324a015
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10.1021/jo01074a603
10.1002/macp.1988.021890307
10.1515/znb-1982-1207 / Z. Naturforsch., Teil B by Wrackmeyer B. (1982)
10.1021/jo00134a010
{'key': 'e_1_2_1_22_2', 'first-page': '385', 'volume': '110', 'author': 'Heitz W.', 'year': '1986', 'journal-title': 'Chem.‐Ztg.'} / Chem.‐Ztg. by Heitz W. (1986)

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:06 a.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 5:31 a.m.)
Indexed	1 year, 3 months ago (May 28, 2024, 8:12 p.m.)
Issued	35 years, 5 months ago (April 1, 1990)
Published	35 years, 5 months ago (April 1, 1990)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	35 years, 5 months ago (April 1, 1990)

Funders 0

None

BibTeX

@article{Giesa_1990, title={Soluble poly(1,4‐phenyleneethynylene)s}, volume={191}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1990.021910413}, DOI={10.1002/macp.1990.021910413}, number={4}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Giesa, Reiner and Schulz, Rolf C.}, year={1990}, month=apr, pages={857–867} }

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