DOI: 10.1002/macp.1990.021910327. Polymerization in inverse microemulsions, 1. Homopolymerizations of water‐ and oil‐soluble monomers in inverse microemulsions

Polymerization in inverse microemulsions, 1. Homopolymerizations of water‐ and oil‐soluble monomers in inverse microemulsions

10.1002/macp.1990.021910327

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractHomopolymerization of acrylamide (AAM) as well as of methyl methacrylate (MMA) in inverse microemulsions was studied and compared with the homopolymerization of these monomers in homogeneous systems. Initiators with various solubilities in water were used. Homopolymerization of AAM in inverse microemulsion was found to be an extremely fast reaction independent of the type of the initiator used. It is assumed that polymerization takes place predominantly in the interlayer between the aqueous phase and the oil phase. In the case of MMA the homopolymerization in inverse emulsion is a relatively slow process. It is assumed that polymerization of MMA in the systems studied takes place in the oil macrophase.

Bibliography

VaÅ¡kovÃ¡, V., JuraniÄovÃ¡, V., & BartoÅ, J. (1990). Polymerization in inverse microemulsions, 1. Homopolymerizations of waterâ and oilâsoluble monomers in inverse microemulsions. Die Makromolekulare Chemie, 191(3), 717â723. Portico.

Authors 3

Viera Vašková (first)
Viera Juraničová (additional)
Jaroslav Bartoň (additional)

References 18 Referenced 37

10.1007/978-1-4757-6424-6
10.1002/anie.198504393
10.1002/pol.1985.170230120
F.Candau Y. S.Leong G.Poyet S. J.Candau “Physics of Amphiphiles: Micelles Vesicles and Microemulsions” XC Corso (1985);
10.1016/0021-9797(84)90017-1
10.1021/j100210a001
10.1007/BF01417464
10.1002/pola.1989.080270704
{'key': 'e_1_2_1_6_2', 'first-page': '3', 'volume': '26', 'author': 'Kurenkov V. F.', 'year': '1984', 'journal-title': 'Vysokomol. Soedin. Ser. A'} / Vysokomol. Soedin. Ser. A by Kurenkov V. F. (1984)
10.1002/macp.1985.021860920
10.1002/macp.1988.021890322
10.1002/macp.1988.021890323
{'key': 'e_1_2_1_9_2', 'first-page': '435', 'volume': '40', 'author': 'Vas̆ková V.', 'year': '1986', 'journal-title': 'Chem. Zvesti'} / Chem. Zvesti by Vas̆ková V. (1986)
10.1051/jcp/1987841095 / J. Chim. Phys. by Candau F. (1987)
F. V.Di Stefano MCS Thesis Lehigh University Bethlehem USA (1981)
10.1021/j100296a039
{'key': 'e_1_2_1_13_2', 'first-page': 'II‐4', 'volume-title': 'Polymer Handbook', 'author': 'Brandrup J.', 'year': '1975'} / Polymer Handbook by Brandrup J. (1975)
I.Lacík unpublished results

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:06 a.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 11:17 p.m.)
Indexed	1 year, 9 months ago (Nov. 20, 2023, 8:19 p.m.)
Issued	35 years, 5 months ago (March 1, 1990)
Published	35 years, 5 months ago (March 1, 1990)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	35 years, 5 months ago (March 1, 1990)

Funders 0

None

BibTeX

@article{Va_kov__1990, title={Polymerization in inverse microemulsions, 1. Homopolymerizations of water‐ and oil‐soluble monomers in inverse microemulsions}, volume={191}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1990.021910327}, DOI={10.1002/macp.1990.021910327}, number={3}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Vašková, Viera and Juraničová, Viera and Bartoň, Jaroslav}, year={1990}, month=mar, pages={717–723} }

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