DOI: 10.1002/macp.1987.021880522. Morphology of nylon 6 spherulites in bulk

Morphology of nylon 6 spherulites in bulk

10.1002/macp.1987.021880522

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractA method of obtaining good quality ultrathin sections from nylon 6 bulk samples has been developed by using a special embedding technique and cryo‐ultramicrotomy. The morphologies of nylon 6 processed by compression and injection molding and of reaction injection molded nylon 6 were studied in ultrathin sections of bulk samples by means of transmission electron microscopy. It was established that the spherulites of nylon 6 in bulk are built up from long flat ribbonlike lamellae. The thickness of the lamellae is in the range 50–60 Å. The width varies from 150 to 600 Å and depends on the type of nylon 6 and the method of processing. The length of the lamellae is relatively large approaching spherulite radii, extending often from the point of their origin up to the spherulite borders. Three or four neighboring lamellae within spherulites usually show similar orientation of their flat faces and form domains which can easily be mistaken for fibrils in light microscopy or low resolution electron microscopy.

Bibliography

Galeski, A., Argon, A. S., & Cohen, R. E. (1987). Morphology of nylon 6 spherulites in bulk. Die Makromolekulare Chemie, 188(5), 1195â1204. Portico.

Authors 3

Andrzej Galeski (first)
Ali S. Argon (additional)
Robert E. Cohen (additional)

References 33 Referenced 33

10.1002/pol.1955.120188713
10.1295/koron1944.15.14
{'key': 'e_1_2_1_3_2', 'volume-title': 'Fifth International Conference for Electron Microscopy', 'author': 'Spit B. J.', 'year': '1962'} / Fifth International Conference for Electron Microscopy by Spit B. J. (1962)
{'key': 'e_1_2_1_4_2', 'first-page': '161', 'volume': '18', 'author': 'Spit B. J.', 'year': '1967', 'journal-title': 'Faserforsch. Textiltech.'} / Faserforsch. Textiltech. by Spit B. J. (1967)
{'key': 'e_1_2_1_5_2', 'first-page': '309', 'volume': '26', 'author': 'Schultz E.', 'year': '1975', 'journal-title': 'Faserforsch. Textiltech.'} / Faserforsch. Textiltech. by Schultz E. (1975)
10.1007/BF00719925
10.1002/pol.1960.1204414416
{'key': 'e_1_2_1_8_2', 'first-page': '983', 'volume': '52', 'author': 'Fichera A. M.', 'year': '1970', 'journal-title': 'Chim. Ind. (Milan)'} / Chim. Ind. (Milan) by Fichera A. M. (1970)
10.1007/BF00599094
10.1007/BF01513552
10.1002/macp.1974.021750322
10.1002/app.1977.070210322
{'key': 'e_1_2_1_12_2', 'first-page': '608', 'volume': '1', 'author': 'Roldan L. G.', 'year': '1963', 'journal-title': 'J. Polym. Sci., Part B'} / J. Polym. Sci., Part B by Roldan L. G. (1963)
10.1007/BF00552445
10.1002/pol.1958.1202811712
10.1002/pol.1960.1204714907
10.1002/pol.1959.1203813313
10.1002/pol.1962.1206217318
10.1063/1.1735884
{'key': 'e_1_2_1_19_2', 'first-page': '792', 'volume': '59', 'author': 'Dietl J. J.', 'year': '1969', 'journal-title': 'Kunststoffe'} / Kunststoffe by Dietl J. J. (1969)
10.1135/cccc19640309
J. D.Gabbert A. Y.Garner R. M.Hedrick paper presented at SAE International Congress & Exposition Detroit Michigan USA Feb. 1982 alsoSAE Tech. Pap. Ser.820420
10.1002/pol.1965.100030221
10.6028/jres.065A.035
10.1007/BF00541393
10.1016/0001-6160(53)90126-6
10.1063/1.1713606
10.1063/1.1713607
10.1016/0022-0248(68)90102-4
{'key': 'e_1_2_1_28_2', 'volume-title': 'The Solid‐Liquid Interface', 'author': 'Woodruff D. P.', 'year': '1973'} / The Solid‐Liquid Interface by Woodruff D. P. (1973)
10.1002/pol.1983.130210611
10.1098/rspa.1981.0115
{'key': 'e_1_2_1_31_2', 'first-page': '324', 'volume-title': 'Macromolecular Physics', 'author': 'Wunderlich B.', 'year': '1973'} / Macromolecular Physics by Wunderlich B. (1973)

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:27 a.m.)
Deposited	1 year, 10 months ago (Oct. 21, 2023, 3:47 p.m.)
Indexed	1 year, 6 months ago (Feb. 13, 2024, 5:20 a.m.)
Issued	38 years, 4 months ago (May 1, 1987)
Published	38 years, 4 months ago (May 1, 1987)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	38 years, 4 months ago (May 1, 1987)

Funders 0

None

BibTeX

@article{Galeski_1987, title={Morphology of nylon 6 spherulites in bulk}, volume={188}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1987.021880522}, DOI={10.1002/macp.1987.021880522}, number={5}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Galeski, Andrzej and Argon, Ali S. and Cohen, Robert E.}, year={1987}, month=may, pages={1195–1204} }

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