DOI: 10.1002/macp.1987.021880311. Polyacrylate graft polymers prepared by grafting of monomethoxypoly(ethylene oxide) homopolymers onto acrylic acid: Self‐gelling polymers

Polyacrylate graft polymers prepared by grafting of monomethoxypoly(ethylene oxide) homopolymers onto acrylic acid: Self‐gelling polymers

10.1002/macp.1987.021880311

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractPolyacrylates of monomethoxypoly(ethylene oxide)Systematic name for MePEO: α‐hydro‐ω‐methoxypoly(oxyethylene). (MePEO) were prepared by grafting MePEO on prepolymerized acryloyl chloride polymers of different molecular weights. Copolymers with carboxyl groups were also prepared by the addition of both water and MePEO. The polymers spontaneously form irreversible gels in water as soon as the degree of polymerization exceeds a certain limit. This gel formation confirms preceding results on similar polymers obtained by polymerization of MePEO acrylate and methacrylate macromonomers. It is concluded that the gelification phenomenon is not due to chemical cross‐linking but rather to the presence of a high density of strongly interacting grafts of PEO on the polymer backbone. This new type of self‐gelling system is considered to be of special interest.

Bibliography

Gramain, P., & Frere, Y. (1987). Polyacrylate graft polymers prepared by grafting of monomethoxypoly(ethylene oxide) homopolymers onto acrylic acid: Selfâgelling polymers. Die Makromolekulare Chemie, 188(3), 593â598. Portico.

Authors 2

Philippe Gramain (first)
Yves Frere (additional)

References 9 Referenced 24

{'key': 'e_1_2_1_1_2', 'first-page': '16', 'volume': '27', 'author': 'Gramain Ph.', 'year': '1986', 'journal-title': 'Polym. Commun.'} / Polym. Commun. by Gramain Ph. (1986)
10.1007/BF00264152
{'key': 'e_1_2_1_3_2', 'first-page': '235', 'volume-title': '27° symposium international sur les macromolécules', 'author': 'Masson P.', 'year': '1981'} / 27° symposium international sur les macromolécules by Masson P. (1981)
{'key': 'e_1_2_1_4_2', 'first-page': '235', 'volume': '6', 'author': 'Reveillon A.', 'year': '1982', 'journal-title': 'Polym. Bull.'} / Polym. Bull. by Reveillon A. (1982)
10.1002/apmc.1982.051020112
{'key': 'e_1_2_1_6_2', 'first-page': '290', 'volume-title': 'Encyclopedia of polymer science and technology', 'year': '1964'} / Encyclopedia of polymer science and technology (1964)
{'key': 'e_1_2_1_7_2', 'first-page': '757', 'volume-title': 'Encyclopedia of polymer science and technology', 'year': '1964'} / Encyclopedia of polymer science and technology (1964)
10.1002/app.1973.070171201
10.1002/app.1972.070161118

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:27 a.m.)
Deposited	1 year, 10 months ago (Oct. 21, 2023, 3:41 p.m.)
Indexed	1 year, 9 months ago (Oct. 31, 2023, 10:04 a.m.)
Issued	38 years, 5 months ago (March 1, 1987)
Published	38 years, 5 months ago (March 1, 1987)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	38 years, 5 months ago (March 1, 1987)

Funders 0

None

BibTeX

@article{Gramain_1987, title={Polyacrylate graft polymers prepared by grafting of monomethoxypoly(ethylene oxide) homopolymers onto acrylic acid: Self‐gelling polymers}, volume={188}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1987.021880311}, DOI={10.1002/macp.1987.021880311}, number={3}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Gramain, Philippe and Frere, Yves}, year={1987}, month=mar, pages={593–598} }

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