DOI: 10.1002/macp.1983.021841113. Small angle neutron scattering studies of poly(ethylene oxide) in the melt

Small angle neutron scattering studies of poly(ethylene oxide) in the melt

10.1002/macp.1983.021841113

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractThe neutron scattering from mixtures of deuterated and undeuterated poly(ethylene oxide), (D‐PEO, H‐PEO), in the small angle and intermediate angle region has been measured in the melt. We found no indications of a molecular segregation. The value of molecular weight evaluated agreed with that obtained by other methods. For a sample with a molar mass of 120000 g/mol the radius of gyration 〈rw2〉1/2 was found to be 13,6 nm, which corresponds to a characteristic ratio of C = 6,9. The form factor of a single chain can be described by the Debye equation for a random coil with the same unperturbed dimensions. Our results are compared with rotational isomeric state calculations and measurements in solvents.

Bibliography

Kugler, J., Fischer, E. W., Peuscher, M., & Eisenbach, C. D. (1983). Small angle neutron scattering studies of poly(ethylene oxide) in the melt. Die Makromolekulare Chemie, 184(11), 2325â2334. Portico.

Authors 4

Joachim Kugler (first)
Erhard W. Fischer (additional)
Manfred Peuscher (additional)
Claus D. Eisenbach (additional)

References 41 Referenced 47

R. G.Kirste “Jahresbericht des SFB 41 für 1969” p.47(1970)
10.1002/macp.1972.021620128
10.1016/0022-3093(78)90104-7
10.1007/978-94-009-9646-5_5
P.Herchenröder.Thesis Mainz 1978
10.1016/0032-3861(78)90220-3
10.1002/bip.1969.360080514 / Statistical Mechanics of Chain Molecules by Flory P. J. (1969)
10.1021/ma60050a022
10.1002/app.1959.070010110
10.1021/ja00437a006
J.Kugler U.Struth K.Hahn P.Herchenröder R.Born E. W.Fischer Neutron Scattering Studies on the Crystallization of Poly(ethylene oxide) in preparation
10.1002/marc.1980.030010211
M.Peuscher G.Wegner C. D.Eisenbach Synthesis of Poly(ethylene‐d4 oxide) Makromol. Chem. in preparation
C. D.Eisenbach M.Peuscher Syntheses of High Molecular Weight Poly(ethylene oxide) Polymerization Kinetics and Polymer Characterization Makromol. Chem. in preparation
10.1016/0014-3057(77)90186-0
M.Peuscher C. D.Eisenbach Gel Permeation Chromatography of Poly(ethylene oxide) J. Polym. Sci. in preparation
M.Peuscher C. D.Eisenbach Solution Properties of Narrowly Distributed High Molecular Weight Poly(ethylene oxide): Viscosity/Molecular Weight Relations and Unperturbed Dimensions Macromolecules in preparation
{'key': 'e_1_2_1_18_2', 'first-page': '61', 'volume-title': 'Macromolecules Physics', 'author': 'Wunderlich B.', 'year': '1976'} / Macromolecules Physics by Wunderlich B. (1976)
10.1107/S0021889876011394
Neutron Beam Facilities at the HFR ILL Grenoble 1981
R. E.Ghosh ILL Report 81 GH 29T Grenoble 1981
W.Marshall S.Lovesey “Theory of Thermal Neutron Scattering” Oxford1971
10.1007/BF00285134
{'key': 'e_1_2_1_24_2', 'first-page': '67', 'volume-title': 'Scaling Concepts in Polymer Physics', 'author': 'de Gennes P. G.', 'year': '1979'} / Scaling Concepts in Polymer Physics by de Gennes P. G. (1979)
10.1002/pol.1980.180180417
10.1002/macp.1973.021680122
10.1021/j150451a002
{'key': 'e_1_2_1_28_2', 'volume-title': 'Macromolecules in Solution', 'author': 'Morawetz H.', 'year': '1965'} / Macromolecules in Solution by Morawetz H. (1965)
10.1098/rspa.1976.0147
10.1002/cjce.5450580513
10.1016/0032-3861(82)90121-5
10.1002/pol.1969.160070311
M.Peuscher Thesis Freiburg 1982
10.1016/0032-3861(67)90039-0
10.1002/pol.1978.180160312
10.1002/pol.1982.180200907
10.1021/ja01085a001
10.1039/f29726801111
10.1021/ma60035a005
10.1021/ja00968a005
D. Y.Yoon private communication

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 7:42 p.m.)
Deposited	1 year, 10 months ago (Oct. 20, 2023, 4:19 a.m.)
Indexed	5 months, 2 weeks ago (March 19, 2025, 8:53 a.m.)
Issued	41 years, 10 months ago (Nov. 1, 1983)
Published	41 years, 10 months ago (Nov. 1, 1983)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	41 years, 10 months ago (Nov. 1, 1983)

Funders 0

None

BibTeX

@article{Kugler_1983, title={Small angle neutron scattering studies of poly(ethylene oxide) in the melt}, volume={184}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1983.021841113}, DOI={10.1002/macp.1983.021841113}, number={11}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Kugler, Joachim and Fischer, Erhard W. and Peuscher, Manfred and Eisenbach, Claus D.}, year={1983}, month=nov, pages={2325–2334} }

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