DOI: 10.1002/macp.1983.021841111. Study of photopolymers, 18. Synthesis and photochemical reaction of novel polymers with pendant photosensitive and photosensitizing groups

Study of photopolymers, 18. Synthesis and photochemical reaction of novel polymers with pendant photosensitive and photosensitizing groups

10.1002/macp.1983.021841111

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractSelf‐sensitized photosensitive polymers with pendant photosensitive and photosensitizing groups were prepared by reaction of polystyrene containing pendant chloromethyl and photosensitizing groups, with the potassium salts of photosensitive compounds such as cinnamic acid, crotonic acid, or 2‐cyano‐3‐(α‐styryl)acrylic acid in DMF using tetrabutylammonium bromide as phase transfer catalyst. The photochemical reactivity and the practical photosensitivity of the resulting polymers were measured by IR spectrometry and by the gray‐scale method, respectively. Pendant 4‐nitro‐1‐naphthyloxy and 4‐nitrophenoxy groups in the polymers show the highest photosensitizing activity for pendant cinnamoyl groups. The photochemical reactivity and the sensitivity of these polymers are affected by the content of photosensitizing units in the polymer skeleton, the glass transition temperature of the polymers, however, is not influenced. Pendant 2‐benzoylbenzoyl groups act as excellent photosensitizers for pendant crotonoyl groups, however, the photochemical reactivity of this polymer was found to be lower than that of the polymer with pendant cinnamoyl and suitable photosensitizing groups. Pendant 2‐cyano‐3‐(α‐styryl)acryloyl groups in the polymer, which exhibit high photochemical activity, are also sensitized by pendant methyleosin moieties.

Bibliography

Lizawa, T., Nishikubo, T., Takahashi, E., & Hasegawa, M. (1983). Study of photopolymers, 18. Synthesis and photochemical reaction of novel polymers with pendant photosensitive and photosensitizing groups. Die Makromolekulare Chemie, 184(11), 2297â2312. Portico.

Authors 4

Takashi Lizawa (first)
Tadatomi Nishikubo (additional)
Eiji Takahashi (additional)
Masaki Hasegawa (additional)

References 26 Referenced 22

{'key': 'e_1_2_1_1_2', 'volume-title': 'Photosensitive Polymers', 'author': 'Nagamatsu G.', 'year': '1977'} / Photosensitive Polymers by Nagamatsu G. (1977)
10.1002/app.1959.070020607
10.1002/app.1974.070180709
10.1002/pol.1969.150070122
10.1002/pol.1972.150100614
10.1002/pol.1976.130140405
10.1002/pol.1981.130190404
10.1002/marc.1982.030030601
10.1295/koron.40.425
10.1002/marc.1980.030011212
{'key': 'e_1_2_1_11_2', 'first-page': '383', 'volume-title': 'Micro Quantitative Analysis', 'author': 'Nara A.', 'year': '1968'} / Micro Quantitative Analysis by Nara A. (1968)
10.1002/pol.1967.150051112
10.1021/jo01325a006
10.1246/bcsj.42.905
10.1246/bcsj.41.1977
10.1002/pol.1983.170210714
{'key': 'e_1_2_1_17_2', 'first-page': '35', 'volume': '1973', 'author': 'Nishikubo T.', 'journal-title': 'Nippon Kagaku Kaishi'} / Nippon Kagaku Kaishi by Nishikubo T.
{'key': 'e_1_2_1_17_3', 'first-page': '160375q', 'volume': '78', 'year': '1973', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1973)
10.1002/pol.1978.170161101
10.1295/koron.37.549
{'key': 'e_1_2_1_19_3', 'first-page': '187088v', 'volume': '93', 'year': '1980', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1980)
10.1002/pol.1981.170191105
10.1002/app.1982.070270619
10.1246/nikkashi1898.69.4_761
{'key': 'e_1_2_1_22_3', 'first-page': '20235h', 'volume': '65', 'year': '1966', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1966)
10.1002/pol.1961.1205516229

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 7:42 p.m.)
Deposited	1 year, 10 months ago (Oct. 20, 2023, 4:19 a.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 5:19 a.m.)
Issued	41 years, 10 months ago (Nov. 1, 1983)
Published	41 years, 10 months ago (Nov. 1, 1983)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	41 years, 10 months ago (Nov. 1, 1983)

Funders 0

None

BibTeX

@article{Lizawa_1983, title={Study of photopolymers, 18. Synthesis and photochemical reaction of novel polymers with pendant photosensitive and photosensitizing groups}, volume={184}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1983.021841111}, DOI={10.1002/macp.1983.021841111}, number={11}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Lizawa, Takashi and Nishikubo, Tadatomi and Takahashi, Eiji and Hasegawa, Masaki}, year={1983}, month=nov, pages={2297–2312} }

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