DOI: 10.1002/macp.1962.020530102. Studies on amylose and its derivatives. Part III. The effect of temperature on the intrinsic viscosities of amylose in several solvents

Studies on amylose and its derivatives. Part III. The effect of temperature on the intrinsic viscosities of amylose in several solvents

10.1002/macp.1962.020530102

Crossref journal-article

Wiley

Die Makromolekulare Chemie (311)

Abstract

AbstractThe intrinsic viscosities of several amylose fractions dissolved in dimethyl sulphoxide (DMSO), formamide and 0.5 M KCl have been measured in the temperature range 25 to 55°C. The temperature coefficient of viscosity was found to be negative for amylose in DMSO and formamide, but was negligible in 0.5 M KCl. A recent extension of the FLORY solution theory proposed by KURATA and STOCKMAYER has been used successfully to describe the behaviour of amylose solutions, and from this an equation representing Θ conditions for amylose at 25°C. is proposed.

Bibliography

Cowie, J. M. G. (1962). Studies on amylose and its derivatives. Part III. The effect of temperature on the intrinsic viscosities of amylose in several solvents. Die Makromolekulare Chemie, 53(1), 13â20. Portico.

Authors 1

J. M. G. Cowie (first)

References 16 Referenced 22

10.1021/ja01149a002
10.1021/ja01149a003
10.1021/ja01128a031
10.1002/pol.1959.1204113814
{'key': 'e_1_2_1_5_2', 'first-page': '207', 'volume': '20', 'author': 'Rao M. R.', 'year': '1961', 'journal-title': 'J. sci. Ind. Res. India'} / J. sci. Ind. Res. India by Rao M. R. (1961)
10.1002/pol.1958.1202711519
10.1016/0095-8522(59)90058-3
10.1002/macp.1960.020420123
M.KurataandW. H.Stockmayer IUPAC.‐Symposium on Macromolecular Chemistry Montreal (1961).
10.1021/ac60159a015
10.1139/v61-024
{'key': 'e_1_2_1_12_2', 'first-page': '227', 'volume': '18', 'author': 'Brown W.', 'year': '1961', 'journal-title': 'Ark. Kemi'} / Ark. Kemi by Brown W. (1961)
W. H.Stockmayer personal communication.
10.1063/1.1743472
10.1021/ja01522a077
{'key': 'e_1_2_1_16_2', 'volume-title': 'Principles of Polymer Chemistry', 'author': 'Flory P. J.', 'year': '1953'} / Principles of Polymer Chemistry by Flory P. J. (1953)

Dates

Type	When
Created	22 years, 4 months ago (April 16, 2003, 6:45 a.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 1:50 p.m.)
Indexed	1 year, 9 months ago (Nov. 20, 2023, 9:02 p.m.)
Issued	63 years, 8 months ago (Jan. 1, 1962)
Published	63 years, 8 months ago (Jan. 1, 1962)
Published Online	22 years, 5 months ago (March 12, 2003)
Published Print	63 years, 8 months ago (Jan. 1, 1962)

Funders 0

None

BibTeX

@article{Cowie_1962, title={Studies on amylose and its derivatives. Part III. The effect of temperature on the intrinsic viscosities of amylose in several solvents}, volume={53}, ISSN={0025-116X}, url={http://dx.doi.org/10.1002/macp.1962.020530102}, DOI={10.1002/macp.1962.020530102}, number={1}, journal={Die Makromolekulare Chemie}, publisher={Wiley}, author={Cowie, J. M. G.}, year={1962}, month=jan, pages={13–20} }

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