DOI: 10.1002/kin.550250806. A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K

A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K

10.1002/kin.550250806

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractA variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule−1 s−1: CH3F, (3.7 ± 0.8) × 10−11, CH3Cl, (3.3 ± 0.7) × 10−11; CH3Br, (3.0 ± 0.7) × 10−11; CF2H2, (4.3 ± 0.9) × 10−12; CO, (5.5 ± 1.0) × 10−13 (in 700 torr total pressure of N2 diluent); CF3H, (1.4 ± 0.4) × 10−13; CF3CCl2H (HCFC‐123), (1.2 ± 0.4) × 10−12; CF3CFH2 (HFC‐134a), (1.3 ± 0.3) × 10−12, CHF2CHF2 (HFC‐134), (1.0 ± 0.3) × 10−12; CF2ClCH3 (HCFC‐42b), (3.9 ± 0.9) × 10−12, CF2HCH3 (HFC‐152a), (1.7 ± 0.4) × 10−11; and CF3CF2H (HFC‐125), (3.5 ± 0.8) × 10−13. Quoted errors are statistical uncertainties (2σ). For rate constants derived using relative rate techniques, an additional uncertainty has been added to account for potential systematic errors in the reference rate constants used. Experiments were performed at 295 ± 2 K. Results are discussed with respect to the previous literature data and to the interpretation of laboratory studies of the atmospheric chemistry of HCFCs and HFCs. © 1993 John Wiley & Sons, Inc.

Bibliography

Wallington, T. J., Hurley, M. D., Shi, J., Maricq, M. M., Sehested, J., Nielsen, O. J., & Ellermann, T. (1993). A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 Â± 2 K. International Journal of Chemical Kinetics, 25(8), 651â665. Portico.

Authors 7

Timothy J. Wallington (first)
Michael D. Hurley (additional)
Jichun Shi (additional)
M. Matti Maricq (additional)
Jens Sehested (additional)
Ole J. Nielsen (additional)
Thomas Ellermann (additional)

References 28 Referenced 64

Alternative Fluorocarbon Environmental Acceptability Study Report World Meteorological Organization Report No. 20 1989 Vol. II Appendix: AFEAS Report.
10.1016/0009-2614(92)85228-3
10.1007/BF00114752
{'key': 'e_1_2_1_5_2', 'first-page': '987', 'volume': '96', 'author': 'Maricq M. M.', 'year': '1992', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. by Maricq M. M. (1992)
10.1063/1.1135753
10.1021/j100372a052
10.1016/0009-2614(92)80051-C
10.1021/j100205a048
10.1016/0009-2614(91)90480-W
O. J.Nielsen unpublished data.
10.1002/kin.550200107
10.1021/j100175a054
{'key': 'e_1_2_1_14_2', 'first-page': '169', 'volume': '89', 'author': 'Wagner H.', 'year': '1971', 'journal-title': 'Anales Assoc. Quin. Argentina'} / Anales Assoc. Quin. Argentina by Wagner H. (1971)
10.1016/0009-2614(72)80008-3
10.1139/v73-535
10.1016/0009-2614(82)83438-6
10.1016/0009-2614(88)87462-1
10.1002/bbpc.19890931016
10.1002/kin.550240704
10.1021/j150617a017
10.1016/0301-0104(83)85058-7
10.1039/f29858100443
10.1016/0301-0104(85)85070-9
10.1016/0009-2614(92)85432-A
10.1063/1.555639 / J. Phys. Chem. Ref. Data by Baulch D. L. (1981)
O. J.Nielsen unpublished data.
10.1021/j100191a037
10.1002/kin.550241111

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 11 p.m.)
Deposited	1 year, 9 months ago (Oct. 26, 2023, 12:16 a.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 1:30 p.m.)
Issued	32 years ago (Aug. 1, 1993)
Published	32 years ago (Aug. 1, 1993)
Published Online	20 years, 10 months ago (Sept. 30, 2004)
Published Print	32 years ago (Aug. 1, 1993)

Funders 0

None

BibTeX

@article{Wallington_1993, title={A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K}, volume={25}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550250806}, DOI={10.1002/kin.550250806}, number={8}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Wallington, Timothy J. and Hurley, Michael D. and Shi, Jichun and Maricq, M. Matti and Sehested, Jens and Nielsen, Ole J. and Ellermann, Thomas}, year={1993}, month=aug, pages={651–665} }

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