DOI: 10.1002/kin.550220807. Rate constants for the gas‐phase reactions of O<sub>3</sub> with a series of monoterpenes and related compounds at 296 ± 2 K

Rate constants for the gas‐phase reactions of O3 with a series of monoterpenes and related compounds at 296 ± 2 K

10.1002/kin.550220807

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractRate constants for the gas‐phase reactions of O3 with a series of monoterpenes and related compounds have been determined at 296 ± 2 K and 740 torr total pressure of air or O2 using a combination of absolute and relative rate techniques. Good agreement between the absolute and relative rate data was observed, and the rate constants obtained (in units of 10−17 cm3 molecule−1 s−1) were: α‐pinene, 8.7; β‐pinene, 1.5; Δ3‐carene, 3.8; 2‐carene, 24; sabinene, 8.8; d‐limonene, 21; γ‐terpinene, 14; terpinolene, 140; α‐phellandrene, 190; α‐terpinene, 870; myrcene, 49; trans‐ocimene, 56; p‐cymene, <0.005; and 1,8‐cineole, <0.015. While these rate constants for α‐ and β‐pinene and sabinene are in good agreement with recent absolute and relative rate determinations, those for the other monoterpenes are generally lower than the literature data by factors of ca. 2–10. The measured rate constants for the monoterpenes are reasonably consistent with predictions based upon the number and positions of the substituent groups around the 〉CC〈 bond(s).

Bibliography

Atkinson, R., Hasegawa, D., & Aschmann, S. M. (1990). Rate constants for the gasâphase reactions of O3 with a series of monoterpenes and related compounds at 296 Â± 2 K. International Journal of Chemical Kinetics, 22(8), 871â887. Portico.

Authors 3

Roger Atkinson (first)
David Hasegawa (additional)
Sara M. Aschmann (additional)

References 44 Referenced 174

10.1029/RG017i005p00937
P. R.Zimmerman Tampa Bay area photochemical oxidant study. Final Report Appendix C. Determination of emission rates of hydrocarbons from indigenous species of vegetation in the Tampa/St. Petersburg Florida area. EPA 904/9‐77‐028 U.S. Environmental Protection Agency Atlanta Georgia February1979.
10.1104/pp.65.5.797
10.1086/botanicalgazette.143.3.2474826
10.1029/JC088iC15p10667
10.1029/JC088iC15p10679
10.1016/0004-6981(85)90131-3
10.1021/es00134a011
10.1029/JD093iD02p01407
10.1016/0045-6535(88)90223-8
10.1029/JD093iD04p03751
10.1016/0004-6981(88)90497-0
S.Juuti J.Arey andR.Atkinson J. Geophys. Res. in press (1990).
J.Arey A. M.Winer R.Atkinson S. M.Aschmann W. D.Long C. L.Morrison andD. M.Olszyk J. Geophys. Res. to be submitted for publication(1990).
10.1029/GL005i008p00679
10.1016/0004-6981(87)90108-9
10.1021/j100555a024
10.1021/es00106a004
10.1002/kin.550180303
R.Atkinson S. M.Aschmann andJ.Arey Atmos. Environ. in press.
{'key': 'e_1_2_1_22_2', 'first-page': '1', 'author': 'Atkinson R.', 'year': '1989', 'journal-title': 'J. Phys. Chem. Ref. Data'} / J. Phys. Chem. Ref. Data by Atkinson R. (1989)
10.1021/es00123a016
10.1021/es00132a009
10.1021/j100323a028
10.1021/j100340a015
10.1021/ba-1972-0113.ch008
10.1080/00139307409437404
{'key': 'e_1_2_1_29_2', 'first-page': '183', 'volume': '1', 'author': 'Grimsrud E. P.', 'year': '1975', 'journal-title': 'Int. J. Chem. Kinet., Symp.'} / Int. J. Chem. Kinet., Symp. by Grimsrud E. P. (1975)
10.1016/0004-6981(82)90187-1
10.1021/cr00063a002
10.1007/BF00048331
10.1002/kin.550140103
10.1021/j100560a002
10.1021/ja00458a033
10.1002/kin.550101003
10.1016/0009-2614(80)80326-5
10.1021/ja00403a031
10.1021/j100288a035
10.1021/j100288a036
10.1002/kin.550060509
10.1021/j100614a004
{'key': 'e_1_2_1_43_2', 'volume-title': 'Identification of Essential Oils by Ion Trap Mass Spectrometry', 'author': 'Adams R. P.', 'year': '1989'} / Identification of Essential Oils by Ion Trap Mass Spectrometry by Adams R. P. (1989)
10.1016/0960-1686(90)90438-S
10.1021/j150664a061

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 10:51 p.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 1:51 p.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 1:52 p.m.)
Issued	35 years ago (Aug. 1, 1990)
Published	35 years ago (Aug. 1, 1990)
Published Online	20 years, 10 months ago (Sept. 30, 2004)
Published Print	35 years ago (Aug. 1, 1990)

Funders 0

None

BibTeX

@article{Atkinson_1990, title={Rate constants for the gas‐phase reactions of O3 with a series of monoterpenes and related compounds at 296 ± 2 K}, volume={22}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550220807}, DOI={10.1002/kin.550220807}, number={8}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Atkinson, Roger and Hasegawa, David and Aschmann, Sara M.}, year={1990}, month=aug, pages={871–887} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        2
      ]
    ],
    "date-time": "2025-07-02T17:52:03Z",
    "timestamp": 1751478723878
  },
  "reference-count": 44,
  "publisher": "Wiley",
  "issue": "8",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2004,
            9,
            30
          ]
        ],
        "date-time": "2004-09-30T00:00:00Z",
        "timestamp": 1096502400000
      },
      "content-version": "vor",
      "delay-in-days": 5174,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1990,
        8
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Rate constants for the gas\u2010phase reactions of O<jats:sub>3</jats:sub> with a series of monoterpenes and related compounds have been determined at 296 \u00b1 2 K and 740 torr total pressure of air or O<jats:sub>2</jats:sub> using a combination of absolute and relative rate techniques. Good agreement between the absolute and relative rate data was observed, and the rate constants obtained (in units of 10<jats:sup>\u221217</jats:sup> cm<jats:sup>3</jats:sup> molecule<jats:sup>\u22121</jats:sup> s<jats:sup>\u22121</jats:sup>) were: \u03b1\u2010pinene, 8.7; \u03b2\u2010pinene, 1.5; \u0394<jats:sup>3</jats:sup>\u2010carene, 3.8; 2\u2010carene, 24; sabinene, 8.8; <jats:italic>d</jats:italic>\u2010limonene, 21; \u03b3\u2010terpinene, 14; terpinolene, 140; \u03b1\u2010phellandrene, 190; \u03b1\u2010terpinene, 870; myrcene, 49; <jats:italic>trans</jats:italic>\u2010ocimene, 56; <jats:italic>p</jats:italic>\u2010cymene, &lt;0.005; and 1,8\u2010cineole, &lt;0.015. While these rate constants for \u03b1\u2010 and \u03b2\u2010pinene and sabinene are in good agreement with recent absolute and relative rate determinations, those for the other monoterpenes are generally lower than the literature data by factors of ca. 2\u201310. The measured rate constants for the monoterpenes are reasonably consistent with predictions based upon the number and positions of the substituent groups around the \u3009C\uf8feC\u3008 bond(s).</jats:p>",
  "DOI": "10.1002/kin.550220807",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        2
      ]
    ],
    "date-time": "2005-01-02T03:51:14Z",
    "timestamp": 1104637874000
  },
  "page": "871-887",
  "source": "Crossref",
  "is-referenced-by-count": 174,
  "title": "Rate constants for the gas\u2010phase reactions of O<sub>3</sub> with a series of monoterpenes and related compounds at 296 \u00b1 2 K",
  "prefix": "10.1002",
  "volume": "22",
  "author": [
    {
      "given": "Roger",
      "family": "Atkinson",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "David",
      "family": "Hasegawa",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Sara M.",
      "family": "Aschmann",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2004,
        9,
        30
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/RG017i005p00937"
    },
    {
      "key": "e_1_2_1_3_2",
      "unstructured": "P. R.Zimmerman Tampa Bay area photochemical oxidant study. Final Report Appendix C. Determination of emission rates of hydrocarbons from indigenous species of vegetation in the Tampa/St. Petersburg Florida area. EPA 904/9\u201077\u2010028 U.S. Environmental Protection Agency Atlanta Georgia February1979."
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1104/pp.65.5.797"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1086/botanicalgazette.143.3.2474826"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JC088iC15p10667"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JC088iC15p10679"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(85)90131-3"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00134a011"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD093iD02p01407"
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0045-6535(88)90223-8"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD093iD04p03751"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(88)90497-0"
    },
    {
      "key": "e_1_2_1_14_2",
      "unstructured": "S.Juuti J.Arey andR.Atkinson J. Geophys. Res. in press (1990)."
    },
    {
      "key": "e_1_2_1_15_2",
      "unstructured": "J.Arey A. M.Winer R.Atkinson S. M.Aschmann W. D.Long C. L.Morrison andD. M.Olszyk J. Geophys. Res. to be submitted for publication(1990)."
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/GL005i008p00679"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(87)90108-9"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100555a024"
    },
    {
      "key": "e_1_2_1_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00106a004"
    },
    {
      "key": "e_1_2_1_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550180303"
    },
    {
      "key": "e_1_2_1_21_2",
      "unstructured": "R.Atkinson S. M.Aschmann andJ.Arey Atmos. Environ. in press."
    },
    {
      "key": "e_1_2_1_22_2",
      "first-page": "1",
      "author": "Atkinson R.",
      "year": "1989",
      "journal-title": "J. Phys. Chem. Ref. Data"
    },
    {
      "key": "e_1_2_1_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00123a016"
    },
    {
      "key": "e_1_2_1_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00132a009"
    },
    {
      "key": "e_1_2_1_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100323a028"
    },
    {
      "key": "e_1_2_1_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100340a015"
    },
    {
      "key": "e_1_2_1_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ba-1972-0113.ch008"
    },
    {
      "key": "e_1_2_1_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00139307409437404"
    },
    {
      "key": "e_1_2_1_29_2",
      "first-page": "183",
      "volume": "1",
      "author": "Grimsrud E. P.",
      "year": "1975",
      "journal-title": "Int. J. Chem. Kinet., Symp."
    },
    {
      "key": "e_1_2_1_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(82)90187-1"
    },
    {
      "key": "e_1_2_1_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr00063a002"
    },
    {
      "key": "e_1_2_1_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00048331"
    },
    {
      "key": "e_1_2_1_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550140103"
    },
    {
      "key": "e_1_2_1_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100560a002"
    },
    {
      "key": "e_1_2_1_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00458a033"
    },
    {
      "key": "e_1_2_1_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550101003"
    },
    {
      "key": "e_1_2_1_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2614(80)80326-5"
    },
    {
      "key": "e_1_2_1_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00403a031"
    },
    {
      "key": "e_1_2_1_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100288a035"
    },
    {
      "key": "e_1_2_1_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100288a036"
    },
    {
      "key": "e_1_2_1_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550060509"
    },
    {
      "key": "e_1_2_1_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100614a004"
    },
    {
      "key": "e_1_2_1_43_2",
      "volume-title": "Identification of Essential Oils by Ion Trap Mass Spectrometry",
      "author": "Adams R. P.",
      "year": "1989"
    },
    {
      "key": "e_1_2_1_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0960-1686(90)90438-S"
    },
    {
      "key": "e_1_2_1_45_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150664a061"
    }
  ],
  "container-title": "International Journal of Chemical Kinetics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fkin.550220807",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/kin.550220807",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        22
      ]
    ],
    "date-time": "2023-10-22T17:51:47Z",
    "timestamp": 1697997107000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/kin.550220807"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1990,
        8
      ]
    ]
  },
  "references-count": 44,
  "journal-issue": {
    "issue": "8",
    "published-print": {
      "date-parts": [
        [
          1990,
          8
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/kin.550220807"
  ],
  "URL": "http://dx.doi.org/10.1002/kin.550220807",
  "relation": {},
  "ISSN": [
    "0538-8066",
    "1097-4601"
  ],
  "subject": [],
  "container-title-short": "Int J of Chemical Kinetics",
  "published": {
    "date-parts": [
      [
        1990,
        8
      ]
    ]
  }
}