DOI: 10.1002/kin.550151104. Stopped‐flow determination of carbon dioxide–diethanolamine reaction mechanism: Kinetics of carbamate formation

Stopped‐flow determination of carbon dioxide–diethanolamine reaction mechanism: Kinetics of carbamate formation

10.1002/kin.550151104

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractThe reaction mechanism of carbon dioxide with diethanolamine (DEA) is investigated using the stopped‐flow method with optical detection in the ranges of concentration [DEA] = 0.111–8.4 × 10−2Mand [CO2] = 2.94–5.6 × 10−3M. The comparison of the fast time‐dependent light transmission change of a pH indicator with theoretical simulations of integrated rate equations requires a kinetic model in which a simple carbamate formation takes place simultaneously with hydration reactions, whose contributions are far from being negligible. A first‐order reaction relative to DEA is thus found with a rate constant for carbamate formation smaller than usually predicted (110 ± 15M−1s−1at 25°C). The equilibrium constant for the same reaction is also determined giving pKR= 5.3 at 25°C, in satisfactory agreement with values assumed so far.

Bibliography

Barth, D., Tondre, C., & Delpuech, J. J. (1983). Stoppedâflow determination of carbon dioxideâdiethanolamine reaction mechanism: Kinetics of carbamate formation. International Journal of Chemical Kinetics, 15(11), 1147â1160. Portico.

Authors 3

D. Barth (first)
C. Tondre (additional)
J. J. Delpuech (additional)

References 20 Referenced 20

10.1149/1.2407312
{'key': 'e_1_2_1_3_2', 'volume-title': 'Gas Purification', 'author': 'Kohl A.', 'year': '1979'} / Gas Purification by Kohl A. (1979)
{'key': 'e_1_2_1_4_2', 'series-title': 'John M. Campbell (Campbell Petroleum Series)', 'volume-title': 'Gas and Liquid Seeetening', 'author': 'Maddox R. N.', 'year': '1977'} / Gas and Liquid Seeetening / John M. Campbell (Campbell Petroleum Series) by Maddox R. N. (1977)
{'key': 'e_1_2_1_5_2', 'first-page': '53', 'volume': '102', 'author': 'Blance C.', 'year': '1981', 'journal-title': 'Entropie'} / Entropie by Blance C. (1981)
10.1080/00986448008935972
10.1016/0009-2509(79)85087-3
{'key': 'e_1_2_1_8_2', 'first-page': '497', 'volume': '36', 'author': 'Laddha S. S.', 'year': '1981', 'journal-title': 'Chem. Eng. Sci.'} / Chem. Eng. Sci. by Laddha S. S. (1981)
10.1016/0009-2509(82)80100-0
10.1021/i160075a005
10.1016/0009-2509(80)85006-8
10.1016/0300-9467(77)80002-6
10.1002/cjce.5450540507
10.1002/cjce.5450540615
10.1039/TF9656100681
10.1021/j150624a027
F. J. W.RoughtonandL.Rossi‐Bernardi NASA SP 188 p. 41–45 Washington DC 1969. (10.1080/00325481.1969.11697161)
10.3891/acta.chem.scand.32a-0015
P. V.DanckwertsandM. M.Sharma Chem. Eng. CE244 1966.
10.1051/jcp/1969660232 / J. Chim. Phys. by Delpuech J. J. (1969)
10.6028/jres.066A.008

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 9:55 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 5:53 p.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 6:38 p.m.)
Issued	41 years, 9 months ago (Nov. 1, 1983)
Published	41 years, 9 months ago (Nov. 1, 1983)
Published Online	20 years, 10 months ago (Oct. 19, 2004)
Published Print	41 years, 9 months ago (Nov. 1, 1983)

Funders 0

None

BibTeX

@article{Barth_1983, title={Stopped‐flow determination of carbon dioxide–diethanolamine reaction mechanism: Kinetics of carbamate formation}, volume={15}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550151104}, DOI={10.1002/kin.550151104}, number={11}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Barth, D. and Tondre, C. and Delpuech, J. J.}, year={1983}, month=nov, pages={1147–1160} }

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